CEMS -THE ULTIMATE TOOL FOR EMISSION REGULATION

Central Pollution Control Board

 Outline of presentation
 CEMS – Definition
 Benefits of CEMS
 Components of CEMS
 Methods and Options for Source emission monitoring
 Location of installation of CEMS
 In-situ CEMS
 Extractive CEMS PM CEMS Technology Selection Matrix
 PM CEMS Calibration issues
 CEMS Options for Gaseous pollutants
 Available International quality certification of CEMS
 Minimum Quality Control Requirement
 Options for continuous Velocity measurement technologies
Parameter-wise Regulatory requirement of CEMS in 17 categories
of industries and HWI
Proposed steps in implementation of CEMS in regulatory
framework
 CEMS (Continuous Emissions Monitoring System)

The system composed of Equipment, Instrument to draw,

condition, analyze the flue gas sample and provide
permanent record of emissions or process control parameters
continuously at real time basis is called Continuous Emissions
Monitoring System (CEMS)
Benefits of CEMS
• Provides real time data.
• Remotely accessible to operator/regulator.
• Greater transparency in monitoring of performance.
• Continuous performance check of Air Pollution Control
Devices and optimization of resources used.
• Time series analysis possible with continuous data.
• Reduction in regulatory cost as well as long term monitoring
cost.
• Expected better compliance through self regulation by
industry hence lower emission.
• Primary requirement for participation in market driven
pollution control venture (ETS)
COMPONENTS OF A CEMS
 Sample Collection — sampling device
 Interface – Sample conditioning & transportation
wherever required
 Analyzer — Specific to pollutants, generates an output
signal proportional to the concentration
 Calibration devices – Analyzer control system, calibration
gases, recording etc
 Data Acquisition – Data logging system record electrical
signals in defined number of channels
 Data Handling System— Pick, calculate, record, transfer
the data in report form to desired destination
 Additionally Flow Rate Monitor (where applicable)—
Senses flue gas velocity, used to determine the mass
emissions rate of the pollutant
 Methods & Options for Source Emission Monitoring
Manual
Automatic Stack Emission
Monitoring

Portable / Reference Predictive

CEMS
Methods EMS

Extractive In-situ

Dilution Hot Wet Point Type Cross Stack

In Stack Out of Stack

Cold Dry PD
Location of Installation for CEMS
Firstly The location satisfies the minimum siting criteria of
Emission Regulation Part III (i.e., the location is greater than or
equal to eight stack duct diameters downstream and two
diameters upstream from a flow disturbance
Secondly It should be at the plane 500 mm above the Isokinetic testing Port, so,
that the reference monitoring methods are not disturbed

The installation should have logistic support like easy approach for
calibration, maintenance etc.
In-situ CEMS
SCHEMATIC CEMS MONITORING MODULE
Sampling / in-situ analyzer Segment Transfer Interface Analyzer Data acquisition & Handling
Available Technologies for Non Extractive CEMS for gas and PM

I. In-situ Cross Duct/Stack

Gas is being measured passing by a
specific ‘line of sight’ of the monitor,
typically ranging from a few feet, to the
full distance across the interior diameter
of the stack/ duct
e.g. Opacity, DOAS, FTIR, Optical
Scintllation, Light Scattering etc.

II. In-situ Probe Type

Gas is being measured at one specific
point or along a short path in the stack
or duct
e.g, Probe Electrification (DC and AC
triboelectric)
Extractive CEMS
 Extractive PM CEMS
Scatter-light Wet
Principle is same as dry but the gas is extracted and heated to
vaporise the water droplets and moisture.

Dust measuring in moisture saturated gases in waste

incinerators, emission in wet scrubbers, in desulphurization
plants & other wet gas in industrial processes
 Beta attenuation Technique (Extractive)
Attenuation of a Beta ray (electrons) emitted by a radioactive
source emitter by the particles collected on a suitable filter
matrix

Sample Probe, Nozzle

Pressurized Air
Valve
Tape-Filter Printer (optional)
4-20mA
PLC STATI
Cover Foil Counter Tube
(optional)
C-14 Source
Total Flow
Filter-Adapter Vacuum Pump
with Bypass
Sample Cooler with Controller
Automatic Drain
Supply Reel
Exhaust
Filter Advance Take-up
Stepping Motor Reel

Stack

Dilution Gas
Venturi Nozzle
 Challenges for Extractive CEMS
PM Sample has to be drawn from Stack iso-
kinetically
Distance from source and analyzer
Positive Bias of Secondary PM

Advantages of Extractive CEMS

Wet Stack emission can be monitored
Measurement Ranges of analyzer may be
maximized
 Size fractionation is possible
 Maintenance is less compared to in-situ system
 PM CEMS TECHNOLOGY SELECTION – STACK CHARACTERISTICS MATRIX
Parameter DC Tribo AC Tribo Light Scatter Opacity Light Extractive
Scintillation BAM
Light Scatter

Units of g/s, mg/m3, mg/m3 mg/m3 mg/m3 mg/m3 mg/m3

Measured Value kg/hr g/s, kg/hr

Velocity Monitor X      
Required

Duct < 1m    X X * *
Diameter
Duct >1m to 4m      * *
Diameter
Duct > 4m X X X   * *
Diameter
Electrostatic X ***     
Precipitator
Stack Gas X ***     
Temperature >
5000C
Wet Scrubber or X *** X X X  
Water Droplet
<700C
Large particles   X   X 
> 20um
Dust> 100 mg/m3   ****   X 
Varying gas  ***    ** 
velocity

* Primary Wet Stack, ** Worked on slowly varying velocity, *** ESP/Wet scrubber, *** Meas.upto 300 mg/m3
Calibration, Verification of Calibration and certification of
PM CEMS

Instrument functioning validity

• Valid Zero status
• Valid drift criteria

Limitation in PM CEMS – there is no Reference standard

for SPAN Check except standard filters for photometric
principles.
Calibration of signal against Gravimetric PM
Measurement is the only way to evolve a Dust Factor
Steps for Calibration of CEMS
• Perform repeated isokinetic sampling (minimum 6
points)
• Convert the manual reference method test data into
measurement units ( e.g., mg / NM3 or mg/sec)
consistent with the measurement conditions of PM
CEMS.
• Calculate the correlation equation(s) by drawing
Regression curve (Linear)
• Do the variability test (statistical accuracy test)
 PM CEMS CALIBRATION PROCEDURE
STEP I

Date of Time period Normalized Factory Operating

sampling of sampling Concentration of PM Condition (Production
Emission(iso-kinetic capacity (%); APCD
sampling)** on/off)
Yi (mg/Nm3)

Recommended for 15 points calibration at different load factor to ensure

linearity in detection range
At least 6 times if load variation is not possible
Supporting parameters like velocity, % Moisture, CO2 and O2 makes the system
full proof for regulatory purposes.
 PM CEMS CALIBRATION PROCEDURE
 Step 2: Draw the scatter plot and fit the
regression line
 In the scatter plot, CEMS reading
should be on X-axis and Iso-kinetic 70
y = 1.9821x - 0.7055
reading on Y-axis. 60 R² = 0.9714

 Find out the equation : y = a + bx 50

i.e: New CEMS reading = a + b*

Iso-kinetic reading
40

(Old CEMS un-calibrated reading)

30

20
Iso-kinetic
Sr. No. CEMS reading reading
10
0 0
1 25.2 44.2
0
2 26.1 53.4 0 5 10 15 20 25 30
3 24.1 46 -10
4 28.3 59.8 CEMS reading

5 21.1 38.1
6 18.1 36.8
Statistical Accuracy Test

•
CEMS for Gaseous Pollutants
 Cold Dry Extractive System
Heated
filter Blow Back

Probe
(at stack) To distantly located
analyzers thro’ Heated Walk-in
sample line shelter

Analyzers
Condenser Pump SO2

NOx
CO
CO2 Output Signal to
Drain DAS

Calibration gas supply

to analyzers
 Hot Wet Extractive System
Blow Back
Heated
filter

Probe
(at stack) To distantly located Walk-in
analyzer - heated line shelter

Heated
Analyzer
SO2
Heated
NOx
Pump
CO
CO2 Output Signal to
DAS

Calibration gas supply

to analyzers
Dilution Probe
In-situ Gaseous Pollutants Measuring Techniques
• IR – GFC (Gas Filter Correlation)

• IR – IFC (Interference Filter Photometric Correlation)

• UV DOAS

• TDLS (Tunable Diode Laser)

• Zirconia
Optical Components An example for In-situ Multiple gas analyzer

DOAS
Differential
Optical
Absorption
Spectroskopy
In-situ gas analyzers

DOAS
DOAS
Differential
Differential
Optical
Optical
Absorption
Absorption
Spectroskopy
Spectroskopy
Summary of CEMS Technology Options
Typical Schematic presentation of an Analyzer
IR source Cuvette Detector
Sample gas Sample gas front rear
absorption volume

Measuring side

Reference side
Pressure-balancing
N2 capillary
Membrane capacitor

Synchronous
motor
Measuring
amplifier

Modulation
wheel A/D
N2 N2 converter

Microprocessor

Analog outputs
Display
RS232C Interface
 Typical Analyzer with Calibration System
IR source Cuvette Detector
Sample gas Sample gas front rear
absorption volume

Measuring side N2

Reference side N2
Pressure-balancing
capillary
Membrane capacitor

Synchronous Gear
motor motor
N2 Measuring
amplifier

Modulation
wheel A/D
N2 N2 converter

Microprocessor

Analog outputs
Display
RS232C Interface
 International Certification for PM-CEMS
European Union USA

QAL 1 (EN) MACT

(Quality assurance level 1) (Maximum Achievable Control
QAL 2 & QAL 3 (EN) Technology); this is an objective
Performance Standard oriented quality certification
applicable to US only
TUV (Germany) EPA Technology approval system
(Technical watch-over
Association) – a Product
standard
MCERTS (UK) PS-1 to PS 11
(Monitoring Certification (USEPA) It is a performance
Schemes) – a Product standard Standard
 Continuous Velocity / Flow Measurement

Pitot Tube / DP Differential Pressure

Measuring Transducer
Microprocessor
Evaluation Unit
Differential pressure developed
due to the flow between Cross Over
Absolute Temperature
two points is proportional to Cock Pressure
Measuring
Measuring
Transducer
Transducer (optional)
the square of the flow rate. Flow Probe
(optional)

Flow
Direction

Ultrasonic
Transit time difference
between upstream and
downstream signal is
proportional to the velocity
of flue gas.
 Continuous Velocity / Flow Measurement

Thermal Mass Flow

The energy required to maintain the
constant temperature between
two probes is directly
proportional to the mass flow
rate.

IR-Time Correlation Technique Det 2

Measured gas velocity using a time
delay correlation of flue gas
infrared emission received by Det 1
two detectors spaced a fixed
distance apart.
 Minimum Quality Control Requirements
a)CEMS Specification should have compliance with one or more of the
international standards e.g. US-EPA, German TUV and MCERTS, UK. It is not
necessary to meet all three.
b) All CEMS shall be installed operated, maintained and calibrated in a
manner consistent with the manufacturer’s recommendations
c) The CEMS must to perform a daily system calibration check
automatically
i)The system calibration check must be performed daily at 2 levels: a low
level (0-20% of span value) and at a high level of 1.5 times the emission
limits.
ii)For extractive systems, the calibration gases are to be introduced
upstream of all filters and sample conditioning system as close to the tip of
the probe as possible.
ii) Opacity monitor calibration checks must be performed daily at 2 levels;
a low level (0-10%) and span level of (40-60%). PM monitors must conduct
a daily calibration at a low level (0-10%) and span level of (50-100%) of the
full scale range (max. mg/m3).
iii) Flow monitor calibration checks shall be at a low value of (0-10%) and a
span level of (40-60% of 125% x maximum velocity)
 Minimum QC Requirements

d) Daily drift checking

For opacity monitors daily drift is limited to +/-2% opacity

For PM’s the daily drift is limited to +/-3% of span
For flow monitors the daily drift is limited to +/-3% of span
Daily records must be kept and adjustments shall be made if the drift is
greater than 10% of the calibration gas value

e) The CEMS must operate continuously collecting and recording valid

data for at least 95% for all required parameters.

Allowable period of Downtime in following situations

i) Monitor breakdown
ii) Schedule monitor maintenance
iii) Daily zero and span checks
iv) Performance specification testing.

If data robustness fall below 55%, Specific accuracy test is mandatory.

 Flow meter Selection Matrix

Impact Differential Pressure

Thermal Bi-directional Infrared
Type (Pitot Tube)
anemometer 1 ultrasonic correlation
Single point Multiport
Irregular
X  2 2 
Flow
Max Flue
Gas 200 – 300oC 450° C - 850 °C
Up to 550°C Up to 550°C Up to 1000oC
Temperatu (model specific) (model specific)
re
Wet stack X X X  
Low speed X (minimum 5 m/s)   1 m/s – 50m/s
High Up to 40 m/s
   1 m/s – 50m/s
Speed (model specific)
Calibration Factory+Site Factory+Site Factory+Site 3 Factory+Site Factory+Site
1 Pressure Transmitter (PT) and Temperature Transmitter (TT) are not installed with a
Thermal Anemometer as it directly measures Mass Flow which is usually the required
quantity. However, for the purpose of ETS in Type 2 CEMS configuration, Volumetric Flow
is required and hence PT and TT are necessary to calculate density and convert mass flow
calculated by the anemometer to volumetric flow.
2 Can be accounted for by using multiple probes/sensors
3 Calibration depends on physical properties (thermal conductivity, specific heat) of the
gas whose flow is to be measured. Thus variation in properties of stack gas from factory
calibrated values can result in inaccurate measurement.
 HARDWARE SPECIFICATIONS
Industry should select a vendor fulfilling the following requirements:
 CEMS device should be tamper proof
 PM CEMS device should ideally measure and report both the
uncalibrated data to the DAS.
 PM CEMS device and flow meter should meet following
specifications of key operating parameters:
Name of Parameter Specifications
PM CEMS Device Flow Meter
Measurement range User defined User Defined
Instrument 10 mg/Nm3 or less 1 m/s (minimum detectable limit)
detectable concentration
Data acquisition 1 minute 1 minute
Data transmission 1 minute 1 minute
Deviation in the raw reading < 5% of measurement <2% of measurement range
range
Drift < 1% per month Overall zero & span drift should be <
1% per month
Power supply 220 +/- 10 V at 50 Hz

Data Availability 90% or higher under 90% or higher under normal operation
normal operation
 17 Categories of Industry, their emission standards and probable options for CEMS
SN Industries Pollutants Emission Limits Recommended CEMS Options
1 Aluminium Smelting
Raw Material Handling PM – 150 In situ PM CEMS
Calcinations PM – 250 NDIR for CO
CO – 1% (Max) FTIR for CO and F
Green Anode Shop PM – 150 DOAS for all
Anode Bake Oven PM – 50
Total Fluoride – 0.3 Kg/MT of Al
Pot room PM – 150
Total Fluoride – 2.8 Kg/MT of Al
for Soderberg Technology
Total Fluoride – 0.8 kg/t for Pre-baked
Technology
2 Basic Drugs & Pharmaceuticals For incinerator Preferably Extractive PM CEMS
PM – 50 NDIR for CO
SO2 – 200 IR GFC, FTIR, DOAS for multi-gas
CO – 100 analysis
TOC – 20 FID for HC (TOC)
PCDDs /F – 0.2ng TEQ/NM3 (existing) PCDDs, Metal not possible by
PCDDs /F – 0.1ng TEQ/NM3 (New CEMS
commissioned after July 2009)
Metals – 1.5
3 Chlor Alkali (Hg Cell)
(H2 Gas stream) Hg – 0.2 FTIR for multi-gas
( Hypo tower) Cl2 – 15
(HCl Plant) HCl vapour and Mists – 35
4 Cement (200TPD and above) PM – 250 In-situ PM CEMS
Plant within 5 KM radious of urban agglomeration with PM – 100 Preferably Extractive PM CEMS
more than 5 Lakh population NDIR for CO
New Cement Plants PM – 50 IR GFC, FTIR, DOAS for multi-gas
Cement Plants with Co-incineration All parameters as CHWI analysis
FID for HC (TOC)
PCDDs, Metal not possible by
CEMS
 17 Categories of Industry, their emission standards and probable options for CEMS
SN Industries Pollutants Emission Limits Recommended CEMS Options
5 Copper Smelting (Old Units) PM – 100 In-situ PM CEMS
Copper Smelting (New Units) PM – 75
SO2 recovery units upto 300 T SO2 – 1370 (Existing)
SO2 recovery units above 300 T 1250 (New) UV Fluorescence,
Acid Mist and FTIR, DOAS
Sulphur Trioxide – 90 (Existing); 70 (New)
SO2 – 1250 (Existing); 950 (New)
Acid Mist and Sulphur Trioxide – 70 (Existing); 50 (New)
6 Dyes and Dye Intermediate
Process SO2 – 200 In situ PM CEMS
HCl (Mist) – 35 IR GFC, FTIR, DOAS TLD, PAS for
NH3 – 30 multi-gas analysis
Cl2 – 15 FID for TOC
Captive Incinerator PM – 50 PCDDs, Metal not possible by CEMS
SO2 – 200
HCl (Mist) – 50
CO – 100
TOC – 20
PCDDs /F – 0.1ng TEQ/NM3
Metals – 1.5
7 Fermentation (Distillery) Boiler Standard In situ System for PM
8 Fertiliser (Phosphate) PM – 150 In situ System for PM
Total Fluoride – 25 FTIR, DOAS TLD, PAS for F
Fertiliser (Urea) Old plants PM – 150 or 2Kg/MT product Velocity monitor
Fertiliser (Urea) New plants Total Fluoride – 50 or 0.5Kg/MT product
9 Integrated Iron & Steel In situ System for PM
Sintering plant PM – 150 NDIR for CO
Steel making PM – 150 (Normal Operation); PM – 450 (Oxygen Lancing) Velocity monitor
Rolling Mill PM – 150
Coke Oven PM – 50
CO – 3 Kg/T coke
Refractory Material Plant PM – 150
 17 Categories of Industry, their emission standards and probable options for CEMS

SN Industries Pollutants Emission Limits Recommended CEMS Options

10 Leather Processing Tanneries Boilers Standard In situ PM CEMS
11 Oil Refinery
Furnace, Boiler and captive power plant Polutants Before 2008 After 2008
Gas based SO2 50 50 BAM for PM
NOX 350 250 IR GFC, FTIR, DOAS TLD, PAS
PM 10 5
CO 150 100
Ni + V 5 5
H2S 150 150
Furnace, Boiler and captive power plant SO2 1700 850
Liquid Fuel based NOX 450 350
PM 100 50
CO 200 150
Ni + V 5 5 In situ PM CEMS
H2S 150 150 IR GFC, FTIR, DOAS TLD, PAS for multi-gas analysis
FCC Regenerator Hydro Others or individual technology specific to pollutants
SO2 500 1700
NOX 400 450
350 (N)
PM 100 100
50 (N)
CO 400 400
300 (N)
Ni + V 5 2 (N)
2 CEMS Not Applicable for Metals
% Opac. 30 30 Opacity
SRU H2S 15 10 (N) IR GFC
NOX 350 250
CO 150 100
 17 Categories of Industry, their emission standards and probable options for CEMS

SN Industries Pollutants Emission Limits Recommended CEMS Options

12 Pesticide HCl – 20 IR GFC, FTIR, DOAS TLD, PAS
CL2 – 5
H2S – 5
P2O5 (as H3PO4) - 10
NH3 – 30 P2O5, PM with Pesticide and CH3Cl
PM with Pesticide – 20 Are not conventional CEMS parameter
CH3Cl – 20
HBr – 5
13 Pulp & Paper PM – 250 In situ System for PM
H2S – 10 IR GFC for H2S
14 Petrochemical Before 2007 After 2007 In situ PM CEMS
Polutants IR GFC, FTIR, DOAS TLD, PAS for multi-gas
SO2 1700 850 analysis or individual technology
NOX (Liquid) 150 specific to pollutants
PM 350 (Gas) 250
CO 400 (Liquid) 100
150 (Liquid) 150
150
15 Sugar Boiler Standard In situ PM CEMS
16 Thermal Power Plants In situ PM CEMS
Less than 210 MW PM – 350
More than 210 MW PM – 150 In situ PM CEMS
17 Categories of Industry, their emission standards and probable options for CEMS

SN Industries Pollutants Emission Limits Recommended CEMS Options

17 Zinc Smelting (Old Units) PM – 100 In situ PM CEMS
Zinc Smelting (New Units) PM – 75
SO2 recovery units upto 300 T SO2 – 1370 (Existing);1250 (New) FTIR, DOAS
Acid Mist and Sulphur Trioxide –
90 (Existing); 70 (New)
SO2 recovery units above 300 T SO2 – 1250 (Existing) ;950 (New)
Acid Mist and Sulphur Trioxide –
70 (Existing); 50 (New)
Boilers (According to capacity)
Particulate Matter
Less than 2 T / hr 1600
2 – 15 T/hr 1200
Above 15 T/hr. 150
In situ PM CEMS
Steam Generation
less than 2 Particulate Matter
2 to less than 10 1200
10 to less than 15 800
15 and above 600
150
All above concentrations are subject to
12 % CO2 correction
Notes:

Wherever load based standards are notified Flow/Velocity Monitor is mandatory

O2, CO2 monitoring is essential where the standards are to be corrected for.

CO2 monitoring is a complementary part of monitoring if extractive dilution system is

selected.
 COMMON HAZARDOUS WASTE INCINERATOR
A. Emission
Limiting concentration in mg/Nm3 Sampling Duration in (minutes) unless
unless stated stated
Particulate Matter 50 30
HCL 50 30
SO2 200 30
CO 100 30
50 24 hours
Total Organic Carbon 20 30
HF 4 30
NOx (NO and NO2, expressed as 400 30
NO2
Total dioxins and Furans 0.1 ngETQ/Nm3 8 hours
Cd+Th+their Compounds 0.05 2 hours
Hg and its Compounds 0.05 2 hours
Sb+As+Pb+Co+Cr+Cu+Mn+Ni+ 0.50 2 hours
V+ their Compounds

Notes:
i.All monitored values shall be corrected to 11 % oxygen on dry basis.
ii.The CO2 concentration in tail gas shall not be less than 7%.
iii.In case, halogenated organic waste is less than 1% by weight in input waste, all the facilities in twin chamber
incinerators shall be designed to achieve a minimum temperature of 950oC in secondary combustion chamber and with a
gas residence time in secondary combustion chamber not less than 2 (two) seconds.
iv.In case halogenated organic waste is more than 1% by weight in input waste, waste shall be incinerated only in twin
chamber incinerators and all the facilities shall be designed to achieve a minimum temperature of 1100oC in secondary
combustion chamber with a gas residence time in secondary combustion chamber not less than 2 (two seconds).
v.Incineration plants shall be operated (combustion chambers) with such temperature, retention time and turbulence, as to
achieve Total Organic Carbon (TOC) content in the slag and bottom ashes less than 3%, or their loss on ignition is less than
5% of the dry weight].
 Steps in Implementation of CEMS in Regulatory Frame Work

 Recommending Technologies and their suitability for specific pollutants in

specific emission through guideline
 Ensure quality of instruments by specifying international product standards
 Certification of CEMS installed based on their suitability, compliance on
installation and basic operational criteria (operational criteria like data
robustness may be evolved for India through discussion)
 Recommending minimum Quality Control criteria at initial stage (may be
little relaxed than international practices)
 Building Data base during first one Year
 Basic statistical Data analysis to fix the range of variation against time for
specific industry and specific pollutants
 Fixing variability criteria for specific industry against specific pollutants for
compliance monitoring through regulatory mechanism
 Until the variability criteria is fixed the industries should be allowed to
adopt existing compliance practice
 Guidelines for Quality assurance and performance may be prepared
afterwards and implemented as a full proof system
Thank You