SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name OK 48.00
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use Arc Welding
1.3. Details of the supplier of the safety data sheet
Supplier ESAB AB
Street address Box 8004
402 77 Göteborg
Sweden
Telephone +46 31 509000
Email sds.esab@esab.se
Web site www.esab.com
1.4. Emergency telephone number
Emergency phone number +4631509000
Available outside office hours No
Other
Classification(s): EN ISO 2560-A: E 42 4 B 42 H5
SFA/AWS A5.1: E7018
SECTION 2:Hazards identification
2.1. Classification of the substance or mixture
The product is not classified
2.2. Label elements
The product do not require labeling
2.3. Other hazards
This product contains titanium dioxide which is possibly carcinogenic. This product contains quartz, but normally not in an inhalable
fraction. Quartz can cause silicosis and may cause cancer. Avoid eye contact or inhalation of dust from the product. Skin contact is
normally no hazard but should be avoided to prevent possible allergic reactions. Persons with a pacemaker should not go near welding or
cutting operations until they have consulted their doctor and obtained information from the manufacturer of the device.
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
When this product is used in a welding process, the most important hazards are welding fumes, heat, radiation and electric shock.
Fumes: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or irritation of the
nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function. Overexposure to manganese and
manganese compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the brain,
symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic gait.
Heat: Spatter and melting metal can cause burn injuries and start fires.
Radiation: Arc rays can severely damage eyes or skin.
Electricity: Electric shock can kill.
Other
Emergency Overview: Coated metal rods in varying colours. This product is normally not considered hazardous as shipped. Gloves
should be worn when handling to prevent contaminating hands with product dust.
SECTION 3:Composition/information on ingredients
3.2. Mixtures
CAS No.
Chemical name EC No. Concentration Classification H-phrase
REACH No.
Iron 7439-89-6 30 - 40% - -
231-096-4
01-2119462838 - 24
Limestone 1317-65-3 15 - 35% - -
215-279-6
-
Fluorides 7789-75-5 10 - 20% - -
232-188-7
-
Silicates 1344-09-8 <10% - -
215-687-4
-
Titanium oxide 13463-67-7 3 - 8% - -
236-675-5
-
Manganese 7439-96-5 2 - 5% - -
231-105-1
01-2119449803 - 34
Quartz 14808-60-7 <5% STOT RE 1 H372
238-878-4
-
Silicates 1312-76-1 <5% - -
215-199-1
-
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
Silicon 7440-21-3 2 - 5% - -
231-130-8
-
Aluminum silicate 12141-46-7 <3% - -
235-253-8
-
Product based on This product is a preparation of core wire with extruded coating.
SECTION 4:First aid measures
4.1. Description of first aid measures
Electric shock: Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact with live parts or wires.
If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable pulse, begin Cardio Pulmonary Resuscitation
(CPR). Call a physician immediately.
Inhalation If breathing has stopped, perform artificial respiration and obtain medical assistance immediately! If
breathing is difficult, provide fresh air and call physician.
Skin contact For skin burns from arc radiation, promptly flush with cold water. Get medical attention for burns or
irritations that persist. To remove dust or particles wash with mild soap and water.
Eye contact For radiation burns due to arc flash, see physician. To remove dusts or fumes flush with water for at
least fifteen minutes. If irritation persists, obtain medical assistance.
4.2. Most important symptoms and effects, both acute and delayed
Not applicable
4.3. Indication of any immediate medical attention and special treatment needed
Not applicable
SECTION 5:Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media No specific recommendations for welding consumables. Welding arcs and sparks can ignite
combustible and flammable materials. Use the extinguishing media recommended for the burning
materials and fire situation.
5.2. Special hazards arising from the substance or mixture
Not applicable
5.3. Advice for firefighters
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
Special protective equipment Wear self-contained breathing apparatus as fumes or vapors may be harmful.
for fire-fighters
SECTION 6:Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
refer to section 8.
6.2. Environmental precautions
refer to section 13.
6.3. Methods and material for containment and cleaning up
Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into a container. Wear
proper protective equipment while handling these materials. Do not discard as refuse.
6.4. Reference to other sections
refer to section 8/13
SECTION 7:Handling and storage
7.1. Precautions for safe handling
Preventive handling Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid
precautions exposure to dust. Do not ingest. Some individuals can develop an allergic reaction to certain
materials. Retain all warning and identity labels.
7.2. Conditions for safe storage, including any incompatibilities
Keep separate from chemical substances like acids and strong bases, which could cause chemical reactions.
7.3. Specific end use(s)
Arc Welding
SECTION 8:Exposure controls/personal protection
8.1. Control parameters
Exposure limits Use industrial hygiene monitoring equipment to ensure that exposure does not exceed applicable
national exposure limits. The following limits can be used as guidance. Unless noted, all values are
for 8 hour time weighted averages (TWA). For information about welding fume analysis refer to
Section 10.
UK, Workplace Exposure Limits, mg/m3
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
National occupational Exposure
exposure limits Short-term ex
CAS EC limit
Ingredient posure limit Remark Source Year
no. No. mg/m3-
mg/m3-ppm
ppm
Iron 7439-8 - 5 - - - Fume - 2015
9-6
Fluorides 7789-7 - 2,5 - - - Fume - 2015
5-5
Quartz 14808-6 - 0,1 - - - Respirable fr - 2015
0-7 action
Manganese po 7439-9 - 0,5 - - - Inhalable frac - 2015
wder 6-5 tion
Limestone 1317-6 - 4 - - - Respirable fr - 2015
5-3 action
Titanium oxide 13463-6 - 4 - - - Respirable fr - 2015
7-7 action
Silicon 7440-2 - 4 - - - Respirable fr - 2015
1-3 action
Limestone 1317-6 215-27 10 - - - Inhalable frac - -
5-3 9-6 tion
Titanium oxide 13463-6 236-67 10 - - - Inhalable frac - -
7-7 5-5 tion
Silicon 7440-2 231-13 10 - - - Inhalable frac - -
1-3 0-8 tion
Manganese 7439-9 231-10 0,5 - - - Inhalable frac - -
6-5 5-1 tion
8.2. Exposure controls
Not applicable
Other
Avoid exposure to welding fumes, radiation, spatter, electric shock, heated materials and dust. Train welders to avoid contact with live
electrical parts and insulate conductive parts.
Ventilation Use respirator or air supplied respirator when welding or brazing in a confined space, or where local
exhaust or ventilation is not sufficient to keep exposure values within safe limits. Use special care
when welding painted or coated steels since hazardous substances from the coating may be
emitted. Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from
breathing zone and general area.
Personal protective equipment Wear hand, head, eyes, ear and body protection like welders gloves, helmet or face shield with filter
lens, safety boots, apron, arm and shoulder protection. Keep protective clothing clean and dry.
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
SECTION 9:Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Solid, non-volatile with varying color.
Appearance, colour Not applicable
Appearance, physical state Not applicable
Auto-ignition temperature Not applicable
Decomposition temperature Not applicable
Evaporation rate Not applicable
Explosive properties Not applicable
Flammability (solid, gas) Not applicable
Flash point Not applicable
Initial boiling point and boiling Not applicable
range
Melting point >1300°C / >2300ºF
Melting point / freezing point Not applicable
Odour Not applicable
Odour treshold Not applicable
Oxidising properties Not applicable
Partition coefficient: n-octanol / Not applicable
water
pH value Not applicable
Relative density Not applicable
Solubility Not applicable
Upper / lower flammability or Not applicable
explosive limits
Vapour density Not applicable
Vapour pressure Not applicable
Viscosity Not applicable
9.2. Other information
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
Not applicable
SECTION 10:Stability and reactivity
10.1. Reactivity
Reactivity Contact with chemical substances like acids or strong bases could cause generation of gas.
10.2. Chemical stability
Chemical stability Stable at normal conditions
10.3. Possibility of hazardous reactions
Not applicable
10.4. Conditions to avoid
Conditions to avoid This product is only intended for normal welding purposes.
10.5. Incompatible materials
Not applicable
10.6. Hazardous decomposition products
Hazardous decomposition When this product is used in a welding process, hazardous decomposition products would include
products those from the volatilization, reaction or oxidation of the materials listed in section 3 and those from
the base metal and coating.
The amount of fumes generated from manual metal arc welding varies with welding parameters and
dimensions, but is generally no more than 5 to 15 g/kg consumable.
Fumes from this product contain compounds of the following chemical elements. The rest is not
analysed, according to available standards.
Fume analysis in weight %:
Fe <25
Mn <5
F <25
Pb <0.2
Cu <0.1
Ni <0.1
Cr <0.1
Other
Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in Section 8.
Manganese has a low exposure limit, in some countries, that may be easily exceeded.
Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the welding
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
area can be affected by the welding process and influence the composition and quantity of fumes and gases produced.
SECTION 11:Toxicological information
11.1. Information on toxicological effects
Information on toxicological Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding
effects fumes is difficult because of varying base materials, coatings, air contamination and processes.
The International Agency for Research on Cancer has classified welding fumes as possibly
carcinogenic to humans (Group 2B).
acute toxicity Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever,
dizziness, nausea, dryness or irritation of the nose, throat or eyes.
skin corrosion/irritation Not applicable
serious eye damage/irritation Not applicable
Respiratory/skin sensitization Not applicable
germ cell mutagenicity Not applicable
Genotoxicity Not applicable
carcinogenicity Not applicable
reproductive toxicity Not applicable
STOT-single exposure Not applicable
STOT-repeated exposure Not applicable
Harmful if inhaled Not applicable
Other
Long term effect
Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Overexposure to
manganese and manganese compounds above safe exposure limits can cause irreversible damage
to the central nervous system, including the brain, symptoms of which may include slurred speech,
lethargy, tremor, muscular weakness, psychological disturbances and spastic gait. Prolonged
inhalation of titanium dioxide above safe exposure limits can cause cancer. Inhalable quartz is a
respiratory carcinogen however the process of welding converts crystalline quartz to the amorphous
form which is not considered to be a carcinogen.
SECTION 12:Ecological information
12.1. Toxicity
Not applicable
12.2. Persistence and degradability
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
Not applicable
12.3. Bioaccumulative potential
Not applicable
12.4. Mobility in soil
Not applicable
12.5. Results of PBT and vPvB assessment
Not applicable
12.6. Other adverse effects
Not applicable
Other
Welding consumables and materials could degrade/weather into components originating from the consumables or from the materials
used in the welding process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater.
SECTION 13:Disposal considerations
13.1. Waste treatment methods
Disposal considerations Discard any product, residue, disposable container or liner in an environmentally acceptable
manner, in full compliance with federal and local regulations. Use recycling procedures if available.
USA RCRA: This product is not considered hazardous waste if discarded.
Residues from welding consumables and processes could degrade and accumulate in soils and
groundwater.
Welding slag from this product typically contains mainly the following components originating from
the coating of the electrode.
Slag analysis in %:
CaO <50
F <20
Fe2O3 <10
K2O <5
MnO <10
SiO2 <25
Na2O <5
TiO2 <15
Al2O3 <5
SECTION 14:Transport information
14.1. UN number
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
Not applicable
14.2. UN proper shipping name
Not applicable
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
Not applicable
14.6. Special precautions for user
Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15:Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Other regulations, limitations Canada: WHMIS classification: Class D; Division 2, Subdivision A Canadian Environmental
and legal regulations Protection Act (CEPA): All constituents of this product are on the Domestic Substance List (DSL).
USA: Under the OSHA Hazard Communication Standard, this product is considered hazardous.
USA: This product contains or produces a chemical known to the state of California to cause
cancer and birth defects (or other reproductive harm). (California Health & Safety Code § 25249.5 et
seq.)
United States EPA Toxic Substance Control Act: All constituents of this product are on the TSCA
inventory list or are excluded from listing.
CERCLA/SARA Title III Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs): :
Product is a solid solution in the form of a solid article.
- Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate
notification to the National Response Center and to your Local Emergency Planning Committee.
Section 311 Hazard Class As shipped: Immediate In Use: Immediate delayed
The following metallic components are listed as SARA 313 "Toxic Chemicals" and potential subject
to annual SARA 313 reporting. See Section 3 for weight percent. Manganese: 1.0% de minimis
concentration
15.2. Chemical safety assessment
Chemical safety assessment No
SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No
1907/2006, 1272/2008, ISO 11014-1 and ANSI Z400.1
OK 48.00
Version number: 8
Replaces SDS: 2016-05-31
Issued: 2017-01-11
Other
Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety instructions on the
label. Observe any federal and local regulations. Take precautions when welding and protect yourself and others.
WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate ventilation.
ELECTRIC SHOCK can kill. ARC RAYS and SPARKS can injure eyes and burn skin.
Wear correct hand, head, eye and body protection.
SECTION 16:Other information
Changes to previous revision This Safety Data Sheet has been revised due to modification(s) to section(s) 1-16
References to key literature Refer to ESAB "Welding and Cutting - Risks and Measures", F52-529 “Precautions and Safe
and data sources Practices for Electric Welding and Cutting” and F2035 “Precautions and Safe Practices for Gas
Welding, Cutting and Heating” available from ESAB, and to: www.esab.com
Phrase meaning STOT RE 1 - Specific Target Organ Toxicity — Repeated exposure, hazard category 1
H372 - Causes damage to organs through prolonged or repeated exposure cause the hazard>.
Other
Additional information ESAB requests the users of this product to study this Safety Data Sheet (SDS) and become aware
of product hazards and safety information. To promote safe use of this product a user should:
notify its employees, agents and contractors of the information on this SDS and any product
hazards/safety information.
furnish this same information to each of its customers for the product.
request such customers to notify employees and customers for the same product hazards and
safety information.
The information herein is given in good faith and based on technical data that ESAB believes to be
reliable. Since the conditions of use is outside our control, we assume no liability in connection with
any use of this information and no warranty, expressed or implied is given. Contact ESAB for more
information.
