MATERIAL SAFETY DATA SHEET
Appello Interiors L.L.C
Warehouse 19, RKM Compound, Al Quoz 3, Dubai, UAE
Email: info@appellointeriors.com Tel: +971 4 547 1122
Material Safety Data Sheets
A Material Safety Data Sheet (MSDS) is a document that contains information on the potential hazards
(health, fire, reactivity and environmental) and how to work safely with the chemical product. It is an
essential starting point for the development of a complete health and safety program. It also contains
information on the use, storage, handling and emergency procedures all related to the hazards of the
material. The MSDS contains much more information about the material than the label. MSDSs are
prepared by the supplier or manufacturer of the material. It is intended to tell what the hazards of the
product are, how to use the product safely, what to expect if the recommendations are not followed,
what to do if accidents occur, how to recognize symptoms of overexposure, and what to do if such
incidents occur.
Employer Responsibilities
Employers must ensure that the MSDS is readily accessible to employees for all
hazardous chemicals in their workplace. This may be done in many ways. For example,
employers may keep the MSDSs in a binder or on computers as long as the employees
have immediate access to the information without leaving their work area when needed
and a back-up is available for rapid access to the MSDS in the case of a power outage or
other emergency. Furthermore, employers may want to designate a person(s)
responsible for obtaining and maintaining the MSDSs. If the employer does not have an
MSDS, the employer or designated person(s) should contact the manufacturer to obtain
one.
When would I use an MSDS?
Always be familiar with the hazards of a product BEFORE you start using it. You should
look at a MSDS, match the name of the chemical on your container to the one on the
MSDS, know the hazards, understand safe handling and storage instructions, as well as
understand what to do in an emergency.
1
Section 1: Identification
This section identifies the chemical on the MSDS as well as the recommended uses.
It also provides the essential contact information of the supplier. The required
information consists of:
• Product identifier used on the label and any other common names or synonyms
by which the substance is known.
• Name, address, phone number of the manufacturer, importer, or other
responsible party, and emergency phone number.
• Recommended use of the chemical (e.g., a brief description of what it
actually does, such as flame retardant) and any restrictions on use (including
recommendations given by the supplier).
2
Section 2: Hazard(s) Identification
This section identifies the hazards of the chemical presented on the MSDS and the
appropriate warninginformationassociatedwith thosehazards. The requiredinformation
consistsof:
• The hazard classification of the chemical (e.g., flammable liquid, category1).
• Signal word.
• Hazard statement(s).
• Pictograms (the pictograms or hazard symbols may be presented as graphical reproductions
of the symbols in black and white or be a description of the name of the symbol (e.g., skull
and crossbones,flame).
• Precautionary statement(s).
• Description of any hazards not otherwise classified.
• For a mixture that contains an ingredient(s) with unknown toxicity, a statement describing how
much (percentage) of the mixture consists of ingredient(s) with unknown acute toxicity. Please
notethatthisisa totalpercentageofthemixtureandnottiedtotheindividualingredient(s).
Section 3: Composition/Information on Ingredients
This section identifies the ingredient(s) contained in the product indicated on the MSDS,
including impurities and stabilizing additives. This section includes information on substances,
mixtures, and all chemicals where a trade secret is claimed. The required information
consists of:
Substances
• Chemical name.
• Common name and synonyms.
• ChemicalAbstracts Service (CAS) number and other unique identifiers.
• Impurities and stabilizing additives, which are themselves classified and which contribute to
the classification of the chemical.
Mixtures
• Same information required for substances.
• The chemical name and concentration (i.e., exact percentage) of all ingredients which are
classified as health hazards and are:
° Present above their cut-off/concentration limits or
° Present a health risk below the cut-off/concentration limits.
• The concentration (exact percentages) of each ingredient must be specified except
concentration ranges may be used in the following situations:
° A trade secret claim is made,
° There is batch-to-batch variation, or
° The SDS is used for a group of substantially similar mixtures.
Chemicals where a trade secret is claimed
• A statement that the specific chemical identity and/or exact percentage (concentration) of
composition has been withheld as a trade secret is required.
3
Section 4: First-Aid Measures
Thissectiondescribestheinitialcarethatshouldbegivenbyuntrainedresponderstoan
individualwhohasbeenexposedtothechemical.Therequiredinformationconsistsof:
• Necessary first-aid instructions by relevant routes of exposure (inhalation, skin and
eye contact, and ingestion).
• Description of the most important symptoms or effects, and any symptoms
that are acute or delayed.
• Recommendations for immediate medical care and special treatment needed, when
necessary.
Section 5: Fire-Fighting Measures
This section provides recommendations for fighting a fire caused by the chemical. The
required information consists of:
• Recommendations of suitable extinguishing equipment, and information about
extinguishing equipment that is not appropriate for a particular situation.
• Advice on specific hazards that develop from the chemical during the fire,
such as any hazardous combustion products created when the chemical
burns.
• Recommendations on special protective equipment or precautions for firefighters.
Section 6: Accidental Release Measures
This section provides recommendations on the appropriate response to spills, leaks, or releases,
including containment and cleanup practices to prevent or minimize exposure to people,
properties,or the environment. It may also include recommendations distinguishing between
responses for large and small spills where the spill volume has a significant impact on the
hazard. The required information may consist of recommendations for:
• Use of personal precautions (such as removal of ignition sources or providing sufficient
ventilation) and protective equipment to prevent the contamination of skin, eyes, and clothing.
• Emergency procedures, including instructions for evacuations, consulting
experts when needed, and appropriate protective clothing.
• Methods and materials used for containment (e.g., covering the drains
and capping procedures).
• Cleanup procedures (e.g., appropriate techniques for neutralization, decontamination,
cleaning or vacuuming; adsorbent materials; and/or equipment required for
containment/cleanup).
Section 7: Handling and Storage
Thissectionprovidesguidanceonthesafehandlingpracticesandconditionsforsafestorage
of chemicals. The required information consists of:
• Precautions for safe handling, including recommendations for handling incompatible
chemicals, minimizing the release of the chemical into the environment, and providing advice
on general hygiene practices (e.g., eating, drinking, and smoking in work areas is prohibited).
• Recommendations on the conditions for safe storage, including any incompatibilities.
Provide advice on specific storage requirements (e.g., ventilation requirements).
4
Section 8: Exposure Controls/PersonalProtection
This section indicates the exposure limits, engineering controls, and personal protective
measuresthatcanbeusedtominimizeworkerexposure. Therequiredinformationconsistsof:
• OSHA Permissible Exposure Limits (PELs), American Conference of Governmental
Industrial Hygienists(ACGIH) ThresholdLimitValues(TLVs),and anyother exposure limit
usedor recommended by the chemical manufacturer, importer, or employer preparing the
safety data sheet, whereavailable.
• Appropriate engineering controls (e.g., use local exhaust ventilation, or use only
in an enclosed system).
• Recommendations for personal protective measures to prevent illness or injury from
exposure to chemicals, such as personal protective equipment (PPE) (e.g., appropriate types of
eye, face, skin or respiratory protection needed based on hazards and potential exposure).
• Any special requirements for PPE, protective clothing or respirators (e.g., type of glove
material, such as PVC or nitrile rubber gloves; and breakthrough time of the glove material).
Section 9: Physical and Chemical Properties
This section identifies physical and chemical properties associated with the substance or mixture.
The minimum required information consists of:
• Appearance (physical state, color, etc.); • Upper/lower flammability or explosive limits;
• Odor; • Vapor pressure;
• Odor threshold; • Vapor density;
• pH; • Relative density;
• Melting point/freezingpoint; • Solubility(ies);
• Initial boiling point and boiling range; • Partitioncoefficient:n-octanol/water;
• Flash point; • Auto-ignition temperature;
• Evaporation rate; • Decompositiontemperature;and
• Flammability (solid, gas); • Viscosity.
TheSDSmaynotcontaineveryitemontheabovelistbecauseinformationmaynotberelevant
oris notavailable.Whenthisoccurs,a notationtothateffectmustbe madeforthatchemical
property. Manufacturersmayalsoaddotherrelevantproperties,suchasthedustdeflagration
index (Kst) for combustible dust, used to evaluate a dust’s explosive potential.
5
Section 10: Stability and Reactivity
This section describes the reactivity hazards of the chemical and the chemical stability
information. This section is broken into three parts: reactivity, chemical stability, and other.
The required information consists of:
Reactivity
• Descriptionofthespecifictestdataforthechemical(s).Thisdatacanbefora classorfamily
ofthechemicalifsuchdataadequatelyrepresenttheanticipatedhazardofthechemical(s),
where available.
Chemical stability
• Indication of whether the chemical is stable or unstable under normal ambient temperature
and conditions while in storage and being handled.
• Description of any stabilizers that may be needed to maintain chemical stability.
• Indication of any safety issues that may arise should the product
change in physical appearance.
Other
• Indication of the possibility of hazardous reactions, including a statement whether the chemical
will react or polymerize, which could release excess pressure or heat, or create other hazardous
conditions. Also,a descriptionoftheconditionsunderwhichhazardousreactionsmayoccur.
• List of all conditions that should be avoided (e.g., static discharge, shock,
vibrations, or environmental conditions that may lead to hazardous conditions).
• List of all classes of incompatible materials (e.g., classes of chemicals or specific
substances) with which the chemical could react to produce a hazardous situation.
• List of any known or anticipated hazardous decomposition products that could be
produced becauseofuse,storage,orheating. (Hazardouscombustionproductsshouldalso
beincluded in Section 5 (Fire-Fighting Measures) of the MSDS.)
Section 11: Toxicological Information
Thissectionidentifiestoxicologicalandhealtheffectsinformationorindicatesthatsuchdata
are not available. The required information consists of:
• Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact).
The MSDS should indicate if the information is unknown.
• Description of the delayed, immediate, or chronic effects from short- and long-term exposure.
• The numerical measures of toxicity (e.g., acute toxicity estimates such as the LD50 (median lethal
dose)) - the estimated amount [of a substance] expected to kill 50% of test animals in a
single dose.
• Description of the symptoms. This description includes the symptoms associated with exposure
tothechemicalincludingsymptomsfromthelowesttothemostsevereexposure.
• Indication of whether the chemical is listed in the National Toxicology Program (NTP)
ReportonCarcinogens(latestedition)orhasbeenfoundtobeapotentialcarcinogeninthe
International Agency for Research on Cancer (IARC) Monographs (latest editions) or found
to be a potential carcinogen by OSHA.
6
Section 12: Ecological Information (non-mandatory)
This section provides information to evaluate the environmental impact of the chemical(s) if it
were released to the environment. The information may include:
• Data from toxicity tests performed on aquatic and/or terrestrial organisms, where
available (e.g., acute or chronic aquatic toxicity data for fish, algae, crustaceans, and other
plants; toxicity data on birds, bees, plants).
• Whether there is a potential for the chemical to persist and degrade in the
environment either through biodegradation or other processes, such as oxidationor
hydrolysis.
• Results of tests of bioaccumulation potential, making reference to the octanol-
water partition coefficient (Kow) and the bioconcentration factor (BCF), where
available.
• The potential for a substance to move from the soil to the groundwater (indicate
results from adsorption studies or leaching studies).
• Other adverse effects (e.g., environmental fate, ozone layer depletion potential,
photochemical ozonecreationpotential,endocrinedisruptingpotential,and/orglobal
warmingpotential).
Section 13: Disposal Considerations (non-mandatory)
Thissectionprovidesguidanceonproperdisposalpractices,recyclingorreclamationofthe
chemical(s)oritscontainer,andsafehandlingpractices.Tominimizeexposure,thissection
should also refer the reader to Section 8 (Exposure Controls/Personal Protection) of the SDS.
The information may include:
• Description of appropriate disposal containers to use.
• Recommendations of appropriate disposal methods to employ.
• Description of the physical and chemical properties that may affect disposal activities.
• Language discouraging sewagedisposal.
• Any special precautions for landfills or incineration activities.
Section 14: Transport Information (non-mandatory)
Thissectionprovidesguidanceonclassificationinformationforshippingandtransportingof
hazardous chemical(s) by road, air, rail, or sea. The information may include:
• UN number (i.e., four-figure identification number of the substance).
• UN proper shipping name.
• Transport hazard class(es).
• Packing group number, if applicable, based on the degree of hazard.
• Environmental hazards (e.g., identify if it is a marine pollutant according to the
International Maritime Dangerous Goods Code (IMDG Code)).
• Guidance on transport in bulk (according to Annex II of MARPOL 73/783 and the
International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicalsin Bulk (International Bulk Chemical Code (IBC Code)).
• Any special precautions which an employee should be aware of or needs to comply
with, in connection with transport or conveyance either within or outside their premises
(indicate when information is not available).
7
Section 15: Regulatory Information (non-mandatory)
This section identifies the safety, health, and environmental regulations specific for the product
that is not indicated anywhere else on the MSDS. The information may include:
• Any national and/or regional regulatory information of the chemical or mixtures (including any OSHA,
Department of Transportation, Environmental Protection Agency, or Consumer Product Safety
Commissionregulations).
Section 16: Other Information
ThissectionindicateswhentheMSDS waspreparedor whenthelastknownrevisionwasmade.
TheMSDSmayalsostatewherethechangeshavebeenmadeto the previousversion. Youmay
wishtocontactthesupplierforanexplanationofthechanges.Otherusefulinformationalsomay
be includedhere.
For & Behalf of Appello Interiors LLC
Madan lal
Manager