06-10-2024

9610WJA801013240018 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two surface OABC and OCDE lies in the plane of xy and yz as shown in the figure. A charged

particle 'q' lies in the space at a point P. if

coordinates of 'P' is (a − Δr, a − Δr, Δr) and a >> Δr, then flux passing through surface OABC is
(A)

coordinates of 'P' is (a − Δr, a − Δr, Δr) and a >> Δr, then flux passing through surface OCDE
(B)
is
coordinates of 'P' is (a + Δr, a + Δr, −Δr) and a >> Δr, then flux passing through surface
(C)
OABC is
coordinates of 'P' is (a + Δr, a + Δr, −Δr) and a >> Δr, then flux passing through surface OCDE
(D)
is

2) In a kundt's tube experiment metallic rod of length 1m is clamped from the distance of 25 cm
from one end. If distance between heap of powder 50 cm and speed of sound in air is 330 m/s select

correct statement(s) :-

(A) Frequency in which tube is oscillating is 1320 Hz

(B) Frequency in which tube is oscillating is 330 Hz
(C) Velocity of wave in metallic rod is 330 m/s
(D) Velocity of wave in metallic rod is 1320 m/s

3) In a standing wave on a string.

(A) In one time period all the particles are simulataneously at rest twice.
(B) All the particles must be at their positive extremes simultaneously once in one time period.
(C) All the particles may be at their positve extremes simultaneously once in a time period
(D) All the particles are never at rest simultaneously.

4) A charged particle moves in a gravity-free space without change in velocity. Which of the
following is/are possible ?

(A) E = 0, B = 0
(B) E = 0, B 0
(C) E 0, B = 0
(D) E 0, B 0

5) A charged particle moving in x-y plane enters a region of uniform magnetic field of intensity
at P(0, 0) with velocity and leaves the magnetic field at Q(a, b) with velocity

. Choose the correct statement(s)

(A) The particle can't be positron

(B) Deviation suffered by the particle as it moves from P to Q equals 60°
(C) =b
(D)

6) Two concentric shells A and B have radii R and 2R, charges qA and qB and potentials 2V and
respectively. Now, the shell B is earthed and the new charges on them become q'A and q'B. Then

(A)
(B)

(C)
Potential difference between A and B after earthing becomes

(D)
Potential difference between A and B after earthing becomes

7) The capacitance of a parallel plate capacitor is C when the region between the plate has air. This
region is now filled with a dielectric slab of dielectric constant k. The capacitor is connected to a cell
of emf E, and the slab is taken out

(A) charge CE(k – 1) flows through the cell

(B) energy E2C(k – 1) is absorbed by the cell.
(C) the energy stored in the capacitor is reduced by E2C(k – 1)

(D)
the external agent has to do E2C(k – 1) amount of work to take the slab out.

8) A point object is placed at 30 cm from a convex glass lens of focal length 20 cm. The
final image of object will be formed at infinity if

(A) Another concave lens of focal length 60 cm is placed in contact with the previous lens
(B) Another convex lens of focal length 60 cm is placed at a distance of 30 cm from the first lens
(C) The whole system is immersed in a liquid of refractive index 4/3
(D) The whole system is immersed in a liquid of refractive index 9/8

SECTION-I (ii)

Common Content for Question No. 1 to 2

Comprehension-2
A conducting ring of radius a is rotated about a point O on its periphery as shown in the figure in a
plane perpendicular to uniform magnetic field B which exists everywhere. The rotational velocity is

ω.

1) Choose the correct statemnt(s) related to the potential of the points P, Q and R

(A) VP – VO > 0 and VR–VO < 0

(B) VP = VR>VO
(C) VO> VP = VQ
(D) None of these

2) Choose the correct statement(s) related to the magnitude of potential differences

(A)
VP–VO =

(B)
VP–VQ =
2
(C) VQ–VO = 2Bωa
2
(D) VP – VR = 2Bωa

Common Content for Question No. 3 to 4

Column I represents the standing waves in air columns and string. Column II represents frequency
of the note. Match the column-I with column-II. [v = velocity of the sound in the medium]

Column -I Column -II

(I) Second harmonic for the tube open at both ends

(P)

(II) Fundamental frequency for the tube closed at

one end (Q)

(III) First overtone for the tube closed at one end

(R)

(IV) Fundamental frequency for the string fixed at

both ends (S)

(T)

(U)

3) Which of the following is incorrect combination.

(A) (I) → (S)

(B) (II) → (U)
(C) (III) → (R)
(D) (IV) → (Q)

4) Which of the following is only correct combination.

(A) (I) → (P)

(B) (II) → (S)
(C) (III) → (R)
(D) (IV) → (T)

SECTION-III
1) Find the resistor in which maximum heat will be produced.

2) Due to polarization of a dielectric slab filling the gap between capacitor plates the charge induced
is 80% that of the charge appearing on the capacitor plate. The dielectric constant of the slab
material is

3) In the circuit power factor of box is 0.5 and power factor of circuit is .If current leads the

voltage; the value of resistance (Ω) of resistor inside the box will be :

4) A small pin of size 5mm is placed along principal axis of a convex lens of focal length 6cm at a
distance 11cm from the lens. The size of image of pin is x mm.

Find the value of

5) A satellite of the sun is in a circular orbit around the sun, midway between the sun and the earth.
Then the acceleration of the satellite is x times the acceleration of the earth. find x.

6) A cylindrical rod of mass m, radius r and length L, rests on two rails (see figure). A uniform
magnetic field B acts vertically downwards. The rod carries a current i and can roll along the rails
without slipping. If the rod starts from rest, Calculate its linear speed as a function of its linear

displacement. If your answer is fill value P + Q.

7) A solid conducting sphere of radius 'a' having charge q is surrounded by a concentric conducting
spherical shell of inner radius 2a and outer radius 3a as shown in figure. If the amount of heat
produced when switch is closed is . Fill the value of α.

8) The nth harmonic on a taut string has a frequency of 720 Hz. The next higher harmonic has a
frequency of 840 Hz. What is the value of n ?

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following reaction(s) takes place in presence of NaOH?

(A) CH3CH2CH2OH → CH3CH = CH2 +H2O

(B) CH3CHO + CH3CHO → CH3CH = CHCHO +H2O

(C)

(D) CH3CONH2 ⎯→ CH3CN + H2O

2) High spin complex is/are

2+
(A) [Fe(H2O)6]
3–
(B) [FeF6]
3–
(C) [Fe(CN)6]
3+
(D) [Co(H2O)6]

3)
Choose correct option is/are
(A)

(B) Number stereo isomers in P is 4

(C) Number of stereo isomer in P is 3

(D)

4) Select correct statement/s for structure

(A) β–D–fructofuranose
(B) α–D–fructofuranose
(C) is a reducing sugar
(D) is a non-reducing sugar

5) Many carbonyl compounds undergo reversible hydration in aqueous solution as

R2C = O + H2O R2C(OH)2
For which of the carbonyl compounds, the above equilibrium is shifted towards the product at 25°C.

(A)

(B)

(C) Cl3CCHO

(D)

6) Select the correct statements about Ag+/Ag electrode

(A)
 Addition of CN– in Ag+ / Ag electrode shows a decrease in the value of
(B)

(C) Addition of CN– in Ag+ / Ag electrode shows a increase in the value of

(D) Addition of CN– in Ag+ / Ag electrode shows a decrease in and an increase in

7) Which of the following statement(s) is/are correct?

(A) The coordination number of each type of ions in CsCl crystal is 8.

(B) A metal that crystallizes in BCC structure has a coordination number of 12
(C) A unit cell of an ionic crystal shares some of its ions with other unit cells
(D) The length of the unit cell in NaCl is 552 pm.

8) Mixture of Ph-CHO & HCHO is treated with NaOH then Cannizzaro reaction involves

(A) Oxidation of HCHO

(B) Hydride transfer from HCHO
(C) Oxidation of Ph – CHO
(D) Reduction of Ph – CHO

SECTION-I (ii)

Common Content for Question No. 1 to 2

An aromatic tertiary alcohol upon acid catalysed dehydration gives a product (I).
Reductive ozonolysis of (I) forms compounds (J) and (K). Compound (J) upon reaction with NaOH
gives benzyl alcohol and compound (L), whereas (K) on heating with NaOH gives only (M) Answer
the following questions on the basis of the above write up.

1) The structure of the compound (I) is:

(A)

(B)

(C) PhCH = CH – CH3

(D) PhCH2CH = CH(Ph)

Common Content for Question No. 2 to 3

An aromatic tertiary alcohol upon acid catalysed dehydration gives a product (I).
Reductive ozonolysis of (I) forms compounds (J) and (K). Compound (J) upon reaction with NaOH
gives benzyl alcohol and compound (L), whereas (K) on heating with NaOH gives only (M) Answer
the following questions on the basis of the above write up.

2) The structure of compounds J, K and L respectively are:

(A) PhCHO, PhCH2CHO and PhCH2COONa

(B) PhCHO, PhCOCH3 and PhCOONa
(C) PhCHO, PhCOCH3 and PhCH2COONa
(D) PhCHO, PhCOPh and PhCOONa

Common Content for Question No. 3 to 4

3) In the above sequence of reactions compound B is:

(A)

(B)

(C)

(D)

Common Content for Question No. 4 to 5

A triatomic linear (neglect vibration degree of freedom) ideal gas of two mole is taken through a
reversible process starting from ‘A’ as shown in figure

The volume ratio = 4 and if the temperature at A is –73°C

4) Work done by the gas in AB process is

(A) 3.32 kJ
(B) - 3.32 kJ
(C) 9.97 kJ
(D) - 9.97 kJ

SECTION-III

1)
How many of ‘C’ atoms are there in one molecule of the product ?

2) In cannizaro reaction, in the presence of 40% base, the order of reaction with respect to aldehyde
is

3) Number of possible product in the given reaction below is

4)
No. of π bonds present in F

5) At 48°C, the vapour pressure of pure CS2 is 850 torr. A solution of 2.0 g of sulphur in 100 g of CS2
has a vapour pressure 844.9 torr. Determine the atomicity of sulphur molecule. (Nearest integer)

6) From the following the number of complexes is expected to show optical isomerism is/are:
(1) [Ni(en)3]2+ (2) [Fe(ox)Cl4]3–
(3) [Cr(NH3)3Cl2(NO3)] (4) [Zn(NO3)2(NH3)(CO)]

7) 4 mol of a mixture containing one mol each of LiNO3, NaNO3, Ca(NO3)2 and Mg(NO3)2 is
decomposed by strongly heating. The total number of moles of NO2(g) evolved is (assuming complete
decomposition of all the salts)

8)
Number of "PRIMARY CARBON" atoms in product 's'_______ ?

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let A and B be two square matrices of order n satisfying A + BAT = I and B + ABT = I and O is a
null matrix and I is the identity matrix of order n, then identify the correct statement(s)

(A) A4 – 2A2 + A = O
(B) A4 – 2A2 – A = O
(C) A2 + B = I
(D) B4 – 2B2 – B = O

2) If then

(A)
(B)
(C)
(D)

3) Let X and Y be two arbitrary non-zero, skew-symmetric matrices and Z be an arbitrary , non-
zero, symmetric matrix. Then which of the following matrices is (are) skew symmetric?

(A) Y3Z4 – Z4Y3

(B) X44 + Y44
(C) X4Z3 – Z3X4
(D) X23 + Y23

4) equals

(A)

(B)

(C)

(D)

5) If where a and b are prime numbers then -

(A) a = 2
(B) a = 3
(C) b = 3
(D) b = 2

6) Given that and are two unit vectors such that angle between and is . If be a
vector in the plane of and , such that and then

(A) λ = 2
(B) sum of values of μ = – 1
(C) product of all possible values of μ = –12
(D) Number of distinct values of μ is three.

7)

Given then which of the following is/are true ?

(A) ƒ(x) is concave upwards in its domain.

(B) ƒ(x) has exactly two asymptotes.
(C) ƒ(x) has no point of inflection.
(D)

8) A solution curve of the differential equation (x2 + xy + 4x + 2y + 4) , passes

through the point (1,3). Then the solution curve-

(A) intersects y = x + 2 exactly at one point

(B) intersects y = x + 2 exactly at two points
(C) intersects y = (x + 2)2
(D) does NOT intersect y = (x + 3)2

SECTION-I (ii)

Common Content for Question No. 1 to 2

Let y = ƒ(x) be a fourth degree algebraic polynomial function such that

(i)

(ii) It cuts y-axis at a point where slope of normal is

(iii) Tangent at x = 2 is parallel to y = 8x + 1.
Consider y = g(x) be a quadratic curve touching and cutting y = ƒ(x) on x-axis and y-axis
respectively.

1) The angle of intersection between y = ƒ(x) & y = g(x) at point where they cut y-axis is
(A)

(B)

(C)

(D)

2) The value of is

(A)

(B)

(C)

(D) 4

Common Content for Question No. 3 to 4

If α(a) and β(a) be the roots of equation such that α(a) > β(a).

(a2 + a – 5)x2 – (a2 + a – 5) x – (3a2 + 2a + 10) = 0

On the basis of above information, answer the following questions :

3) The value of α(a) is

(A) 1
(B) 2
(C) 3
(D) 4

4)

The value of β(a) is

(A) –1
(B) 0
(C) 1
(D) 2

SECTION-III

1) The number of solution of equation , lying in [0, 2π], is

2) Find the value of 2(4cos10° – cot10°)2

3) The number of solutions of in [0, 4π], is

4) If , then value of is equal to

(Where a, b, c are coprime numbers & [.] denotes greatest integer function)

5) If solution of the differential equation is ln2(y – 2x) = kx + 1, with initial

condition is y(0) = e, then k is :

6) If , then the value of equals

7) Let 3 vector & are such that & .

If , then value of is equal to

8) Let and be two vectors such that , and . For some α, β ∈ R,

. If and the vector makes 'θ' angle with both and , then
2
[4cos θ] is _____ (where [.] represents G.I.F.)
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8
A. A,B,C,D B,C A,C A,B,D B A,B,D A,B,D A,D

SECTION-I (ii)

Q. 9 10 11 12
A. B C B C

SECTION-III

Q. 13 14 15 16 17 18 19 20
A. 4 5 5 8 4 7 6 6

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 21 22 23 24 25 26 27 28
A. B,C A,B A,B A,C A,B,C A,B,C A,C,D A,B,D

SECTION-I (ii)

Q. 29 30 31 32
A. B B B C

SECTION-III

Q. 33 34 35 36 37 38 39 40
A. 5 2 3 3 8 1 5 3

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 41 42 43 44 45 46 47 48
A. A,C A,B,C C,D A,C A,C A,B,C B,C A,D

SECTION-I (ii)

Q. 49 50 51 52
A. B B C A
 SECTION-III

Q. 53 54 55 56 57 58 59 60
A. 3 6 4 5 2 2 4 1
 SOLUTIONS

PART-1 : PHYSICS

1) Using symmetry if charged particle lies at P1 then ϕOCDE =

and
If the charge particle lies at P2 then

and

2)

For sound wave in copper =

Now for sound wave in air

λair = 1m
speed of sound in air
vair = λairf
⇒ 330 = 1 × f

speed of sound in metallic rod

vm = λmf
= 1× 330
= 330 m/s

3)

(i) In one time period all the particles are simulataneously at rest twice.
(ii) All the particles may be at their positve extremes simultaneously once in a time period

4)
Fnet = qE + qvB sin θ
(i) E = 0, B = 0 then F = 0
(ii) E = 0 but angle between B & v O° or 180° then Fnet = 0
(iii) then
(iv) a
But if they are equal & opposite then Fnet = 0

5)

θ = 60

6)

Potential of A:

Potential of B :

Solving both,
qA = V R
qB = 2V R

When shell B is earthed, V'B = 0

Potential difference between A and B : VA' − VB' = VA' − VB = 2V

since VB'= 0
7)

8) Final image is formed at infinity if the combined focal length of the two lenses (in contact)

becomes 30 cm or
i.e., when another concave lens of focal length 60 cm is kept in contact with the first lens.
Similarly, let be the refractive index of a liquid in which focal length of the given lens
becomes 30 cm. Then

From equations, (1) and (2), we get

9) Potential is maximum at Q. Potential at P and R is equal and minimum at O. (as length of

rod increase e.m.f. increase)
So VP = VR > VO
VQ – VP = VP – VO
Because net e.m.f. is zero.

10) Maximum potential at Q. O and Q' act as a rod.

VQ – VO = ⇒ r = 2a

14)

15)

Solving these two equations

R = 5Ω
16)
17)

18) v = \({\left[ {\dfrac{{4Bi\,{\text {l}}\,x}}{{3m}}} \right]^{1/2}}\)

19)
 So, Ui – Uf = H =

20) nf0 = 720

f0 = 120, n = 6
(n + 1)f0 = 840

PART-2 : CHEMISTRY

21) Aldol &I hydrolysis

22) A and B are high spin complex [NO pairing] C and D are low spin complex.

23)
Number of stereo isomers in P is 4.

24) This is β-D- fructofuranose and a reducing sugar

25) In (A) angle strain is relieved. B & C have strong electron withdrawing groups, so
forms hydrates

26)

27) A metal that crystallizes in BCC structure has a coordination number of 8.

28)

More reactive aldehyde will get oxidised

29)
This is required aromatic tertiary alcohol

30)

J, K and L respectively are: PhCHO, PhCOCH3 and PhCOONa

31)

32) W = –P.ΔV = –nRΔT = – 2 × 8.314 × 600 = – 9.97 kJ

33)

34) Fact

35)

36)
 37)

38) [M (AA)3] → show optical isomerism

While in others plane of symmetry is possible.

39) 2LiNO3 Li2O + 2NO2 + O2

1 mol of LiNO3 will produce NO2 = 1
2Mg (NO3)2 2MgO + 4NO2 + O2
1 mol of Mg(NO3)2 will produce NO2 = 2
2Ca(NO3)2 2CaO + 4NO2 + O2
1 mol of Ca(NO3)2 will produce NO2 = 2
2NaNO3 2NaNO2 + O2
Total number of moles of NO2 produced = 5

40)

PART-3 : MATHEMATICS

41) A + BAT = I ...(1)

T
and B + AB = I ...(2)
A + BAT = I ⇒ AT + ABT = I
⇒ AT = B and BT = A
from (1) A + B2 = I and B + A2 = I
A + (I – A2)2 = I ⇒ and A4 – 2A2 + A = 0
similarly B4 – 2B2 + B = 0

42)

43) X′ = –X, Y′ = –Y, Z′ = Z

P = X4Z3 – Z3X4
P′ = Z3X4 – X4Z3 = –P
& Q = X23 + Y23
Q′ = (–X)23 + (–Y)23 = –Q

44)

I=

I=

put ⇒

I=

Or

45) x = t4
dx = 4t3dt
46) Given

...(1)
comparing with
we have λ = 2 hence (A) is correct.
⇒ from equation (1)
[take dot with in (1)]

...(2)

{using and angle between and

}
from equation (1), again
[take dot with in (1)]

...(3)

{using and angle between and }

again from equation (1) dot with

from equation (2) and (3) (using )

∴ sum of values of μ = –1 and product of values of μ = –12

∴ (B) and (C) are also correct.

48)

+ c , c = 1 + ln3 since y(1) = 3

For y = x + 2, ln ⇒ x = 1 only
For y = (x + 2 )2
Hence no solution

49) Let ƒ(x) = (x – 1)2(ax2 + bx + c)

⇒ a + b + c = 2 & ƒ'(c) = –8, ƒ'(2) = 8
⇒ c = 3, a = 1, b = –2
⇒ ƒ(x) = (x – 1)2(x2 – 2x + 3)
g(x) = 3(x – 1)2 ⇒ g'(0) = –6, ƒ'(0) = –8
Angle of intersection

50) f(x) = (x – 1)2 (x2 – 2x + 3)

51)

So, x2 – 2x – 3 = 0
⇒ x1 = 3, x2 = –1
α(a) = 3, β(a) –1

52)

So, x2 – 2x – 3 = 0
⇒ x1 = 3, x2 = –1
α(a) = 3, β(a) –1
53) Given α + β + γ = 0
⇒ α3 + β3 + γ3 = 3αβγ

⇒
⇒ sinx = 0 or sin2x = sin2x – 1
⇒ sinx = 0

54) 4cos10° – cot10° =

55)

56) tan–1(1 + n + n2) = – cot–1(1 + n + n2)

∴ a = 201, b = 4, c = 101

57) Let ℓn(y – 2x) = z

so given equation is
Initial condition is

⇒ 1 = 2c
So, ℓn2(y – 2x) = 2x + 1
⇒k=2

58)

59)

60)

⇒ 2 × (2019)2 = (2019)2 2cos2θ + (2019)2 2cos2θ + (2019)2

⇒ 2 = 2cos2θ + 2cos2θ + 1
⇒ 4cos2θ = 1