DPP - Daily Practice Problems

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Start Time : End Time :

SYLLABUS :
CHEMISTRY (1
Thermodynamics-1 (First LawofThermodynamics, Thermochemical Equations)
0]
Max. Marks : 120 Time : 60 min.
GENERAL INSTRUCTIONS
•
The Daily Practice Problem Sheet contains 30 MCQ's. For each question only one option is correct. Darken the correct drcle/
bubble in the Response Grid provided on each page.
•
You have to evaluate your Response Grids yourself with the help of solution booklet.
Each correct answer will get you 4 marks and 1 mark shall be deduced for each incorrect answer. No mark will be given/ deducted
if no bubble is filled. Keep a timer in front of you and stop immediately at the end of 60 min.
•

• The sheet follows a particular syllabus. Do not attempt the sheet before you have completed your preparation for that syllabus.
Refer syllabus sheet in the starting of the book for the syllabus of all the DPP sheets.
• After completing the sheet check your answers with the solution booklet and complete the Result Grid. Finally spend time to
analyse your performance and revise the areas which emerge out as weak in your evaluation.
Q.3 �Ht for Al203 is-1670 kJ. Calculate the enthalpy change
for the reaction : 4AI + 3 02 � 2AI203
DIRECTIONS (Q.l-Q.21) : There are 21 multi(>le choice
questions. Each question has 4 choices (a), (b), (c) and (d),
out of which ONLY ONE choice is correct. (a) -2340 kJ (b) -3340 kJ
(c) -1340 kJ (d) -4320 kJ
Q.l What is true regarding complete combustion of gaseous
isobutane? Q.4 The sp ecific heats of iodine vapours and solid are 0.031
and 0.055 Callg respectively. If heat of sublimation of
(a) �H = �E (b) �H>�
iodine is 24 Cal/g at 200°C, what is its value at 250°C ?
(c) �H = �E = 0 (d) �H<�E
(a) 22.8 Cal/g (b) 1 1 .2 Callg
Q.2 How much heat is produced when 4.50 g methane gas is
24.4 Cal/g
(c) 12.8 Cal/g (d)
burnt i n a constant pressure system?
Q.5
:
CH4 + 202 � C02 + 2Hp ; �H =- 802 kJ
Calculate the heat of neutralization by mixing 200 ml of
O.lM �S04 and 200 ml of0.2 M KOH if heat generated
Given
(a) 225.6 kJ (b) 125.6 kJ by the mixing is 2.3 kJ.
(c) 175.6 kJ (d) 325.6 kJ (a) 17.5 kJ (b) 42.5 kJ (c) 57.5 kJ (d) 34.5 kJ

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Q.6 A system does I 00 J ofwork on surroundings by absorbing Q.12 For a gaseous reaction : 2Aig) + 5B2(g) � 2A2B5(g) at
150 J of heat. Calculate the change in internal energy. 27°C the heat change at constant pressure is fmmd to be
(a) 100 J (b) 50 J (c) 25 J (d) 150 J -501603. Calculate the value of internal energy change
(�E). Given that R = 8.3 1 4 J/K mol.
Q.7 A gas absorbs 200 J of heat and expands against the external
(a) -34689 J (b) -37689 J
(c) -27689 J
pressure of 1 . 5 atm from a volume of 0.5 litre to 1 . 0 litre,
Calculate tl1e change in int-ernal energy. (d) -38689 J
(a) 124.25 J (b) 224 J (c) 1 1 4 J (d) 154 J Q.13 Calculate the work performed when 2 moles of hydrogen
expands isothermally and reversibly at 25°C from 1 5 to
Q.8 Heat of reaction for
50 litres.
C6H 2 06 (s) + 602 (g) � 6C02 (g) + 6�0 (1)
1 (a) -1436 calories (b) - 1 3 1 8 calories
at constant pressure is - 6 5 1 kcal at l7°C. Calculate the
(c) - 1 2 1 5 calories (d) - 1 1 72 calories
heat of reaction at constant volume at l7°C-
Q.14 Which orne of the following equations does not correctly
(a) - 554.5 kcal (b) - 654.5 kcal represent the first law of thermodynamics for the given
(c) - 354.5 kcal (d) - 1 54.5 kcal process?
Q.9 A sample of gas is compressed by an average pressure of (a) isothermal process : q =-w
0.50 atmosphere so as to decrease its voltillle from 400 (b) cyclic process : q = - w
cm3 to 200 cm3. During the process 8.00 J of heat flows (c) expansion of gas into vacuum : �U = q
out to surroundings. Calculate the change in internal energy
(d) adiabatic process : �V = - w
of the system.
Q.lS From the following data of�H ofthe following reactions,
(a) 2.13 J (b) 4.17 J (c) 1.13 J (d) 3.52 J
C(s)+ Y2 02 (g) �co (g) ; fl.H=-l l O kJ
Q.lOThe heat of combustion of napthalene (C 0H8(s))
1 and C (s) + �O (g) �co (g) + H2 (g) ;�H= 132 kJ.
at constant volume was measured to be- 5 1 33 kJ mol-1 at
298 K. Calculate the value of enthalpy charnge Calculate the mole composition of the mixture of oxygen
and steam on being passed over coke at l 273K, keeping
(Given R = 8.314 JK- 1 mol- 1 ).
the reaction temperature constant.
(a) - 3 1 3 7955.14 Joule (b) - 5 1 37955 . 1 4 Joule (a) 0.3 : I (b) 2.1 : l (c) 0.6 : l (d) l : I
(c) - 4 1 27955. 1 4 Joule (d) - 3247955.14 Joule Q. 16 200 ml ofKOH and 200 ml ofHN0 ofsame molarity are
3
Q.ll A cooking gas cylinder i s assumed to contain 1 1 .2kg mixed together and liberated 3.426 kJ of heat. Determine
isobutane. The combustion of isobutane is given by- the molarity of each solution.
(a) 0. 1 mole (b) 1 . 3 mole (c) 0.7 mole(d) 0.3 mole
C4H1 0 (g) + (:)
1
02 (g) � 4C02 (g) + 5�0(1); Q.17 The work done in ergs for the reversible expansion of one
mole ofan ideal gas from a volume of 1 0 litres to 20 litres
fl.H = - 2658 kJ at 25°C is
If a family needs 15000 kJ of energy per day for cooking, (a) 2.303 x 298 x 0.082 log 2
how long would the cylinder last? (b) 298 X 107 X 8 . 3 1 X 2.303 log 2
[1 mole of isobutane = 2658 kJ] (c) 2.303 x 298 x 0.082 log 0.5
(a) 22 days (b) 28 days (c) 32 days (d) 34 days (d) 8.31 x l07x 298 - 2 .303 log 0.5

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Q.18 For the reaction Q.23 Choose tlhe correct options for the process at 25°C of
CH3COOH(l) • 20 2 (g) � 2C02 (g)• 2H20(1) at 25°C dissolving 1.00 mol ofKCl in large excess of water.
t.f H0 [K+(aq)] = - 251.2 kJ mol- 1
and I atm. pressure, H • • 874kJ. Then the change in
�f H0 [CI- (aq)] = 167.08 kJ mol-1
•

internal energy (• E) is
t.rH0 = 437.6 kJ moi-1

+
[KCI]
(a) - 874 kJ
-

(b) - 871.53 kJ
(c) - 876.47 kJ (d) 874 kJ (I) t.�0 for the reaction is + 19.3 kJ moi- 1
Q.19 One mole of an ideal gas is allowed to expand reversibly (2) t.rH0 for the reaction is + 12.3 kJ moi- 1
and adiabatically from a temperature of27°C. If the work (3) The process does not represent an ionisation reaction
done during the process is 3 kJ, then final il:emperature of
(4) The process represent an ionisation reaction
=
the gas is (Cv 20 J I K)

( dH) + ( dE)
(a) 100 K (b) 150 K (c) 195 K (d) 255 K
Q.24 Which statement is incorrect -
Q.20 In a closed insulated container, a liquid is stirred with a
paddle to increase its temperature. In this process, which
of the following is true ?
(2)
dT dT
p v
-
_
R

(a) • E• W • Q • 0 (b) • E • O,Q• W • 0

(c) • E • W • 0, Q • 0 (d) • E · Q • O, W • 0
Q.21 One mole of an ideal gas is allowed to expand freely and DIRECTIONS (Q.25-Q.27) : Read the passage given below
adiabatically into vacuum until its volume has doubled. A and answer the questions that follows :
statement which is not true concerning this expression is
(b) A student performed a number of experiments on
(a) • H• 0 • S 0
thermodynamics. In one experiment, he took a closed vessel in
•

(c) • E• 0 (d) W• 0 which he dissolved 28 g of Fe in HCI at 27°C. In another

experiment, he dissolved the same amount ofiron but in an open
DIRECTIONS (Q.22-Q.24) : I n the following questions,
vessel. However, he compressed the gas to l 0 atm pressure at
more than one of the answers given are correct. Select the
27°C and then again allowed to expand it isothermally and
correct answen and mark it according to the following
reversibly until the pressure fell down to 1 atm.
codes:
Q.25 In the first experiment, the work done by the system is
Codes :
(a) 1246 J (b) zero
(a) 1 , 2 and 3 are correct
(b) I and 2 are correct (c) 2492 J (d) 1145 J
(c) 2 and 4 are correct Q.26ln the second experiment, the work done by the system, if
(d) l and 3 are correct the gas were not condensed, would have been nearly
Q.22 Which of the following processes have positive value for (a) 1246 J (b) zero
t.H? (c) 2492 J (d) 1 1 45 J
( 1) �(g) --+ 2H(g)

+
(2) H+(aq) + OH- (aq) � �0 (I) Q.27 The work done by the compressed gas would be nearly
(3) H(g) --+ W (g) e- (a) 1250 J (b) 2500 J
(4) H20(!)--+ �O(s) (c) 4000 J (d) 5000 J

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DIRECTIONS (Q. 28-Q.30) : Each of these questions contains Q.28 Statement 1 : T, P and V are state variables or state
two statements: Statement-! (Assertion) and Statement-2 functions.
(Reason). Each ofthese (]uestions has four alternative choices, Statement 2 :Their values depends on the state of the
system and how it is reached.
only one of which is the correct answer. You have to select the
correct choice. Q.29 Statement 1 : For an isothermal reversible process Q =­
w i.e. work done by the system equals the heat absorbed by
(a) Statement-! is Tme, Statement-2 is True; Statement-2 is a the system.
correct explanation for Statement-1. Statement 2 : Enthalpy change (• H) is zero for
(b) Satement-!
t is True, Statement-2 is True; Statement-2 isNOT isothermal process.
a correct explanation for Statement-! . Q.30 Statement 1 : Zeroth law can also be termed as law of
Statement -I is False, Statement-2 isTrue. thermal equilibrium.
(c)
Statement 2 : Two objects in thermal equilibrium with
(d) Statement - I is Tme, Statement-2 is False. the third one, are in thermal equilibrium with each other.

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DAILY P RACTICE PROBLEM SH E ET 10 - CHEMISTRY

Tota l Questions 30 Tota l Marks 120
Attempted Correct
Incorrect Net Score
Cut-off Score 36 Qual ifying Score 56
Success Gap = Net Score - Qual ifying Score
N et Score = {Correct x 4} - {I ncorrect x 1 }

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22 1------ DPP/ C ( 10) w
(1 0)
DAILY PRACTICE C H E M I STRY
PROBLEMS SOLUT IONS
(1) (d)
C4H10(g) + 6.502 (g)� 4C02(g) + 5l·Ip0) .". �E=-651 103 -6 2 290=-654480CaJ
X X X

�n = [4-7.5] =-3.5 =-654.5 kcal 3

�H=�E+�n�T (9) (a) Here�V=200-400=-200cm
:. �H<�E We know 1 Litre= 1000 cm3
(2) �
(a) Given CH4 + 202 C02 + 2�0; �H =-802 kJ ::::> �V=-0.2L.
·:
16 g CH4 on burning produces heat= 802 kJ Extemal pressure (P) =0.50
:. 4.5 g CH4 on burning produces heat Work done=-P�V = + 0.50 (0.2) =+ 0.1 atm L.
802x4.5 =225.6kJ and ! litre atmosphere= 101.3 Joule
16 :. W=+ 10.13 Joule
(3)
3 --+
(b) Given 2AI + 2 02 Al203 ; �H =- I 670 kJ
According to F.L.O.T.
q = �E-W �E = q + W
then
Multiplying it by2. Given q =-8.00 J
Then 4Al + 302 2Al203
� ::::> � =-8+ l0.13=2.13Joule
�H =2 (-1670)=-3340kJ
X (10) (b) The combustion reaction ofnaptbalene.
(4) (a) 12 (vapour) ; �H = 24 CaVg at 200oC
Iz (solid) � C10H8(s)+ 1202(g)--+ IOC02Cg) +4Hz0(1);
�cp = cp ofproduct-cp ofreactant �=-5133kJ
�cP=0.031-o.oss =-0.024CaVg �n = 0-12 =-2 mol.
I
As � -�H1 = �CP(T2-T1 ) Now applying the relation.
:. ��-24=-0.024(523-473) �H=�E+(�n)3 gRT
:. �Hz= 22.8 CaVg =-5]33 10 + (-2){8. 314)(298)
X
x
(5) (c) Meq ofHzS04 =200 0.1 x 2 =40 =-5133000J-4955.14J
Meq KOH =200 0.2=40X =-5137955.14Joule
·: Meq2.ofHzS04 ·:

giv40es heat 3 kJ and 40 Meq ofKOH on mixing (11) (d) 58 g isobut3 ane provides energy= 2658 kJ
:. 11.2 I o g isobutane provides energy
X
:. 1000 Meq ofHzS04 and 1000 Meq of KOH on
kJ
2658xl1.2xl03 =513268_9 kJ
mixing gives heat= 2.3 xl000 kJ
40 kJ= 57.5 58
(6) (b) W=-IOOJ,q= ISOJ The daily requirement ofenergy= 15000kJ
·:
q=�-W
:. 150=�E-(-l00) = 150-100 :. Cylinder will last= 513268.
15000
9 = 34 days
�E= SOJ (12) (b) 2Aig)+ 5Bz(g) 2A2B5(g); �H=-50160J
�

(7) W=-P�V=-1 .5(1-0.5)

(a) �n=2-(5+2) =-Smol.
= -0.75 atm-litre= -0.75 101 Joule �H = �E + (�n) RT g
(Mi)g
x
q=200J -50160 =6-E+ RT
·:
q=�E-W � =-50160 -(-5) (8.3 14) (300)
200 =�-(-0.75 Ol) XD =-50160+ 12471 =-37689 J
�E= 124.25 Joule (13) (a) We have,
(8) (b) �H = �E + �n RT W=-2.303 nRT log- Vz
Given �H=-651 103 cal., R=2cal.,
x v, 50
T=290K and M=6+6-6 =6 =-2.303 2 2 298 log l5 =-1436 calories.
x x x x
DPP/ C ( 10) -------t 23
(14) (d) Ace. to 1st law ofthermodynamics, !'lU = q + w (18) (a) For tl1is reaction �n 0 thus �E �H. = =

For isothennal process, !'lU = 0, :. q =-w {19) (b) Given number ofmoles= 1
For cyclic process, U = 0, :. q =-w
�
Initial temperature= 27°C =300K
For adiabatic process, q = 0. Hence, !'lU = w Work done by the system= 3 kJ = 3000J
For ·expansion into vacuum, w = Hence, !'lU = q.0.
It will be (-) because work is done by the system.
:. only(d) is incorrect. Heat capacity at constant volume (Cy) = 20 J K I
{15) (c) From the question we see that the first reaction is
exothermi We know that work done
xturecatand
ifcokea miand the second
oftheoxygen
same and
tim
oneeamis�0)
st
e, te
endothisermi
mperat u re
c. Thus,
passed
does over
not W=-nCv(T2-T1 )� 3000 =- ]x 20 (T2 -300)
change, the composition should beequal.
such that !'lH of 3000=-20T2 +6000
both the react ions are numerically 20T2 = 3000'· T2. 3000 =

20 150K =

Inevolthevesfirst110reaction, consumption of !12

mole of02 (20) (c) As the system is closed and insulated. no beat enters.
1 mole kJofofstenergy
forabsorbed. while 132thekJsecond
eam (H20), in reaction,is
of energy or leaves the system,i.e. Q= 0; . �E Q W W. ·. = + =

(21) (d) W = 0 is not true.

:. Mole of02 needed to evolve 132 kJ = Uo 0.5 x 132 (22) (d)
Hz(g)which--+ 2H( ). It nvolves
g breaking
=0.6 (I) H-H needs energy. :. !'lH = +ofbond
i
ve between
(2) /
:. Mole ratio of02 and steam �0) = 0.6 : I W(aq) --+

{16) (d) t.he molarityofKOH and HN03 solutions is x.

Let
:. 200 ml ofx mole KOH solution formatio+n ORwhi-ch(aresul
q) ts inl-J2release
0( ). ofIt energy.
involves bond
:. /'lH=-ve
= 1000 200 x mole OH ions
x
(3) H(g) --+ W(g) +e-. This is ionization, which needs
--

energy.
X
= 0.2 mole ions Of[" .. !'lH =+ve
Simjlarly, 200ml ofx mole HN03 solution (4) HzO (I) HzO(s). Phase transformation from(/)
--+ --+

'
(s). It involves cooling. Hence, �H =-ve
n+
= 1000 200 x xmole tons
-- TT :. (d) is correct answer.
C
(d) KCl(s) + H O( ) K+(aq) + CJ- (aq) t.)i0 =?
H+
(23) z �
= 0.2 xmole ions
(C)
H+ (aq) +Of1 (aq) l-J20 �
1 mol0 excess
0.2x 0.2 0.2 X X
!'lrH = [l'lrH0 (K+(aq) + !'lrH0 (CI-(aq))]
Heat evolved during formation of I mole 1 - [l'lrH0 (KCI)]1
kJ
= [-251.2 + (-167.01 8)] kJmol- - [--437. 6 kJ moi- ]
i
H20= 57.! =-418. 28 mo +437.
kJ 6 kJmoi- 1
:. Heat evolved during formation of0.2 x moleH 20 0
!'lrH =+ 19.3 kJmol- 1 -

=57.1 x0.2 xxkJ

kJ.
However, given heat evolved= 3.426 This process does not represent an ionisation
reaction.
T
he
:. 57.1 x 0.2x=3.426 kJ
process here involves dissolution of KCl(s) in

or
3.426 =0.3 mole.
x= 57.lx0. water
dissociand ation.formation of K+(aq) and CI-(aq) by
2
v
{24) (a) As CP Cv
>

( dHdT )P ( dTE ) (·... ( dHdT ) = cP (dE)

(b) w 2.303 nRTlog v �

dT v = cv )
(17)
> d
=

� and
v p
= 2.303 xI x8.314x 107 x 298log"i020
= 298xJ07 x8.314x2.303log2 AlsoCp -Cv -R ( dHdT ) - (dEdT )v = R
_
�

P
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24 DPP/ C (10)
w
(25) (b) �
Fe+2HCl FeC�+�
56g (27) (a) Work done by the compressed gas=-nRT log pP2I
28 g Fe will produce � =0.5 mole at S.T.P
As t a
he reaction is carried out in closed vessel, =-0.5 8.3 14x300 log l10
x

!!V= 0 :. W= - Pext x!!V=O = 1247 J

(26) (a) When reaction is carried out in open vessel, (28) (d) Values ofstate fimctions depend only on the state of
External pressure= l atm. the system and not on how it is reached.
Initial volume= 0 (as no gas is present) (29) (b) In an isothermal process change in jnternal energy
at
Final volwne 27°C and l atm can be calculated as: (as
(!!E) is zero it is a function oftemperature).
PV=nRT . . According to first law ofthermodynamics

. . V= nRT
p
:. Q+w=!!E,henceQ=-w(if!!E=O)
Ifenergy
a systofemtheundergoes a changes in whi(i.ech., !!Einternal
0.5x0.082lx300
l system remai ns constant = 0),
then-w=Q.
= 12.3 L This means that work done by the system equals the
· ·
!!V =V V 12.3 L
final - initial = heat absorbed by the system.
W =-Pext!!V (30) (a) Zeroth oftemperature can also
law be summarized as
=-!xl2.3 two OQjects at temperature
different in thermal contact
= -12.3 L t a m witemperat
th eachure.other tend to move towards the same
= -12.3 }0).3 J=-J246J
X