Name : Marks :90
Subject : Chemistry Time:1hr 30min
i.Choose the best answers 20×1=20
1. .----------------block elements which show only positive oxidation state
a) s b) p c) d d) f
2. Halo acids have no reaction with
a) B b) C c) Zn d) Al
3. In the manufacture of Pyrex glass,..is used.
a) boric acid b) boric oxide c) sodium borate d) boric anhydride
4. When boric acid reacted with ethyl alcohol in presence of conc.Sulphuric acid it gives ….
a) Borax b) trialkylborate c) Sodium borate d) Octahedral borax
5. Diborane reacts with methyl alcohol to give
a) Borax b) trialkylborate c) trimethyl borate d) Octahedral borax
6. The mixture of carbon monoxide and nitrogen is called -----------------
a) water gas b) producer gas c) both a and b d) none of these
7. The process in which Ethene is mixed with CO and Hydrogen gas to produce propanal .
a) McAfee process b) Oxo process c) Syn process d) Liquation process
8. The compound which act as a molecular sieve for the removal of permanent hardness of
water
a) Inosilicates b) Tecto silicates c) Amphiboles d) Zeolites
9. Boric acid is an acid because its molecule
a) contains replaceable H+ ion b) gives up a proton
c) combines with proton to form water molecule d) accepts OH- from water releasing proton.
10. In diborane, the number of electrons that accounts for banana bonds is
a) six b) two c) four d) three
11. Carbon atoms in fullerene with formula C60 have
a) sp3 hybridised b) sp hybridised
2
c) sp hybridised d) partially sp2 and partially sp3 hybridised
12. The basic structural unit of silicates is
a) (SiO3)2- b) (SiO4)2- c)(SiO)2- d)(SiO4)4-
13. Oxidation state of carbon in its hydrides
a) +4 b) -4 c) +3 d) +2
14. The geometry at which carbon atom in diamond are bonded to each other is
a) Tetrahedral b) hexagonal c) Octahedral d) none of these
15. Duralumin is an alloy of
a) Cu,Mn b) Cu,Al,Mg c) Al,Mn d) Al,Cu,Mn,Mg
16. The stability of +1 oxidation state increases in the sequence
a) Al < Ga < In < Tl b) Tl < In < Ga < Al c) In < Tl < Ga < Al d) Ga< In < Al < Tl
17.The empirical formula for the silicones
a ) (R2SiO) b) (RSi2O) c) (RSiO) d)(R3SiO)
18.Which one is the example for three dimensional silicates
a)Quartz b)Feldspar c)Talc d)Beryl
19.The critical temperature of CO2
a)350 b) 360 c) 380 d) 310
20.Which compound on hydrolysis will gives boric acid and sodium hydroxide
a)Borane b)Aluminium silicate c)boron d)Borax
ii.Answer the following questions 6×2=12
nd
21. A hydride of 2 period alkali metal (A) on reaction with compound of Boron (B) to give
a reducing agent (C). identify A , B and C.
22. Write a short note on hydroboration
23. What are necessary condition for catenation
24. Write about producer gas
25.What is burnt alum
26.How will you prepare Boron trifluoride industrially ?
iii.Answer the following questions 6×3=18
27.What are differences between graphite and diamond
28. Write the Anomalous properties of the first elements of p – block
29.What are silicones .How will you prepare silicones
30.How will you prepare perchloro siloxanes .What will you get after alcoholysis &
ammonialysis on silicon tetrachloride
31.Write about laboratory preparation , reducing behaviour , acidic behaviour & water gas
equilibrium of CO2
32.How will you prepare sodium borate , borazole , lithium borohydride
33.Give uses of i) Boron ii)Boric acid iii)Alum
v)Answer the following questions 6×5=30
34.Explain structure of diborane , Boric acid
35.What are silicates and explain its types
36. Describe briefly allotropism in p- block elements with specific reference to carbon &
metallic nature of p-block elements & uses of silicones
37.A compound (A) which is only non-metal in 13th group reacts with fluorine to give (B) .
Compound (A) on reacting with oxidising acids to give (D) .(D) on heating with soda ash
gives compound (E) .(E) on heating gives borax beads
38. A compound (A) is colourless and poisonous gas reacting with synthetic gas gives
compound (B) . B on reaction with compound of boron (C) gives Compound (D) .C on
heating at red hot gives non-metal (E) .(E) on reaction with sodium hydroxide gives
compound (F)
3100𝐾
39.Complete the reaction i)CO + C2H6 + H2 → ii)CO2 ⇔
iii)SiCl4 + C2H5OH → iv) SiCl4 +NH3 → v)AlCl3 + 3NH4OH →
40.How will you prepare i) meta aluminate from AlCl3 ii) BF3 from boron trioxide
iii)Diborane from sodium boro hydride iv)Boron trifluoride from boric acid
v)Boron nitride from boric acid
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