Class Test (Chemistry)

ATOMIC STRUCTURE

PART – A

1. The angular momentum of an e– can not have the value(s)

h h
(A) 0.5 (B)
 
h 2.5h
(C) (D)
0.5 2

2. The minimum energy required to escape out an e- from its ground state is called as
(A) Ionization potential (B) Separation energy
(C) Excitation energy (D) Kinetic energy

3. Out of the following which have longer wavelength

(A) Radio waves (B) Micro waves
(C) X-Rays (D) Cosmic rays

4. The radius ratio of two Bohr’s orbit of He+ is 9 : 25. Then what would be their nomenclature?
(A) K, L (B) M, N
(C) M, O (D) P, L

5. Out of which following which statement is correct for energy?

z2 19 z2
(A) 13.6 eV / atom (B) 21.69  10 J/ atom
n2 n2
z2 z2
(C) 1312 2 KJ / mole of atom (D) 312.6 Kcal / mole
n n2
(E) All of above

6. What is the separation energy of electron in Li2+ when it is escape out from fourth shell?
(A) 3.4 eV (B) 7.65 eV (C) -13.6 eV (D) 0.85 eV

7. A 100W bulb emits a monochromatic light of wavelength 400 nm. Calculate the no. of
photons emitted/sec by the bulb.
(A) 2 x 1020 photon/sec (B) 6.62 x 1034 photon/sec
23
(C) 6.023 x 10 photon/sec (D) 4 x 104 photon/sec

8. Which of the following statement is correct?

(A) When a photon of 11 eV is absorbed by an e- then it will transfer to II excited state
(B) When a photon of 12.75 eV is absorbed then it will transfer to III excited state
(C) When a photon of 12.09 eV absorbed then it will remains in ground state
(D) When a photon of 16 eV is absorbed then it will escape out from an atom.

9. What is ratio of time period of revolution of e- in 2nd and 3rd bohr orbit of Be+3 atom.
T1 8 T1 27 T1 4 T1 2
(A)  (B)  (C)  (D) 
T2 27 T2 4 T2 9 T2 3

10. What is the ratio of velocity(V1/V2) of electron in 2nd orbit of Li+2(V1) and 3rd orbit of Be+3(V2)?
V1 9 V1 729 V1 18 V 81
(A)  (B)  (C)  (D) 1 
V2 8 V2 512 V2 90 V2 64

11. Out of the following which is correct representation of 2Pz orbital?

 (A)  320 (B)  210 (C)  220 (D)  201

12. Out of the following which is correct representation of 3dx2 – y2?

(A)  320 (B)  321
(C)  322 (D)  323

13. For which orbital  420 is represented

(A) 4dx2 y 2 (B) 4Pdz
(C) 4dxy (D) 4dz2

14. The schrodinger wave equation for hydrogen atom is

3/2
1  1  r0  r /ao
 2s    2   e
4 2   a0   a0 
Where a0 is Bohr radius. If the radial node in 2s be r0, then find r terms of a0
(A) r0 = a0 (B) r0 = 2a0
(C) r0 = a0/2 (D) r0 = 4a0

15. Which of following is not possible?

(A) n = 2, l = 1, m = 0 (B) n = 3, l = 0, m = 0
(C) n = 2, l = 0, m = -1 (D) n = 3, l = 1, m = -1

PART – B

1. The iozination energy of hydrogen atom is 13.6 eV. What will be the ionization energy of
He+?
(A) 13.6 eV (B) 54.4 eV
(C) 122.4 eV (D) Zero

2. The iozination energy of He+ is 19.6 x 10-18J atom-1. Calculate the energy of the first
stationary state of Li+2:
(A) 19.6 x 10-18 J atom-1 (B) 4.41 x 10-18 J atom-1
-19 -1
(C) 19.6 x 10 J atom (D) 4.41 x 10-17 J atom-1.

3. The mass of an electron is m. Its charge of e and it is accelerated from rest through a
potential difference V. The velocity acquired by the electron will be
(A) V / m (B) eV / m
(C) 2eV / m (D) None.

4. What is the wavelength of the radiation emitted producing a line in the Lyman series when
an electron falls from fourth stationary state in hydrogen atom? (RH = 1.1 x 107 m-1)
(A) 96.97 nm (B) 969.7 nm
(C) 9.697 nm (D) None

5. The orbital angular momentum of an electron is 2s orbital is

1 h
(A)  (B) Zero
2 2
h h
(C) (D) 2
2 2
6. For a d-electron, the orbital angular momentum is
  
Given that   
 2 
(A) 6 (B) 2
(C)  (D) 2

7. The angular momentum (L) of an electron in a Bohr orbit is given as

nh h
(A) L  (B) L  I I  1
2 2
mg h
(C) L  (D) L 
2 4

8. Which of the following statement(s) are correct?

1. The electronic configuration of Cr is [Ar] 3d54s1 (atomic No. of cr = 24)
2. The magnetic quantum number may have a negative value
3. In silver atom, 23 electrons have a spin of one type and 24 of the opposite type (Atomic
no. of Ag = 47)
(4) The oxidation state of nitrogen in HN3 is –3
(A) 1, 2, 3 (B) 2, 3, 4
(C) 3, 4 (D) 1, 2, 4.

9. Ground state electronic configuration nitrogen atom can be represented by

1. 2.
3. 3.
(A) 1 only (B) 1, 2
(C) 1, 4 (D) 2, 3

10. The electron, identified by quantum number n and I (i) n = 4, I = 1 (ii) n = 4, I = 0 (iii) n = 3, I
= 2 (iv) n = 3, I = 1 can be placed in order of increasing energy from the lowest to highest as
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii).

11. If the nitrogen atom had electronic configuration 1s7, it would have energy lower than that of
the normal ground state configuration 1s22s22p3, because the electrons would be closer to
the nucleus. Yet 1s7 is not observed because it violated.
(A) Heisenberg uncertainty principal (B) Hund’s rule
(C) Pauli’s exclusion principle (D) Bohr postulates of stationary orbits.

12. How many moles of electrons weigh one kilogram?

1
(A) 6.023 x 1023 (B) x1031
9.108
6.023 54 1
(C) x10 (D)  108.
9.108 9.108  6.023

13. Matrix Match

Column – I Column – II
K.E.
(a) (p) 2
P.E.
1
(b) P.E + 2K.E. (q)
2
P.E.
(c) (r) 1
T.E
 K.E.
(d) (s) 0
T.E.
(A) (a – q), (b – s), (c – p), (d – r) (B) (a – s), (b – q), (c – r), (d – p)
(C) (a – s), (b – q), (c – p), (d – r) (D) (a – r), (b – s), (c – p), (d – q)

14. Matrix Match

Column – I Column – II
Orbital angular momentum of an h
(a) electron (p) S  S  1
2
(b) Angular momentum in an orbit (q) n n  2 B.M
Spin angular momentum in an nh
(c) orbit (r)
2
Magnetic moment h
(d) (s) I  l  1
2
(A) (a – s), (b – r), (c – p), (d – q) (B) (a – r), (b – s), (c – p), (d – q)
(C) (a – r), (b – s), (c – q), (d – p) (D) (a – s), (b – q), (c – r), (d – p)

15. Which of the following represents the incorrect set of the four quantum number of
4f-electrons?
1
(A) 4, 3, 2, + (B) 4, 2, 1, 0
2
1 1
(C) 4, 3, -2, (D) 4, 3, 1, -
2 2

16. The radial distribution curve of the orbital with double dumbbell shape in the 4th principle
shell consists of ‘n’ nodes, n is
(A) 2 (B) 0
(C) 1 (D) 3

17. The probability of finding an electron residing in a Px orbital is zero in the

(A) yz plane (B) xy plane
(C) xz plane (D) y and z direction

18. The first emission line in the atomic spectrum of hydrogen in the Balmer Series appears at
9RH 7RH
(A) cm1 (B) cm1
400 144
3RH 5RH
(C) cm1 (D) cm1
4 36

19. When the frequency of light incident on a metallic plate is doubled, the KE of the emitted
photoelectron will be;
(A) Doubled ‘
(B) Halved
(C) Increased but more than doubled of the previous KE
(D) Remains unchanged
20. A bulb takes 10 seconds to dissociate all molecules in 104 moles of chlorine. Bond energy
of ClCl bond is 3.2 x 1017 Jule/molecule. Power of bulb is:
(A) 19.27 watt (B) 15.27 watt
(C) 192.7 watt (D) 152.7 watt

21. Maximum number of electrons having (n + ) = 5 is

(A) 2 (B) 6
(C) 10 (D) 18

22. Time period of an e moving in 2nd Bohr orbit is x then time period of the e moving in 5th orbit
of same atom is
2  4 
(A)   x (B)   x
5  25 
 125   8 
(C)  x (D)  x
 8   125 
23. Frequency of an electron revolving in 3rd orbit of Hydrogen atom is f, then frequency of
electron revolving in 3rd orbit of Li2+ ion is
(A) 3 f (B) 9 f
(C) f/3 (D) f/9

24. Velocity of electron moving in 2nd orbit of hydrogen atom is  , then velocity of electron
moving in 3rd orbit of He+ is
(A) (9/4)  (B) (1/2) 
(C) (9/8)  (D) (4/3) 

25. Number of radial nodes for 3d suborbit is

(A) 2 (B) 3
(C) 0 (D) 1
26. Type of angular nodes for psuborbit is
(A) spherical (B) conical
(C) planar (D) none

27. Energy of 5th orbit of a hydrogen like species is E, then the ionization energy will be
(A) E (B) E/2
(C) 25 E (D) 2.5 E

28. Energy needed to ionize Li2+ ion, which has its electron in 4th orbit is
(A) 13.6 eV (B) 122.4 eV
(C) 7.65 eV (D) 30.6 eV
29. Ratio of wavelengths of 1st to 3rd spectral line in Be3+ ion corresponding to Paschen series
is
20 3
(A) (B)
3 20
260 12
(C) (D)
180 7
 ANSWERS
PART - A
1. D 2. A 3. A 4. C
5. E 6. D 7. A 8. BD
9. A 10. A 11. B 12. C
13. D 14. B 15. C
ANSWERS
PART – B

1. B 2. D 3. C 4. A
5. B 6. A 7. A 8. A
9. C 10. A 11. C 12. D
13. A 14. A 15. B 16. C
17. A 18. D 19. C 20. C
21. D 22. C 23. B 24. D
25. C 26. C 27. C 28. C
29. D