AITS REVISION 03 CHEMISTRY

Q1. Ground state electronic configuration of nitrogen atom can be represented by:

A. 1 only B. 1, 2 only C. 1, 4 only D. 2,3 only

Q2. The orbital angular momentum of an electron in 2s-orbital is:

1 ℎ ℎ ℎ
A. + B. Zero C. D. √2
2 2𝜋 2𝜋 2𝜋

Q3. The ionization enthalpy of hydrogen atom is 1.312 × 106 𝐽 𝑚𝑜𝑙 −1 . The energy required to excite the
electron in the atom from 𝑛 = 1 𝑡𝑜 𝑛 = 2 is:

A. 9.84 × 105 𝐽 𝑚𝑜𝑙 −1 B. 8.51 × 105 𝐽 𝑚𝑜𝑙 −1 C. 6.56 × 105 𝐽 𝑚𝑜𝑙 −1 D. 7.56 × 105 𝐽 𝑚𝑜𝑙 −1

Q4. The energy required to break one mole of Cl – Cl bond in Cl2 is 242 𝑘𝐽 𝑚𝑜𝑙 −1 . The longest wavelength of
light capable of breaking single Cl – Cl bond is: (𝑐 = 3 × 108 𝑚 𝑠𝑒𝑐 −1 , 𝑁𝐴 = 6.023 × 1023 𝑚𝑜𝑙 −1 )

A. 700nm B. 494nm C. 594nm D. 640nm

Q5. Vapour pressure increases with increase in:

A. Concentration of solution containing non-volatile solute

B. Temperature up to boiling point
C. Temperature up to triple point
D. Altitude of the concerned place of boiling

Q6. The Henry’s law of constant for the solubility of N 2 gas in water at 298 K is 1 × 105 𝑎𝑡𝑚. The mole
fraction of N2 in air is 0.8. The number of moles of N2 from dissolved in 10 moles of water at 298 K and 5
atm pressure is:

A. 4 × 10−4 B. 4 × 10−5 C. 5 × 10−4 D. 4 × 10−6

Q7. An aqueous solution of sucrose C12H22O11, containing 34.2 g/L has an osmotic pressure of 2.38
atmospheres at 170C, for an aqueous solution of glucose C6H12O6, to be isotonic with this solution, it
would have:

A. 34.2g/L B. 17.1 g/L C. 18.0 g/L D. 36.0 g/L of glucose

Q8. 0.6 g of an organic compound when dissolved in 21.7 g water freezes at 272.187 K. The molar mass of
the organic compound is close to:

(𝐾𝑓 of water is 1.86 deg/molality; freezing point is 273 K)

A. 61 𝑔 𝑚𝑜𝑙 −1 B. 63 𝑔 𝑚𝑜𝑙 −1 C. 65 𝑔 𝑚𝑜𝑙 −1 D. 67 𝑔 𝑚𝑜𝑙 −1

Q9. The reaction is non-spontaneous when:

A. ∆𝐻 is +ve, ∆𝑆 is –ve
B. Both ∆𝐻 𝑎𝑛𝑑 ∆𝑆 are –ve
C. ∆𝐻 is -ve, ∆𝑆 is +ve
D. None of these

Q10. Which plot represents an exothermic reaction?

Q11. Given,

𝑁𝐻3 (𝑔) + 3𝐶𝑙2 (𝑔) ⇌ 𝑁𝐶𝑙3 (𝑔) + 3𝐻𝐶𝑙(𝑔); −∆𝐻1

𝑁2 (𝑔) + 3𝐻2 (𝑔) ⇌ 2𝑁𝐻3 (𝑔); −∆𝐻2

𝐻2 (𝑔) + 𝐶𝑙2 (𝑔) ⇌ 2𝐻𝐶𝑙(𝑔) + 3𝐻𝐶𝑙(𝑔); ∆𝐻3

The heat of formation of NCl3(g) in terms of ∆𝐻1 , ∆𝐻2 𝑎𝑛𝑑 ∆𝐻3 is:
1 3
A. ∆𝐻𝑓 = −∆𝐻1 + ∆𝐻2 − ∆𝐻3
2 2
1 3
B. ∆𝐻𝑓 = ∆𝐻1 + ∆𝐻2 − ∆𝐻3
2 2
1 3
C. ∆𝐻𝑓 = −∆𝐻1 − ∆𝐻2 − ∆𝐻3
2 2
D. None of above

Q12. In thermodynamics, a process is called reversible when:

A. Surroundings and system change into each other

B. There is no boundary between system and surroundings
C. The surroundings are always in equilibrium with the system
D. The system changes into the surroundings spontaneously

Q13. Consider the endothermic reaction X → Y with the activation energies 𝐸𝑏 𝑎𝑛𝑑 𝐸𝑓 for backward and
forward reactions, respectively. In general:

A. 𝐸𝑏 < 𝐸𝑓 B. 𝐸𝑏 > 𝐸𝑓

C. 𝐸𝑏 = 𝐸𝑓 D. there is no definite relation between 𝐸𝑓 𝑎𝑛𝑑 𝐸𝑏

Q14. The endothermic reaction with high activation energy for the forward reaction is given by the
diagram:
Q15. The rate constant for a first order reaction is 6.909 𝑚𝑖𝑛−1 . Therefore, the time required in minutes for
the participation of 75% of the initial reactant is:
1 2 3 3
A. log 2 B. log 4 C. log 2 D. log 4
2 3 2 2

Q16. The rate of gaseous reaction is given by the expression 𝑘[𝐴][𝐵]. If the volume of reaction vessel is
suddenly reduced to one-fourth of the initial volume, the reaction rate relative to the original rate will be:

A. 1/16 B. 1/8 C. 8 D. 16

Q17. In gaseous reversible reaction, 𝑁2 (𝑔) + 𝑂2 (𝑔) ⇌ 2𝑁𝑂(𝑔) + 𝐻𝑒𝑎𝑡

If pressure is increased, then the equilibrium constant would be:

A. Unchanged
B. Increased
C. Decreased
D. Sometimes increased, sometimes decreased

Q18. For the chemical equilibrium 𝐶𝑎𝐶𝑂3 (𝑠) ⇌ 𝐶𝑎𝑂(𝑠) + 𝐶𝑂2 (𝑔).

∆𝐻𝑟0 can be determined from which one of the following plots?

Q19. For the reaction 𝑁2 + 𝑂2 ⇌ 2𝑁𝑂 equilibrium constant 𝐾𝐶 = 2. Degrees of dissociation of N2 and O2 are:
1 1 1 1 1 2 2
A. , B. , C. both are D. ,
1+√2 1−√2 1−√2 1+√2 1+√2 1+√2 1−√2

Q20. Consider the following reaction in which all the reactants and products are in gaseous state

2𝑃𝑄 ⇌ 𝑃2 + 𝑄2 ; 𝐾1 = 2.5 × 105

1
𝑃𝑄 + 𝑅2 ⇌ 𝑃𝑄𝑅; 𝐾2 = 5 × 10−3
2
The value of 𝐾3 for the equilibrium:
1 1 1
𝑃2 + 𝑄2 + 𝑅2 ⇌ 𝑃𝑄𝑅 𝑖𝑠:
2 2 2
A. 2.5 × 10−3 B. 2.5 × 103 C. 1.0 × 10−5 D. 5 × 103

Q21. The correct order of increasing [H3O+] in the following aqueous solution is:
(a)0.001 M H2S< 0.01 M H2SO4< 0.01 M NaCl< 0.01 M NaNO2

(b) 0.01 M NaCl< 0.01 M NaNO2<0.001 M H2S <0.01 M H2SO4

(c) 0.01 M NaNO2 < 0.01 M NaCl< 0.001 M H2S <0.01 M H2SO4<

(d) 0.001 M H2S < 0.01 M NaCl< 0.01 M NaNO2< 0.01 M H2SO4

Q22. Q21. Which of the following is a buffer solution?

(a) CH3COOH + CH3COONa

(b)NaCl + NaOH

(c)HCl + NH4Cl

(d) CH3COOH + HCL

Q23. Q22. In the acid-base relation;

HCl + CH3COOH ⇌Cl- + CH3COOH2+,

The conjugate acid od acetic acid is:

(a)Cl-

(b)HCL

(c) CH3COOH2+

(d) H3O+

Q24. Q23. At 900C, Pure water has [H3O+] = 10-6mol liter-1. The value of KW at 900C is:

(a) 10-6

(b) 10-12

(c) 10-14

(d) 10-8

Q25. Q24. Equivalent weight of FeC2O4 in the change,

FeC2O4→ Fe3+ + 2CO2 is:

(a)M/3

(b) M/6

(c) M/2

(d) M/1

Q26. Q25. The oxidation number of sulphur is Sg, S2F2 and H2S respectively are:

(a) 0, +1 and -2

(b) +2,+1 and -2

(c) 0, +1 and +2

(d) -2, +1 and -2

Q27. Q26. When KMnO4 acts as an oxidation agent and ultimately forms𝑀𝑛𝑂42− , 𝑀𝑛𝑂2 , 𝑀𝑛𝑂2 𝑂3 and 𝑀𝑛2+ ,
then the number of electrons transferred in each case respectively is:

(a) 4,3,1,5

(b) 1,5,3,7

(c) 1,3,4,5

(d) 3,5,7,1
Q28. Q27.The reduction potential value of M,N and O are +2.46V, -1.13, respectively. Which of the
following orders is correct regarding their reducing property?
value of O is missing
(a) O > N > M

(b) O > M > N

(c) M > N > O

(d) M > O > N

Q29. Conductivity (Unit Siemen’s ‘S’) is directly proportional to area of the vessel and the concentration of
the solution in it and is inversely proportional to the length of the vessel, then the unit of constant of
proportionality is:

(a) S m mol-1

(b) S m2 mol-1

(c) S-2 m2mol

(d) S2 m2 mol-2

Q30. Zn(s) + Cu2+ (aq) ⇌ Cu(s) + Zn2+ (aq.)

[𝑍𝑛2+ ]
Reaction quotient Q = , Variation 𝐸𝑐𝑒𝑙𝑙 with 𝑄 is the ____
line with 𝑂𝐴 = 1.10 volt 𝐸𝑐𝑒𝑙𝑙 = 1.1591 volt when:
[𝐶𝑢2+ ]

(a) [Cu2+] / [Zn2+] = 0.01

(b)[Zn2+] /[Cu2+] =0.01

(c)[Zn2+] / [Cu2+] =0.1

(d)[Zn2+] / [Cu2+] = 1

Q31. The correct order of I.E.2.is:

(a) Na > F > O > N

(b) Ne > O > F > N

(c) O > F > Ne > N

(d) O > Ne > F > N

Q32. Which of the following order is incorrect?

(a) Electronegativity of central atom : CF4> CH4> SiH4

(b) Hydration energy : Al3+ > Be2+> Mg2+> Na+

(c) Electric conductance : F-(aq.) >Cl-(aq.)> S2-(aq.)

(d) Magnetic conductance: Ni4+ > V3+> Sr2+

Q33. Correct expression of “Allred and Rochow’s” scale is:

𝑍𝑒𝑓𝑓
(a) Electro negativity = 0.744 + 0.359
𝑟2

𝑟2
(b)Electro negativity = 0.359 +0.744
𝑍𝑒𝑓𝑓

𝑍𝑒𝑓𝑓
(c)Electro negativity =0.359 +0.744
𝑟2

𝑍𝑒𝑓𝑓
(d)Electro negativity = 0.359 +0.744
𝑟2

Q34. In which of the following compounds B – f bond length is shortest?

(a) BF-4

(b) BF3
(c) BF3← NH3

(d) BF3←N(CH3)3

Q35. Amongst LiCl, BeCl2, MgCl2 and RbCl the compounds with greatest and least ionic character,
respectively are:

(a)LiCl and RbCl

(b)RbCl and BeCl2

(c)RbCl andMgCl2

(d) MgCl2 and BeCl2

Q36. The two orbitals have a bond angle of 1200. The Percentage of s-character in the hybrid orbital is
nearly:

(a) 25%

(b) 33%

(c) 50%

(d) 66%

Q37. The bond length of the S – O bond is maximum in which of the following compounds?

(a) SOCl2

(b)SOF2

(c) SOBr2

(d) All have the same length

Q38. Which of the following order is correct in spectrochemical series of ligands?

(a)Cl-< F- < C2O42-< NO2-< CN-

(b)NO2-<C2O42-<Cl-<F- <CN-

(c)C2O42-<F- <Cl-<NO2-<CN-

(d)F- <Cl-<NO2-<CN-<C2O42-

Q39. If E.A.N of central metal cation M2+ in non-chelating complex is 36 and atomic no. of metal M is 26,
then the number of monodenatate ligand is in this

(a) 5

(b) 4

(c) 6

(d) None of these

Q40. The CFSE for [(CoCl)6]4- complex is 18000 cm-1. The ∆ for [CoCl4]2- will be:

(a)18000cm-1

(b) 16000 cm-1

(c) 8000cm-1 10,000

(d) 2000cm-1

Q41. Which one of the following complexes exhibit chirality?

(a) [CO(en)2Cl2]+ ist option is wrong

(b) cis-[RhCl2(NH3)4]+
(c) cis-[PtCl2(en)]

(d) mer-[Co(NO2)3(dien)]

Q42. d𝜋 – p𝜋 bonding is shown in

(a) P2O3, P2O5, PO43-

(b) CO, NO,CO2, NO2

(c) NH3, PH3, BiH3

(d) NO3-, NO2-, N3-, CN-

Q43. In the case of nitrogen family (group-16)

(a) The tendency for catenation decreases markedly as we go down the group

(b) Maximum coordination of oxygen is four due to lack of d-orbital but that of other elements is six due to
presence of d-orbitals
Remove question
(c) The tendency to form multiple bonds with C,N and O decreases as going down the group from S to Te.

(d) All are correct

Q44. Acid strength of oxoacids of halogen is in order:

(a) HOI >HOBr>HOCl> HOF

(b)HOCl>HOBr>HOI >HOF

(c)HOI >HOCl>HOBr>HOF

(d)HOI >HOCl>HOBr>HOF

Q45. Cerium (Z = 58) is an important member of the lanthanoids. Which of the following statements about
cerium is incorrect?

(a) The common oxidation states of cerium are +3 and +4

(b) The +3 oxidation state of cerium is more stable than the +4oxidation state of cerium is more stable than
the +4 oxidation state

(c) The +4 oxidation state of cerium is not known in solutions

(d) Cerium (IV) acts as an oxidizing agent

Q46. What is the current order of spin only magnetic moment (in B.M) of Mn 2+, Cr2+ and V2+?

(a) Mn2+> V2+> Cr2+

(b)V2+>Cr2+>Mn2+

(c)Mn2+>Cr2+>V2+

(d)Cr2+>V2+>Mn2+

Q47. Which statement is not correct with respect to transition metals?

(a)The colour if the hydrated ions is due to transitions of electrons from different ‘d’ orbitals of the same
principal quantum number

(b) Most transition metals should, on thermodynamic considerations, liberate hydrogen from acids

(c) The complex formation of transition metal ions is often accompanied by a change in the intensity of the
colour

(d)The compounds of the elements in low oxidation states are generally ionic

Q48. The maximum number of molecules is present in:

(a) 15 L of O2 gas at STP

(b) 10 L of H2 at STP

(c) 1.5 g of H2gas

(d)5 g of CO2 gas

Q49. Mixture X = 0.02 mol of [Co(NH3)5SO4] Br and [Co(NH3)5Br] SO4 was prepared in 2 liter of solution

1 liter of mixture X + excess AgNO3 Y

1 liter of mixture X + excess BaCl 2 Z

Numbers of moles of Y and Z are:

(a) 0.02, 0.01

(b) 0.01, 0.01

(c) 0.01, 0.02

(d) 0.02, 0.02

Q50. Carbon and the oxygen combine to form two oxides of carbon dioxide in the ratio of the weights if
carbon and oxygen is respectively 12: 16 and 12: 32. These figures illustrate the:

(a) Law of multiple proportions

(b) Law of conservation of mass

(c) Law of reciprocal proportions

(d) Law of constant proportions