22-06-2025

2001CJA101021250014 JA

PHYSICS

SECTION-I(i)

1) In the circuit shown if resistance of ammeter is 100Ω, reading of ammeter will be

(A) 0.2 A
(B) 0.05 A
(C) 0.1 A
(D) zero

2) Time constant of charging of the capacitor shown in the adjoining figure is

(A) 2RC
(B) CR/2
(C) zero
(D) infinite

3) A length of wire carries a steady current. It is first bent to form a circular coil of one turn. The
same length is now bent more sharply to give a double loop of a smaller radius. The magnetic field
cause at the centre by the same current is

(A) a quarter of its first value

(B) two times its first value
(C) four times its first value
(D) half its first value

4) A person is sitting facing the engine in a moving train. He tosses a coin. The coin falls behind him.
This shows that the train is

(A) moving forward with a finite acceleration

(B) moving forward with a finite retardation
(C) moving backward with a uniform speed
(D) moving forward with a uniform speed.

SECTION-I(ii)

1) When no current is passed through a conductor

(A) the free electrons do not move

(B) the average speed of a free electron over a large period of time is zero
(C) the average velocity of a free electron over a large period of time is zero
(D) the average of the velocities of all the free electrons at an instant is zero

2) A potentiometer arrangement is shown in the figure. Driving cell has e.m.f. e and internal
resistance r. Resistance of uniform potentiometer wire AB is R & its length is L. F is the cell of e.m.f.
e/3 and internal resistance r/3. Choose the CORRECT statements for the following circuit:

(A) Balance point can be obtained for all finite values of R > r/2.
(B) If R = 2r/3 & LAJ = 5L/6, current through battery (e/3) is 3e/5r.
(C) If R = 2r/3 & LAJ = 5L/6, current through battery (e) is 3e/5r.
(D) If R = r/2 & LAJ = L power consumed by battery (e/3) is zero.

3) Capacitor C1 of capacitance and capacitor C2 of capacitance are separately charged

fully by a common battery. The two capacitors are then separately allowed to discharge through
equal resistors both starting at time t = 0.

(A) The current in the two discharging circuits at t = 0 are equal and not zero.
(B) The currents in the two discharging circuits at t = 0 are not equal and not zero.
The current through the resistor connected to C1 is always greater than the current through
(C)
C2.
(D) Capacitor C1, loses 50% of its initial charge sooner than C2 loses 50% of its initial charge.

4) A painter is applying force himself to raise him and the box with an acceleration of 5 m/s2 by a
massless rope and pulley arrangement as shown in figure. Mass of painter is 100 kg and that of box
is 50 kg. If g = 10 m/s2, then :-

(A) Tension in the rope is 1125 N.

(B) Tension in the rope is 2250 N.
(C) Force of contact between the painter and the floor is 375 N.
(D) Force of contact between the painter and the floor is 750 N.

SECTION-II

1) In the circuit shown in figure each battery is 5 V and has an internal resistance of 0.2 Ω. What is

the reading of ideal voltmeter V (in Volt )?

2) An uncharged capacitor of capacitance C is connected in given circuit diagram, switch S is closed

at t = 0. If current in branch BC as function of time is given by then find the

numerical value of I τ.

3) A galvanometer gives full scale deflection with 8 mA current. By connecting a resistor of value
2240Ω in series it can be converted into a voltmeter of range 0 – 18 V. If the galvanometer is
connected to RΩ in parallel it becomes ammeter of range 0 - 2A, write the value of

4) 10 resistors each of resistance can be connected in such as to get maximum and minimum
equivalent resistance. The ratio of maximum and minimum equivalent resistance will be _______ .

5) In the circuit shown, the current (in A) in 2 Ω resistor is

6) The current density in a cylindrical conductor of radius R varies according to the equation

, where r is distance from the axis. Thus, the current density is maximum at the

axis, where r = 0 and decreases linearly to zero at the surface, where . Current in terms of
is given by then value of n will be ____

7) Four infinite long wires are arranged at the vertices of square as shown. Two wires at A and D
carry current out of plane and two wires B and C carry currents into the plane. Mark the number at
which net magnetic field due to these four wires at centre will be shown.

8) What should be minimum ‘m’ (in kg) such that system just start moving, if
 CHEMISTRY

SECTION-I(i)

1) (P) (Q) (R) (S)

How many of the following statements is/are incorrect
1. Stability order is R > P > S > Q
2. Vanderwalls strain in maximum for R
3. Potential energy is maximum for R
4. Potential energy order is Q > S > R > P

(A) 3
(B) 4
(C) 2
(D) 1

2) On Neptune planet, where everything is frozen, astronauts discovered two forms of 1,2-
dibromoethane : gauche and anti. Assuming that there are no rotations about single bonds, which
statement about the two forms is correct?

(A) They are enantiomers

(B) They are diastereomers
(C) They are meso compounds
(D) Both will show optical activity

3) Number of moles of required to oxidize one mole of ferrous oxalate completely in acidic
medium will be

(A) 7.5 moles

(B) 0.2 moles
(C) 0.6 moles
(D) 0.4 moles
4) Which of the following complex is expected to have lowest Δ0 values?

3+
(A) [Co(NH3)6]
3-
(B) [CoF6]
3+
(C) [Rh(NH3)6]
3+
(D) [Ir(NH3)6]

SECTION-I(ii)

1) is D-erythrose. Which of the following structure is correctly matched with

relationship it has with D-erythrose.

(A)

Diasteroisomer

(B)

Identical

(C)

(D)

2) Which of the following compounds are optically active ?

(A)
(B)

(C)

(D)

3) Which of the following statements is/are correct?

(A) IUPAC name of compound [Pt(NH3)2Cl(NO2)] is diamminechloridonitrito-N-platinum(II)

(B) Ligands such as and are ambidentate ligands.
3+
(C) [Co(NH3)6] is an outer orbital complex.
(D) Vitamin B12 is a coordination compound of cobalt.

4) In aqueous solution, HNO2 disproportionates to give:

(A) HNO3
(B) NO
(C) N2O3
(D) N2

SECTION-II

1) How Many of the following statements are not correct ?

(a) A meso compound has chiral centres but exhibits no optical activity
(b) A meso compound has no chiral centres and thus are optically inactive
(c) A meso compound has molecules which are superimpossable on their mirror images even though
they contain chiral centres
(d) A meso compound is optically inactive because the rotation caused by any molecule is cancelled
by an equal and opposite rotation caused by another molecules that is the mirror image of the first
(e) A compound whose molecule has D configuration will always be dextrorotatory
(f) A compound whose molecule has D configuration may be dextrorotatory or levorotatory
(g) A compound whose molecule has L configuration will always be levorotatory
(h) A compound whose molecule has L configuration may be dextrorotatory or levorotatory
2) How many chiral carbon(s) is/are present in Gorlic acid (C18H30O2)

3) The number of optically active compounds in the isomers of C4H9Br is–

4) Calculate total numbers of ether possible for C5H12O molecular formula [Structural Isomer]

5) Dissolving 2.48 g of white phosphorous (P4) in boiling conc. NaOH solution in an inert atmosphere
gives a gas Q. The amount of gas Q (in gram) formed is:
[Given : Atomic mass of H = 1, O = 16, Na = 23, P = 31]

6) How many moles of colourless diatomic gas are obtained on thermal decomposition of 1 mole of
ammonium dichromate?

7) Total how many stereoisomers are there for the complex [Pt(CO)2 (PPh3)2]?

8) A power company burns approximately 500 tons of coal per day to produce electricity. If the
sulphur content of the coal is 1.5 % by mass, then how many tons of SO2 are dumped into the
atmosphere every day?

MATHEMATICS

SECTION-I(i)

1) Number of points at which is non-differentiable?

(A) 1
(B) 2
(C) 3
(D) 4

2) Let A = . If M and N are two matrices given by and then

MN2 is

(A) A non-identity symmetric matrix

(B) a skew-symmetric matrix
(C) neither symmetric nor skew-symmetric matrix
(D) an identity matrix
3) Sum of n terms of the series sinx sec3x + sin3x sec32x + sin32x sec33x+...., is

(A)

(B)

(C)
(D)

4) The function f(x) = [x]2 – [x2] (where [y] is the greatest integer less than or equal to y), is
discontinuous at :

(A) all integers

(B) all integers except 0 & 1
(C) all integers except 0
(D) all integers except 1

SECTION-I(ii)

1) If f(x) = xsinx, then correct option's is/are-

(A)

(B)

(C)

(D)

2) Let A be a non singular, symmetric matrix of order three such that A = adj(A + AT), then -

(A)

(B) A–1 = 16A

(C) adj(A–1) = 64A
adj(A–1) =
(D)

3) The equation sin6x + cos6x = a2 has real solutions

(A)

(B)

(C)

(D)
4)

If , then which of the following statement(s) holds good ?

(A) ƒ(x) is continuous at x = 1

(B) ƒ(x) is discontinuous at x = 1

(C) exists finitely

(D) does not exist

SECTION-II

1) How many matrices M with entries from {0, 1, 2} are there, for which the sum of the
diagonal entries of MTM is 5?

2) If and then |B| is

3) A function is represented parametrically by the equations

Then the value of is _____ .

4) If then K is

5) The value of is equal to

6) Let is differentiable function for all real x and a ∈ R, b ∈

[0,10π], then number of ordered pair of (a,b) is-

7)

If f(x) = maximum , 0 x 2 , where { . } represents fractional part function,

then number of points of which f(x) is continous but not differentiable, is

8) Let S be the set of points where the function, f(x) = |2–|x–3||, x ∈ R, is not differentiable. Then
is equal to _______.
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. B C C A

SECTION-I(ii)

Q. 5 6 7 8
A. C,D A,C,D A,D A,C

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 0.00 16.00 24.90 100.00 6.00 1.33 3.00 1.00

CHEMISTRY

SECTION-I(i)

Q. 17 18 19 20
A. A B C B

SECTION-I(ii)

Q. 21 22 23 24
A. A,B,C,D B,D A,B,D A,B

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 4.00 1.00 2.00 6.00 0.68 1.00 0.00 15.00

MATHEMATICS

SECTION-I(i)

Q. 33 34 35 36
A. B A B D

SECTION-I(ii)

Q. 37 38 39 40
A. A,B B,C B,C B,C
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 198.00 0.00 1.00 8.00 35.00 10.00 4.00 3.00
 SOLUTIONS

PHYSICS

1)

2)

There is no Resistance in series with C.

3)

4)

Conceptual

5)

When no current is passed through a conductor the average velocity of a free electron over a
large period of time is zero and the average of the velocities of all the free electrons at an
instant is zero. When no current is passed through a conductor the average velocity of a free
electron over a large period of time is zero and the average of the velocities of all the free
electrons at an instant is zero.

6)
so it represent balancing length

ie/3 = 0 ; ie =

for R = & LAJ = L ; system is in balance

⇒P=0

7) and

So, and

at t = 0, i1 = i2 =
option-(1) is correct
c1 < c2 ⇒ capaction c1 will lose its carge faster.
option (4) is correct
8)

9)
ΔV = ε – Ir

10) For time constant

Charge on capacitor in steady state

= 4 ΔVBC = 4 × 4 = 16 μC

Charge as function of time

11)

RG = 10
Now for ammeter

12)

13) The resistors of 4 Ω and 8 Ω are connected in parallel.

∴ Potential drop across 4 Ω resistor =
Potential drop across 8 Ω resistor
Let current in 4 Ω resistor be i
∴ 4i = 8 × 2
or i = 4 A
∴ current through 2Ω resistor
=4+2=6A

14)

shaded area

15)
 Use right hand thum rule and vector addition.

16)

In equilibrium :
mg = T and
2T = μ(10 kg)g in limitring case
⇒ 2T = 0.2 × 10 × 10
⇒ T = 10
∴ mg = T = 10
⇒ m = 1 kg

CHEMISTRY

17)

Vanderwalls strain in maximum for R

Potential energy is maximum for R
Potential energy order is Q > S > R > P

18) Gauche & Anti forms are non superimposable non mirror images stereoisomers
(diasteromer)

19)

Moles of MnO4- × 5 = Moles of ferrous oxalate × 3

Moles of MnO4- = 0.6 moles

20)

Fact

21) Given compound

(A)
(B)

(C)

(D)

22)

2 and 4 are optically active due to not having symmetry.

23)

[Co(NH3)6]3+ is an inner orbital complex.(d2sp3)

24)

HNO2 → HNO3 + NO + H2O

25)

b, d, e, g are incorrect

26) The given compound

Starred carbon is chiral carbon.

27) 2-Bromo butane (R & S)

28)

6 ether structural isomers are possible

29)

P4 + 3OH- + 3H2O → PH3 + 3H2PO2-

 Moles of PH3 formed =

30) (NH4)2 Cr2O7 → N2 + Cr2O3 + 4H2O

31)

Complex is tetrahedral so does not exhibit Geometrical isomerism, it is optically inactive due
to presence of POS.

32)

Mass of SO2 =

MATHEMATICS

33)

=
f(x) is non differentiable at x = 1,3

34)

Now
=

=
 =
N = A + A3 + A5 + ......... + A19
= A - 22A + 24A - 26A.................-218A
= A[1 - 4 + 16 - 64 .......... - 218]

Now, MN2 =

35)

[tan 3x – tan x + tan32x – tan x+...........

+ tan3nx - tan3 n–1x

36)

f(x) = [x]2 – [x2]

at x = 0;
f(0) = 0 – 0 = 0
f(0+) = [0+]2 – [(0+)2] = 0 – 0 = 0
f(0–) = [0–]2 – [(0–)2] = (–1)2 – 0 = 1
∴ Discontinuous at x = 0.
at x = 1; f(1) = [1]2 – [12] = 0
f(1+) = [1+] – [(1+)2] = 1 –1 = 0
f(1–) = [1–]2 – [(1–)2] = 0 – 0 = 0
∴ continuous at x = 1
at x = n,
f(n) = [n]2 – [n2] = 0
f(n+) = [n+]2 – [(n+)2] = n2 – n2 = 0
f(n–) = [n–]2– [(n–)2] = (n – 1)2 – (n2 – 1)
= n2 – 2n + 1 – n2 + 1
= –2n + 2
for continuity
∴ f(n) = f(n+) = f(n–)
0 = 0 = –2n + 2 Þ n = 1
∴ Discontinuous at all integers except 1.

37) f(x) = xsinx

38) ∵ AT = A ⇒ A = adj(2A) ⇒ A = 4 adjA ⇒ |A| = 64|A|2 ⇒

Now,

and adjA–1 = adj(16A) = 256 adjA =

39)

Given equation will have solution

if

40)

∵ LHL ≠ RHL
∴ Discontinuous at x = 1.
Similarly

41)

Let M =
Now Tr (M T M) = 5
⇒ a2 + b2 + c2 + d2 + e2 + f2 + g2 + h2 + i2 = 5
Reqd. no. of matrices =
= 198

42) A2 = I
⇒ B = 1010I + 1010A

B= ⇒ |B| = 0

43)

44)

45) The given expression

= 32 + 8 – 5 = 35

46)
47)

See figure

There are 4 points

48)

f(x) =

=
S = {5, 3, 1}

Now
=
=
=1+1+1
=3