Recent Progress in Phase-Change Memory Technology
Recent Progress in Phase-Change Memory Technology
2, JUNE 2016
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Fig. 5. Cross sectional SEM images along (a) BL direction and (b) WL direc-
tion. (c) TEM image of cell module along BL direction. (d) Schematic diagram
Fig. 4. (a) Both the percentage of Ge and Te content inside a memory cell of PRAM cell array and unit cell. (e,f) Cross sectional TEM images of 20
and (b) data retention characteristics can depend on the horizontal dimensions. nm confined cell. (Reprinted, with permission, from [21].)
(Reprinted, with permission, from [26]).
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BURR et al.: RECENT PROGRESS IN PHASE-CHANGE MEMORY TECHNOLOGY 149
TABLE I
COMPARISON OF PHASE-CHANGE MATERIAL COMPOSITIONS FOR HIGH THERMAL STABILITY. IS DETERMINED FROM RESISTIVITY VERSUS
TEMPERATURE MEASUREMENTS, RESET CURRENT AND SET SPEED FROM 256 MBIT CHIP OPERATION, AND THE RECRYSTALLIZATION
TIME NEEDED TO COMPLETE 90% OF THE PHASE TRANSFORMATION FROM LASER TESTING. (REPRINTED, WITH PERMISSION, FROM [49].)
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stack switches between LRS and HRS without melting the ma-
terial [Fig. 12(b)]. In contrast to conventional PCM switching
achieved by order-disorder transition, iPCM switching is said
to depend on short-range movement of atoms [86], [87], with
the conduction channel of Te-Te inducing the difference in
resistance. In the SET state, the atomic sequence is believed
to be Ge-Te-Te-Ge, while in the RESET state; the sequence is
Te-Ge-Ge-Te [87].
This ability to switch without melting should then lead to
both reduced power consumption and improved endurance [83]. Fig. 13. a) Disturbed cell resistance as a function of disturbing current. Dis-
turbed cell is initially written by program & verify scheme to make 1.0
RESET current as small as 3 has been demonstrated with RESET state. b) RESET volume characterization in the disturbance-induced
/ superlattice PCM cell at a SET resistance of failed bits. Test sequence: odd numbered cells RESET/even numbered cells
30 [88]. Since its first introduction, device performance of RESET/read all (odd and even numbered cells) (Reprinted, with permission,
from [107].).
superlattice PCM stacks has been continuously improved, by
optimizing the superlattice stack design and by decreasing the
cell size [86], [87], [89], [90]. Although the conduction mech- change as its neighbors are repeatedly programmed (Fig. 13),
anism, switching mechanism, and even the precise multilayer and proposed that this issue could be avoided by reducing
structure are still not fully understood, various physical proper- the required RESET current of the PCM cell. It has also been
ties of the superlattice stack such as magnetoelectric property shown that the phase-change material thickness as well as the
are being explored as well [91], [92]. properties of the capping layer on the phase-change material in
Circuit and systems implications of lower switching power the Wall-type PCM cell structure can influence thermal disturb
can be sizeable, since high memory-device switching power can (Fig. 3) [23].
easily lead to unpleasant density reductions that can strongly in- Alternative materials, such as stoichiometric GaSb, can offer
crease memory cost. These can be due to increases in cell size both fast switching speed and good thermal stability [108],
(either to accommodate larger access devices or wider wires of- while showing a decrease in mass density upon crystallization
fering lower resistance losses), losses in area efficiency (larger- ( ) [109]. In contrast, typical phase-change materials
size drive transistors), or in lower write parallelism. such as GST-225 exhibit an increase in mass density 5%–6%,
with the crystalline phase being more dense than amorphous
VI. IMPROVEMENTS IN RELIABILITY phase. At a composition of Ga:Sb = 30:70, no mass density
Although PCM shows excellent endurance characteristics change is observed, which could potentially suppress void
for cycles, cycling-induced degradation can generate formation and thus extend PCM cycling endurance [108].
early tail-bits that trigger read errors, thereby limiting overall As mentioned earlier, higher reliability allows the use of
endurance. Three typical tail-bit behaviors are observed: more efficient ECC (error–correction coding) solutions, so as
cell-open, stuck-high (SET failure) and stuck-low (RESET to minimize the portion of the array used for redundant data,
failure) [93], [94]. Cell-open failure is attributed to void ag- and to maximize the portion available for user data. Efficient
glomeration and accumulation toward the bottom electrode ECC and wear-leveling schemes [110] also help keep area
(BE), leading to an “open” cell once the void completely blocks efficiency—the fraction of CMOS real-estate used for memory
current from reaching the BE. Stuck-low failure is attributed devices as opposed to peripheral circuits—high. As we will
to Sb enrichment in the active volume during repeated cycling see in the next section, 3D access devices can help move the
[95]–[98], which decreases dynamic resistance and increases memory above the front-end silicon real-estate, thus relaxing
RESET current. The onset of this failure mode is observable this tension between utilization of silicon for peripheral cir-
as a “right-shift” of the - characteristics [99] [Fig. 8(a)]. cuitry versus that needed for access devices. However, the
Stuck-high failure is a transitional behavior between stuck-low need for numerous dense-pitch vias between the underlying
and cell-open due to GST phase segregation or voids at the circuitry and the overlying memory layers still imposes strong
interface between GST and BEC [96], [98], [100]. Void forma- constraints on how flexibly the silicon can be utilized.
tion is driven by mechanical stress due to the repeated changes
in volume during SET-RESET switching, while phase sepa- VII. IMPROVEMENTS IN DATA DENSITY: 3D
ration is driven by incongruent melting and recrystallization Besides memory cell engineering, care must be taken to
at the boundary between liquid and solid [96], [100]–[102]. choose an access device capable of delivering high current and
A cell design that promotes complete melting [103] can help power without requiring a significantly larger footprint than
suppress phase segregation. Other techniques for minimizing the PCM element itself. This becomes even more complicated
cycling degradation include reductions in SET pulse width and when designing integration schemes which could allow for
lower SET current [104], [105], to reduce SET-induced elec- higher effective data density (and thus lower cost) through 3D
tromigration and phase segregation. An In-Situ-Self-Anneal memory arrays with multiple layers of PCM cells [111]. Here
(ISSA) healing procedure can extend cycling endurance by the access devices must also be fabricated with temperatures
occasionally rejuvenating stressed PCM cells [106]. commensurate with Back-End-Of-Line processing ( )
As cell-to-cell pitch reduces, thermal write disturb can be a [111]. Polysilicon diodes [112], [113], carbon nanotube tran-
concern. [107] showed that the resistance of a PCM cell can sistors [114], OTS (Ovonic Threshold Switches) [115], [116],
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BURR et al.: RECENT PROGRESS IN PHASE-CHANGE MEMORY TECHNOLOGY 155
for more MLC levels [Fig. 16(c)]. The metric used is the time
needed for the read current to reach a reference value during
a linear voltage ramp, so that no resistance state ever experi-
ences a read condition that would perturb the state. Yet this Fig. 18. (a) Schematic diagram of a PCM cell with metal nitride surfactant in
metric allows the deepest RESET states to be distinguished from the full SET state, in a partial RESET state, and in the full SET state, along with
modest yet equally resistive RESET states. The reference cur- equivalent circuit models. The metal nitride layer provides an alternative read
current path to the amorphous region, with its effective resistance modulated
rent value, —at which the linear voltage ramp terminates, by the thickness of the amorphous region. Median and standard deviation of
defining this alternative “ ” metric by relating the time-delay resistance versus time comparing PCM devices built (b) without and (c) with
to read voltage at —may be fixed or varied as a function the metal nitride surfactant. With the surfactant, resistance contrast is slightly
reduced, but the drift coefficient is reduced 6 . (Reprinted, with permission,
of the instantaneous voltage value [147]–[149]. This ramped from [72].)
read-voltage approach avoids the read disturb that would oth-
erwise occur if the high read voltages needed to distinguish the
deepest RESET levels were applied to all cells. Since this al- is coding and signal processing, which can complement both
ternative cell-state metric is less sensitive to bandgap variations drift-resilient cell-state metrics and drift-resilient cell design.
[147], the effects of drift are strongly reduced as compared to Rather than detect stored data with fixed thresholds, detection
normal drift behavior of the low-field resistance (Fig. 17). thresholds can be adapted according to the changing character-
Kim et al. [72] introduced a PCM cell design integrated istics of the memory cells, not with reference cells, but through
with a metal nitride (“metallic surfactant”) layer to stabilize modulation coding in which small blocks of user data are en-
the resistance of the PCM cell in the RESET state. The metal coded into short codewords [136], [150]. By storing information
nitride layer helps mitigate resistance instabilities such as re- in the relative order of levels (which is maintained over time
sistance drift, noise, and temperature dependence by providing quite well) within each codeword, such codes can offer robust-
an alternative current path around the amorphous region during ness to drift. Balanced codes, where each stored level appears
the read operation [Fig. 18(a)]. In this structure an in-situ (approximately) the same number of times, provide for easier
process of a thin metal nitride layer plus phase-change material parameter estimation and better estimation of the changing level
deposition lines and fills a hole, making contact to a lower thresholds [151]. The combination of coding, adaptive threshold
electrode exposed at the bottom of the hole. The lack of a detection and judicious placement of target programmed levels
vacuum break between the metallic liner and the deposition can lead to remarkable tolerance to drift and variability, even
of the phase-change material helps ensure a strong interface for prolonged periods of time after programming. A PCM array
between the lower electrode and the phase-change material. of 64 k cells, cycled 1 million times and then programmed at 4
Such a design can reduce the effective drift coefficient by 6 levels/cell, could be reliably detected more than 45 days later at
[Fig. 18(b) and (c)], resulting in lower error rate for given error rates close to , using permutation modulation coding
retention time with 2-bit-per-cell MLC PCM. This design does and adaptive threshold detection (Fig. 19) [150]. Further en-
reduce the maximum ON-OFF resistance ratio of the PCM cell, hanced robustness to drift has recently been demonstrated in
because the drift benefits only arise when the resistance of the MLC PCM arrays even after exposure to elevated temperatures,
metallic surfactant is lower than that of the amorphous-GST. by employing advanced readout metrics and coding/detection
However, this structure was also shown to greatly reduce the schemes [149].
number of open failures (compared to a version of the cell To a larger extent than other aspects of PCM technology,
without the metal nitride liner) during a write endurance test MLC operation has already incorporated and involved nu-
[72]. merous circuit and systems advances, ranging from customized
The variability of resistance drift causes stored level-distri- circuitry for rapid iterative write to modulation coding for
butions to shift and broaden over time, seriously affecting the drift-resilient coding to new readout schemes that are drift
ability to accurately retrieve previously-stored information. An- resilient. However, numerous opportunities still exist for ad-
other approach to cope with MLC PCM drift and variability vancing the state-of-the-art in MLC for phase-change memory.
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Fig. 20. a) Spike Timing Dependent Plasticity (STDP) as observed in rat hip-
pocampal neurons [159] and b) as observed in mushroom-cell PCM devices. (©
ACM, all rights reserved. Reprinted, with permission, from [154].)
Fig. 19. Adaptive threshold detection schemes show lower error rates as a func-
tion of time on a 64 kcell array (previously exercised through 1 million program-
ming cycles). (Reprinted, with permission, from [150].)
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BURR et al.: RECENT PROGRESS IN PHASE-CHANGE MEMORY TECHNOLOGY 157
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Geoffrey W. Burr (S'87–M'96–SM'13) received
cell storage and retention at elevated temperatures,” in Proc. IEEE Int.
the Ph.D. degree in electrical engineering from
Reliabil. Phys. Symp., 2015.
the California Institute of Technology, Pasadena,
[150] H. Pozidis et al., “Reliable MLC data storage and retention in CA, USA, in 1996, under the supervision of Prof.
phase–change memory after endurance cycling,” in IMW 2013, 2013, Demetri Psaltis.
pp. 100–103. Since that time, he has worked at IBM Re-
[151] H. Pozidis, T. Mittelholzer, N. Papandreou, T. Parnell, and M. search-Almaden, San Jose, CA, USA, where he
Stanisavljevic, “Phase change memory reliability: A signal processing is currently a Principal Research Staff Member.
and coding perspective,” IEEE Trans. Magn., vol. 51, no. 4, p. He has worked in a number of diverse areas, in-
3500107, Apr. 2015. cluding holographic data storage, photon echoes,
[152] D. Kuzum, R. D. Jeyasingh, and H.-S. Wong, “Energy efficient pro- computational electromagnetics, nanophotonics,
gramming of nanoelectronic synaptic devices for large–scale imple- computational lithography, phase-change memory, storage class memory, and
mentation of associative and temporal sequence learning,” in IEDM novel access devices based on mixed-ionic-electronic-conduction (MIEC)
Tech. Dig., 2011, p. 30.3. materials. His current research interests include non-volatile memory and
[153] M. Suri et al., “Phase change memory as synapse for ultra–dense neu- cognitive computing.
romorphic systems: Application to complex visual pattern extraction,” Dr. Burr is a member of MRS, SPIE, OSA, Tau Beta Pi, Eta Kappa Nu, and
in IEDM Tech. Dig., 2011, p. 4.4. the Institute of Physics (IOP).
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BURR et al.: RECENT PROGRESS IN PHASE-CHANGE MEMORY TECHNOLOGY 161
Matthew J. Brightsky received the B.S. degree in He is currently a Research Staff Member with the IBM T. J. Watson Research
physics, mathematics, and astrophysics from the Uni- Center. His current research interests are characterization and modeling of phase
versity of Wisconsin at Madison, Madison, WI, USA, change memory devices for various memory applications such as storage-class
in 1994, and the Ph.D. degree in physics from Iowa memory, embedded memory, and brain-inspired neuromorphic computing.
State University, Ames, IA, USA, in 1999.
He is a Research Staff Member at the IBM T. J.
Watson Research Center, Yorktown Heights, NY,
USA. He was with IBM at the IBM Microelectronics Norma Sosa received the B.S. degree in chemistry/
Center, Essex Junction, VT, USA, where he worked materials science and the M.S. degree in materials
on developing low-standby-power SRAM, and on science and engineering from the University of Cal-
dc and RF compact models for CMOSFETs and ifornia, Los Angeles, CA, USA, in 2002 and 2004,
passive devices. In 2005, he joined the exploratory memory group at the T. respectively, and the Ph.D. degree in materials sci-
J. Watson Research Center and has since worked on integration schemes for ence and engineering from Northwestern University,
phase change memory devices. He is an author or coauthor of 14 patents, 31 Chicago, IL, USA, in 2009.
technical papers, and a book chapter. She has been a Research Staff Member with the
IBM Thomas J. Watson Research Center, Yorktown
Heights, NY, USA, since 2009, where she has worked
on layer transfer techniques of III-V and other semi-
Abu Sebastian (M'03–SM'11) received the B. E. conductors for photovoltaic device applications. Her research interests also in-
(Hons.) degree in electrical and electronics engi- clude phase change memory materials and integration.
neering from Birla Institute of Technology and
Science, Pilani, India, in 1998, and the M. S. and
Ph.D. degrees in electrical engineering from Iowa
State University, Ames, IA, USA, in 1999 and 2004, Nikolaos Papandreou (M'03) received the Diploma
respectively. and Ph.D. degree, both in electrical and computer
He is currently a Research Staff Member at IBM engineering, from the University of Patras, Patras,
Research–Zurich, Switzerland. His research has Greece, in 1998 and 2004, respectively.
spanned several topics broadly related to dynamics From 2005 to 2008 he was Research Associate
and control at the nanometer scale. His research at the Electrical and Computer Engineering Depart-
interests include memory and cognitive technologies and enabling tools ment, University of Patras, Greece, where he worked
for nanotechnology such as nanoscale sensing and nanopositioning. He has in various R&D projects in the areas of digital com-
published over 100 articles on these topics. munications. Between 2006 and 2008, he has also
served as Adjunct Faculty Member at the Computer
Engineering and Informatics Department, University
of Patras, Greece. In 2008, he joined IBM Research–Zurich, Switzerland,
where he is working on non-volatile memory technologies with emphasis
Huai-Yu Cheng received the B.S., M.S. and Ph.D.
on phase-change memory and flash. His research interests include device
degrees in materials science and engineering from
characterization and reliability, signal processing and coding for memory
National Tsing Hua University, Taiwan, in 2001,
channels, next generation storage systems and architectures.
2003, and 2007, respectively.
Dr. Papandreou is a member of the Technical Chamber of Greece.
She joined Macronix International Co., in 2007
and is currently a Senior Researcher based in York-
town Heights, NY, USA.
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162 IEEE JOURNAL ON EMERGING AND SELECTED TOPICS IN CIRCUITS AND SYSTEMS, VOL. 6, NO. 2, JUNE 2016
European patents in the areas of solid-state memory technology, probe-based tions Society Leonard G. Abraham Prize Paper Award. He was also co-recip-
data storage, control systems technology and optical data storage. He is a ient of the 2005 Technology Award of the Eduard Rhein Foundation. In 2005,
Principal Research Scientist, and an IBM Master Inventor. he was appointed an IBM Fellow and inducted into the IBM Academy of Tech-
Dr. Pozidis received the 2009 Control Systems Technology Society Award nology. In 2009, he was co-recipient of the IEEE CSS Control Systems Tech-
and the 2009 IEEE Transactions on Control Systems Technology Best Paper nology Award and of the IEEE Transactions on Control Systems Technology
Award. Outstanding Paper Award.
Evangelos Eleftheriou (S'81–M'86–SM'00–F'02) Chung H. Lam received the B.Sc. degree in elec-
received the B.S. degree in electrical engineering trical engineering at Polytechnic University of New
from the University of Patras, Patras, Greece, in York, in 1978, the M.Sc. and Ph.D. degrees, both in
1979, and the M.Eng. and Ph.D. degrees in electrical electrical engineering, at Rensselaer Polytechnic In-
engineering from Carleton University, Ottawa, stitute, Troy, NY, USA, in 1987 and 1988, respec-
Canada, in 1981 and 1985, respectively. tively.
He joined the IBM Research–Zurich labora-
tory, Rüschlikon, Switzerland, as a Research Staff
Member in 1986. Since 1998, he has held various
management positions and currently heads the Cloud
and Computing Infrastructure department of IBM
Research–Zurich, which focuses on enterprise solid-state storage, storage for
big data, microserver/cloud server and accelerator technologies, high-speed
I/O links, storage security, and memory and cognitive technologies. He holds Since joining IBM, Yorktown Heights, NY, USA, in 1978, he has taken respon-
over 100 patents (granted and pending applications). sibilities in various disciplines of semiconductor research, development, and
Dr. Eleftheriou was Editor of the IEEE Transactions on Communications manufacturing including circuit and device designs as well as process integra-
from 1994 to 1999 in the area of Equalization and Coding. He was Guest Ed- tions for memory and logic applications in IBM's Microelectronic Division. In
itor of the IEEE Journal on Selected Areas in Communications special issues 2003, he transferred to the IBM Research Division at the T. J. Watson Research
“The Turbo Principle: From Theory to Practice” as well as of the IEEE Trans- Center. In 2007, he was named an IBM Distinguished Engineer. Currently, he
actions on Control Systems special issue on “Dynamics and Control of Micro- manages Phase Change Memory Research Joint Projects. He has more than 100
and Nano-scale Systems”. He was co-recipient of the 2003 IEEE Communica- granted U.S. patents and published more than 60 technical papers.
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