09-06-2025

4602CJA101021250004 JA

PART-A-PHYSICS

SECTION-I(i)

1) A parallel plate capacitor has two layers of dielectric as shown in figure. This capacitor is
connected across a battery. The graph which shows the variation of electric field (E) & distance (x)

from left plate.

(A)

(B)

(C)
(D)

2) A parallel plate capacitor is made of two square plates of side 'a', separated by a distance d
(d<<a). The lower triangular portion is filled with a dielectric of dielectric constant K, as shown in

the figure. Capacitance of this capacitor is :

(A)

(B)

(C)

(D)

3) In the circuit shown, the charge on the 3μF capacitor at steady state will be :

(A) 6 μC
(B) 4 μC

(C)
μC
(D) 3μC

4) A parallel plate capacitor has area of each plate as A, the separation between the plates as d and
it is charged to potential V, and then disconnected from the battery. If a dielectric slab, completely
filling the capacitor is introduced, how much work will be done in doing so :

(A)

(B)
(C)

(D)

5) A frame made of thin homogeneous wire is shown in figure. Assume that the number of
successively embedded equilateral triangle with sides decreasing by half tends to infinity. The side

AB has a resistance R . The equivalent resistance between A and B is :

(A) infinite
(B) zero
(C) 2R0

(D)

6) The figure shows a circuit with three ideal batteries.

List (I) contains description of a physical quantity and List (II) contains the magnitude of a physical
quantity in SI unit.

List–I List–II

(P) Current in branch BF (1)

(Q) Current in branch BAGF (2)

(R) Voltage drop between BC (3)

(S) Power dissipated across 4Ω resistor. (4)

(5) None
(A) (P) → (2) ; (Q) → (3) ; (R) → (1) ; (S) → (4)
(B) (P) → (1) ; (Q) → (1) ; (R) → (2) ; (S) → (1)
(C) (P) → (2) ; (Q) → (1) ; (R) → (1) ; (S) → (2)
(D) (P) → (1) ; (Q) → (1) ; (R) → (1) ; (S) → (2)

SECTION-I(ii)

1) Two capacitors are connected to a resistance and battery as given. Capacitor with capacitance C
is charged upto 2V0, where V0 is potential of battery and capacitor of 2C capacitance is initially
uncharged. If switch is closed at t = 0 then choose correct statement(s).

(A) ratio of final charge on C to 2C is 2.

(B)
total work done by battery after switch is closed is .

(C)
total work done by battery after switch is closed is .

(D)
total heat loss across resistance after closing switch is .

2) The given diagram shows a modified meter bridge. The wire AB has uniform resistance used for
measuring two unknown resistances. When the first galvanometer is used for obtaining the balance
point, it is found at point C. Now the first galvanometer is removed and the second galvanometer is
used, which gives balance point at D. Using the details given in the diagram, find out the value of R1
and R2. (Here AB = L ; AC = L/4 and AD = 2L/3)

(A) R1 = R/3
(B) R2= 8R/3
(C) R1 = 5R/3
(D) R2= 4R/3

3) A conducting medium is shaped in a form of a quarter of an annulus of radii 'b' and and
thickness 't'. Specific resistance of the medium is The CORRECT option(s) is/are
 Resistance between faces LMNO and PQRS is
(A)

(B)
Resistance between LMRS and ONQP is
Resistance between faces MRQN and LSPO is
(C)

(D) Between faces LMNO and PQRS and LMRS and ONQP, resistance is same

4) In the circuit shown in the figure, switches S1 and S2 have been closed for a long time, then :-

(A) Charge on the capacitor is 100 μC

(B) Charge on the capacitor is 20 μC
Charge on the capacitor increases to 120 μC if one third of the gap of the capacitor's plates is
(C)
filled with a dielectric (K = 2) of same area.
Charge on the capacitor remains unchanged if one third of the gap of the capacitor's plates is
(D)
filled with a dielectric (K = 2) of same area.

5) The capacitance of a parallel plate capacitor is C when the region between the plate has air. This
region is now filled with a dielectric slab of dielectric constant k. The capacitor is connected to a cell
of emf E, and the slab is taken out

(A) charge CE(k – 1) flows through the cell

(B) energy E2C(k – 1) is absorbed by the cell.
(C) the energy stored in the capacitor is reduced by E2C(k – 1)

(D)
the external agent has to do E2C(k – 1) amount of work to take the slab out.
6) Twelve indentical capacitors each of capacitance C are connected as shown in figure.

The effective capacitance between P and T is

(A)

The effective capacitance between P and U is

(B)

The effective capacitance between P and Q is

(C)

(D) All of the above statements are incorrect

SECTION-III

1)

There are six plates of equal area A and separation between the plates is d (d<<A) are arranged as

shown in figure. The equivalent capacitance between points 2 and 5, is . Then find the value of
a.

2)

The current through a wire depends on time as i = i0 + Ω sin πt, where i0 = 1 A and α = A. Find
the charge crossed through a section of the wire in 3 seconds.

3) The figure shows four identical conducting plates each of area A. The separation between the
consecutive plates is equal to L. When both the switches are closed, if charge present on the upper

surface of the lowest plate from the top is written as ,then what is the value of x ? Treat
symbols as having usual meaning.

4)

The current density at a point is . Find the rate of charge flow (in A) through a

cross sectional area

5) In the given circuit diagram, the current through the 1Ω resistor is given by I amp. Fill 2 I in.

PART-B-CHEMISTRY

SECTION-I(i)

1) major product

(A)

(B)

(C)

(D)
2) Which of the following represents correct major product of the given reaction?

major product

(A)

(B)

(C)

(D)

3) Geometry of reaction intermediate in SN1 reaction is

(A) Tetrahedral
(B) Planar
(C) Triangular bipyramidal
(D) None of these

4) product (P). , P is -

(A)

(B)

(C)
(D)

5) Which of the following is halogen exchange reaction ?

(A) RX + NaI → RI + NaX

(B)

(C)

(D)

6) Conider the reaction

product
The alkene formed in major amount :-

(A) CH3–CH=CH–CH3

(B)

(C) CH3–CH2–CH=CH2
(D) Both (1) and (3)

SECTION-I(ii)

1) The correct statement is-

(A)
Order of reactivity of E1 is as : > >
– – – –
(B) Order of nucleophilicity F < Cl < Br < I (In H2O )

(C)
Order of reactivity of SN2 is as : > >

(D)
Order of reactivity of SN1 is as : > >

2) Which of the following is/are not an example of polar protic solvent?

(A) THF
(B) ROH
(C) DMF
(D) Acetone

3) What could be the product(s) for the following SN1 reaction?

(A)

(B)

(C)

(D)

4) Identify correct reactivity order for various alkyl halides

(A)
> > Me – Cl >
reactivity order with NaI / acetone

(B)

> > Me – I
rate of hydrolysis (SN1)

(C)

rate of E2 reaction with alc.KOH

 > >
(D)

rate of E1 reaction

5)
What is correct about the given reaction.

(A) It is unimoleculer nucleophilic substitution reaction.

(B) Major product obtained by rearranged carbocation.
(C) It is two step process.
(D) Rate of reaction depends on the concetration of alkyl halide and nucleophile.

6) In which product formation takes place according to Hoffmann's rule

(A)

(B)

(C)

(D)

SECTION-III

1) How many of the following will change the colour of KMnO4 / H+ solution ? (i)
(ii) (iii) (iv)

(v) (vi) (vii)

(viii)

2) Correct major product is shown in how many of the following reaction(s)? (A)

(B)

(C)

(D) CH3CH = CH2 CH3CH2CH2Br

(E)

(F)
3)
The ratio x/y on completion of the above reaction is _________.

4) How many reactions are correct ?

5) Number of mole of RMgX required in the following conversion are?

PART-C-MATHEMATICS

SECTION-I(i)
1) The value of tan–1 + tan–1 + tan–1 , where a,b,c ∈ R+ and λ = a + b + c, is equal to

(A)

(B) π

(C)

(D) None

2) If the right hand derivative of f(x) = [x] tan πx at x = 7 is kπ, then k is equal to ([y] denotes
greatest integer y)

(A) 6
(B) 7
(C) –7
(D) 49

3) Number of points of discontinuity of f(x) = in [0, 20] is (where [.] & {.} denote greatest
integer function and fractional part function respectively)

(A) 14
(B) 15
(C) 10
(D) 11

4) Given , then f(x) is discontinuous at x is equal to

(A)

(B)

(C)

(D)

5) Let p, q, r ϵ R+ such that p + q + r = 21, then the value of can not be equal
to

(A) 7
(B) 4
(C) 8
(D) 5
6) Evaluate

(A) e
(B) –e

(C)

(D)

SECTION-I(ii)

1) If , where a ≥ 0 & L is finite number, then

(A) a = 0, L = 1
(B) a = 1, L = e2
(C) 0 < a < 1, L = 0
(D) 0 ≤ a < 1, L = 0

2) If ; a, b > 0 & n ∈ N, then (a + b + n) can be equal to

(A) 3
(B) 2
(C) 4
(D) 8

3) If , then which of the following statement(s) holds good ?

(A) f(x) is continuous at x = 1

(B) f(x) is discontinuous at x = 1

(C) exists finitely

(D) does not exist

4) Which of the following is/are correct ?

(A) |x|(ex – 1) + sin2|x| is differentiable at x = 0

(B) |x – 2| (ℓnx – ℓn2) is differentiable at x = 2
(C) |x – sinx| is differentiable at x = 0
(D) |x| – 2ℓn|x + 2| is differentiable at x = 0
5) For any positive integer n, let Sn : (0, ∞) → R be defined by ,

where for any x ∈ R, cot–1 x ∈ (0, π) and tan–1(x) ∈ .

Then which of the following statements is (are) TRUE ?

(A)
, for all x > 0
(B) , for all x > 0

(C)
The equation has a root in (0, ∞)

(D)
, for all n ≥ 1 and x > 0

6) Let x1, x2, x3, x4 be four non zero numbers satisfying the equation

then which of the following relation(s) hold good?

(A)

(B)

(C)

(D) (x1 + x2 + x3)(x2 + x3 + x4)(x3 + x4 + x1)(x4 + x1 + x2) = abcd

SECTION-III

1) Number of integral ordered pairs (a, b) for which

sin–1(1 + b + b2 +.... ∞) + is

2)

The value of the expression is of

the form (Where A, B are coprime number). Then the value (where [.] denotes the greatest
integer function), is

3) , then f–1(x) is discontinuous at x =

4) If f(x) = x + {–x} + [x], where [x] is the integral part & {x} is the fractional part of x, then the
number of points of discontinuity of f(x) in [–2, 2] is

5) If the equation has three roots where

then the value of is
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. A C B C D C

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,B,D C,D A,B,C A,C A,B,D A,B,C

SECTION-III

Q. 13 14 15 16 17
A. 1 4 3 6 5

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. C C B C A C

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. A,B,D A,C,D A,B A,B,D A,B A,C,D

SECTION-III

Q. 30 31 32 33 34
A. 3 3 2 3 2

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. B B C A C D

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,B,C C,D B,C A,B,C A,B B,C,D
 SECTION-III

Q. 47 48 49 50 51
A. 0 3 2 5 1
 SOLUTIONS

PART-A-PHYSICS

1)

2)

3)
4) Energy stored initially =

& Q = CV =

Energy stored finally =

{∴ Q is same}

W.D. = ΔE

5)

It follows from symmetry considerations that the initial circuit can be replaced by an
equivalent one (Figure). We replace the "inner"

triangle consisting of an infinite number of elements by a resistor of resistance RAB/2, where

the resistance RAB is such that RAB = Rx and RAB = . After simplification, the circuit becomes
a system of series and parallel-connected conductors. In order to find Rx, we write the equation

Solving this equation, we obtain

6)
I= , I1 = I2 =

and power dissipated in 4Ω = .

7)
KVL

charge on 1 =

charge on 2 =
Work done by battery Wb = –qV0

Heat loss = Wb – (Uf – Ui)

=–

8) ⇒ R1 + R2 = 3R ... (i)

⇒ R + R1 = 2R2 ... (ii)

Solving equation (i) and (ii) we get

9) Between faces LMNO and PQRS

Between faces LMRS and ONQP for an element at distance r from O.

So,

10) At

q = 10 × 10
= 100 μC

11)

12)
between P and T
(2,4,5) and (3,6,8) are at same potential

eq = =
(B)
1,2 and 3, 4 at same potential

So Ceq =

(C)
(4,5) and 3,6 at same Potential

eq = =

13)

Redraw the circuit Ceq = C =

14)

i = io + α sin πt.

= 10 + sin πt

q= = 10 × 3 + × × 2 = 31 C
 Average current = = A

15)
C(x – V0) + C(x – 0) + C(x + 4V0) = 0
3Cx = –3CV0

Q=
⇒ x=3

16)

The rate of flow of charge = current = I =

⇒I= = (2 × 104)

17)

=0;
v – 20 + v + 2 (v – 5) = 0 = 4v – 20 – 10 = 0

v= = v

PART-B-CHEMISTRY

18)
19)

20)

In SN1 reaction, intermediate is carbocation (sp2, planar)

21)

22)

Finkel stein reaction is a helogen exchange reaction.

23) Explain Question :

Asking about the major alkene formed in elimination of CH3–CH2–CH(F)–CH3 with CH3O–.
Concept :
E2 elimination reaction.
Solution :
When leaving group is then Hofmann alkene is formed in good yield.
[Attention : Removal of less hindered β-H in Hofmann elimination, priority order of removal of
β-H : 1° > 2° > 3°]

Final Answer : (3)

24)
Sn1, E1 reactivity ∝ stability of carbocation

25)

THF, DMF & acetone are polar aprotic solvents.

26)

27)

28)

In presence of weak nucleophile, given alkyl halide undergo with SN1 mechanism.
So rearrangement of carbocation takes place in given compound.

29) (A) Major product is CH2 = CH – CH2 – CH3 E2 with characters of E1CB.
(B) Major product is CH3– CH = CH – CH3 E2
(C) Major products is CH2 = CH – CH2 – CH3 E2
(D) Major products is CH2 = CH – CH2 – CH3 E2
30) Acidic KMnO4 can only oxidise 1° and 2° alcohols.

31) Correct major products is

(A) Acid catalysed hydration
(B) Oxymercuration-Demercuration
(D) Peroxide effect-Anti Markovnikov addition of HBr.

32)
∴ x = 2 mole

33)

3 (i, ii, iv)

Correct reaction are (i), (ii), (iv)
(iii) Benzylic hydrogen is absent
(v) Racemic mixture is formed

34)
PART-C-MATHEMATICS

35) =

=
=π

36) f(x) = [x] tan πx, f'(7+) = ?

f(x) = 7 tan πx ∀ x∈ [7, 8)

37)
38)

∴ ƒ(x) is discontinuous at 4sin2x = 1

39) Let L = → (1∞ form)

Now apply A.M. ³ G.M.

∴ L cannot be 8

40) Let
41)

42)
if n < 2, then limit D.N.E

if n = 2, then a – b = 0 &

if n > 2, then a – b = 0 &

43)

∵ LHL ≠ RHL
∴ Discontinuous at x = 1.
Similarly

44) |x| (ex – 1) + sin2|x| has repeated roots at x = 0

⇒ differentiable at x = 0
|x – 2| (ℓnx – ℓn2) is differentiable at x = 2
because of repeated roots
|x – sinx| =

= has repeated roots at x = 0

⇒ differentiable at x = 0

45)

Sn(x) = tan–1(nx + x) – tan–1 x = tan–1

(A) = tan–1 = – tan–1 (x > 0)

(B) cot( )= =

(C) = tan–1 = ⇒ ⇒x∉R

(D) tan( )= ;∀n≥1;x>0

We need to check the validity of ∀n≥1;x>0;n∈N

⇒ 2nx ≤ (n + 1) x2 + 1
⇒ (n + 1)x2 – 2nx + 1 ≥ 0 ∀ n ≥ 1 ; x > 0 ; n ∈ N

Discriminant of y = (n + 1)x2 – 2nx + 1 is

and n ∈ N
D < 0 for n = 1 ; true for x > 0
D > 0 for ≥ 2 ⇒ ome x > 0
for which y < 0 as both roots of
y = 0 will be positive.
≥2
So, y ≥ 0 ∀ n ≥ 1 ; ∀ x > 0 ; n ∈ N is false.
46)

47)

Ans. (0)

for above expression to be defined

which is only possible for b = 0

If b = 0

⇒ ⇒
⇒

⇒ (Not integer)
So no integral ordered pairs (a, b) are possible.

48)

=
49)

50)

f(x) = x + [x] + {–x}

Case-1: x ∈ I, f(x) = 2x
Case-2: x ∉ I, f(x) = x + [x]+1–{x}
f(x) = 2[x] +1
f(n) = 2n, f(n+ ) = 2n + 1,f (n–1– ) = 2n – 1
It is discontinuous at every integer in [–2, 2]
Total = 5 integral points

51)