14-12-2024

1001CJA103098240008 JA

PART-1 : PHYSICS

SECTION-I (i)

1) The wire AB of a meter bridge changes linearly from radius r to 2r from left end to right end.
Length of wire is 1m. Where should the free end of the galvanometer be connected on AB so that the

deflection in the galvanometer is zero?

(A)
from end B

(B)
from end A

(C)
from end A

(D)
from end B

2)

There are two parallel plate of surface area A & separation d. Then

(A)
Potential difference between the plates is

(B)
Potential difference between the plates is
(C) If A is earthed, the charge (Q1 + Q2) will flow to earth
(D) If B is earthed, the charge (Q2 – Q1) will flow to earth

3) The following are the P–V diagrams for cyclic processes for a gas. In which of these processes is
heat absorbed by the gas ?
(A)

(B)

(C)

(D)

4) In the following hexagons, made up of two different material P and Q, current enters and leaves
from points X and Y respectively. In which case the magnetic field at its centre is not zero

(A)

(B)
(C)

(D)

5) The position vector of a particle of mass m is given by the following equation ,

–3 –2
where α = 10/3 ms , β = 5 ms and m = 0.1 kg. At t = 1 s, which of the following statement (s) is
(are) true about the particle?

(A) The velocity is given by .

(B) The angular momentum with respect to the origin is given by .

(C) The force is given by .

(D) The torque with respect to the origin is given by .

6) A horizontal plank has a rectangular block placed on it. The plank starts oscillating vertically and
simple harmonically with an amplitude of 40 cm. The block just loses contact with the plank when
the latter is at momentary rest. Then :

(A)
the period of oscillation is
the block weighs double of its true weight, when the plank is at one of the positions of
(B)
momentary rest
(C) the block weighs 0.5 times its true weight on the plank halfway up.
(D) the block weighs 1.5 times its true weight on the plank halfway down.

SECTION-I (ii)

1) Entries in list-I consists of diagrams of thermal conductors. The type of conductor & direction of
heat flows are listed below. Entries in list-II consists of the magnitude of rate of heat flow belonging
to any of the entries in list-I. If temperature difference in all the cases is (T1 – T2), then match list

List-I List-II
 (P) (1) 6πk0R(T1–T2)

Thick cylindrical shell, flow along axis

(Q) (2)

Thick spherical shell, radial flow

(R) (3) πk0R(T1 – T2)

Thick cylindrical shell, radial flow

(S) (4)

Solid cylinder, flow along axis, variable k as

k = k0(1 + x/(3R))

(5) None of these

(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 1;Q → 3;R → 3;S → 4
(C) P → 2;Q → 3;R → 1;S → 3
(D) P → 1;Q → 1;R → 3;S → 2

2) A particle with charge Q is moving in fields of combination given below. Then match the following
:-

List–I List–II

A trajectory of charge particle may

(P) Uniform only (1)
be straight line

A trajectory of charge particle may be

(Q) Uniform only (2)
Parabola

A trajectory of charge particle may be non

(R) Uniform and Uniform (3)
parallel to each other uniform right circular cylindrical helix
 K.E. of charge particle can not be
(S) Uniform and Uniform (4)
perpendicular to each other constant.

(A) P → 1,2,4;Q → 1,2,3;R → 1,3,4;S → 1,4

(B) P → 1,2,4;Q → 1;R → 1,3,4;S → 1,4
(C) P → 1,3,4;Q → 1,4;R → 1,2,4;S → 1,4
(D) P → 1,3,4;Q → 1;R → 1,4;S → 1,4

3) In all cases a uniform, rigid disc of mass M and radius R is made to roll on a horizontal rigid
surface. The surface has two parts AB and BC.

List-I List-II

Friction does not act on the

(P) (1)
disc during BC motion
The disc undergoes
pure rolling motion with constant velocity over AB
part and then it enters BC part

Body undergoes pure

(Q) (2)
rolling motion over BC part
The disc undergoes
pure rolling motion over AB part with constant
velocity. Then it enters BC part.

Friction acts on the body

(R) in backward direction (3)
during BC motion The disc undergoes
pure rolling motion over AB part. A constant force
F = Mg acts horizontally at the centre as shown.
Then it enters BC part.

The body undergoes

(S) forward slipping during BC (4)
motion A constant force F =
Mg acts horizontally at the centre of disc. The disc
undergoes pure rolling over AB part. At instant
when it enters BC part the force F is removed.
 (5) A constant force F =
Mg acts horizontally at the centre of disc and
disc undergoes pure rolling. Then it enters BC
part.

(A) P → 1,2,3,5;Q → 1,2,5;R → 4;S → 5

(B) P → 1,2,4,5;Q → 3,4,5;R → 4,5;S → 5
(C) P → 1,2,4,5;Q → 1,2,3,4;R → 3;S → 5
(D) P → 1,3,5;Q → 1,2,3,4;R → 3,5;S → 5

4)

In the equation X = A sin (ωt + π/4) match the following :

List-I List-II

Kinetic energy at x
(P) (1) Zero
= A/2

Potential energy at
(Q) (2) Maximum
x = A/2

Kinetic energy at x
(R) (3)
=A times the maximum value

Potential energy at
(S) (4)
x=A times the maximum value
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 4;Q → 3;R → 1;S → 2
(C) P → 2;Q → 4;R → 2;S → 3
(D) P → 3;Q → 1;R → 4;S → 1

SECTION-II

1) In the shown planar fame made of thin uniform rods, the length of section AB and EF is ℓ1 and its
linear thermal expansion coefficient is α1. The length CD is ℓ2 and its linear thermal expansion
coefficient is α2. CB and DE are of same length having thermal linear coefficient of expansion is α2. It

is given that = 3.5. Points A, B, E and F reside on same line, that is, section AB and EF overlap.

Find the ratio of for which the distance between end A and F remains same at all temperatures.
2) A thermos contains 140 gm coffee at 80°C. To cool it, we drop two 10 gm ice cubes at 0°C into
thermos. Ice cubes are at 0°C initially. What is the final temperature of the coffee (in °C), if its
specific heat capacity is same as that of water.

3) Two wires of the same material and length but diameter in the ratio 1 : 2 are stretched by the
same force. The ratio of potential energy per unit volume for the two wires when stretched will be :

4) Two moles of a monoatomic ideal gas is taken through a cyclic process shown on pressure (P)
temperature (T) diagram in figure. Process CA is represented as PT = Constant. If efficiency of given

cyclic process is , then find x.

5) Two carnot engine A and B are operated in series. A receives heat at 900K and reject to a
reservoir at temperature T. The second engine B recieve the heat rejected by first engine and in turn
reject heat to a reservoir at 400K. If both the engines have equal efficiency and temperature T is
100α K. Find α.

6) A galvanometer of resistance 40Ω, shunted by a resistance of 50Ω gives a deflection of 50

divisions when joined in series with a resistance of and a 2 volt battery, what is the current
sensitivity of galvanometer (in div/mA) ?

7)

In the given circuit as shown in figure the value of (in Ω) for which current through 4Ω resistor is
zero.

8) Four capacitors and a battery are connected as shown. The potential drop across the
7µF capacitor is 6V. Than find emf 'E' (in Volt) of the battery.

PART-2 : CHEMISTRY

SECTION-I (i)

1) Compound which gives alcohol on reduction is/are

(A)

(B)

(C)

(D)

2) In the above reaction

the using reagents X and Y are ;

(A) Na/ liq. NH3 for X

(B) H2, Pd/ BaSO4 for Y
(C) NaBH4 for X
(D) All of these are correct

3) 12.2 gm of sodium salt of weak monobasic acid (Ka = 10–6) is dissolved in 100 ml of water and pH
of resulting solution is found to be 10 at 25ºC. Then which of the following is corrrect
(A) Molar mass of salt is 122 gm/mole
(B) pH of solution when 1 gm of same weak acid is dissolved in 1 litre of of water is 4
–8
(C) Kb of conjugate base of same weak acid is 10
(D) Molar mass of conjugate base of same weak acid is 99

4) 100 ml of 0.5M hydrazoic acid (HN3, Ka = 3.6 x 10–4) and 400ml of 0.1M cyanic acid
(HOCN, Ka = 8 x 10–4) are mixed. which of the following is (are) true for the final solution?
(Assume α < < 1 for both acids)

(A) [H+] = 10–2

(B) = 3.6 x 10–3
(C) [OCN–] = 4.571 x 10–3
(D) [H+] = 1.4 x 10–2

5) Which of the following statement(s) is/are correct?

+
(A) Permanganate ion at [H ] = 1 significantly oxidizes H2O to O2 at low temperature.
(B) Permanganate titrations are unsatisfactory in presence of HCl.
Intense color and temperature dependent paramagnetism of KMnO4 can be explained by
(C)
valence bond theory.
(D) Acidified KMnO4 oxidizes KI to I2.

6) Find the INCORRECT order among the following?

(A) Bi+5 > Bi+3 (Stability)

(B) SO2 > SO3 (Acidic nature)
(C) Tl3+ > In3+ (Oxidizing power)
(D) CaO > MgO (Lattice energy)

SECTION-I (ii)

1)

List - II
List - I
(Type of reaction/intermediate
(Chemical reaction)
involve)

(P) (1) Elimination reaction

(Q) (2) Addition reaction

 Carbocation intermediate is
formed
(R) (3)
[Classical /Non classical]

(S) (4) Rearrangment reaction

(5) Racemic mixture is formed

(A) P → 3,4;Q → 2,3;R → 3,5;S → 1,3
(B) P → 1,3;Q → 3,4;R → 3,4;S → 2,3,5
(C) P → 1,3;Q → 3,4;R → 2,3,5;S → 3,4
(D) P → 1,3;Q → 3,5;R → 4,5;S → 2,5

2)

List-I List-II

(P) Propan-2-ol + 2-methyl propanol (1) Maximum boiling azeotrope

(Q) H2O + HNO3 (2) Raoult's law is obeyed

(R) CS2 + CH3COCH3 (3) Positive deviation from Raoult's law

Fractional distillation column gives azeotrope from

(S) H2O + HCOOH (4)
residual liquid

(5) Mixture form ideal solution.

(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 3;Q → 1;R → 3;S → 2
(D) P → 2;Q → 4;R → 1;S → 3

3)

List-I List-II
(Reactions) (Observations)

(P) CrO5 (on standing (1) Redox reaction

(Q) (2) Evolution of O2 is associated

Green colour
(R) (3) solution/compound is formed
as product

Orange/Yellow colour
(S) (4) solution/compound is
formed as product
The correct option is :-
(A) P → 3,4;Q → 1,4;R → 2,4;S → 1,2,3,4
(B) P → 1,2;Q → 2,4;R → 1,2,3;S → 1,2,4
(C) P → 1,2,3;Q → 1,3;R → 1,3;S → 1,2,3
(D) P → 3,4;Q → 1,2,3;R → 2,3,4;S → 2,3,4

4) Match the following:

List–I List–II

(P) [CoCl3(NH3)3] (1) show facial form

3–
(Q) [Cr(Ox)3] (2) cis form is optically active

(R) [CrCl2(Ox)2] (3) Trans form is optically inactive

(S) [RhCl3(Py)3] (4) show meridional form

(5) chelate complex (5 - membered)

Select the most appropriate match.
(A) P → 1,2,4;Q → 2,4;R → 3;S → 1,4,5
(B) P → 1,2,4;Q → 2,5;R → 2,3;S → 2,3
(C) P → 1,4;Q → 2,4;R → 2,3,5;S → 1,2,4
(D) P → 1,4;Q → 5;R → 2,3,5;S → 1,4

SECTION-II

1)
How many (x) moles of HI consumed in the given reaction?

2) Number of reactions in which aldehyde can be obtained as one of the product.

(i) CH3–CH2OH (ii) CH3–CH2–CH2–OH

(iii) (iv)

(v) (vi) CH3–CH=NH

(vii) (viii) CH3–CH=CH–CH3

(ix)

3) Number of reactions which gives 2º alcohol as a major product :

(a) (b)

(c) (d)

(e) H3C – HC = CH2 (f)

4) What is the pH of 0.1M NaHCO3? K1 = 4.5 x 10–7, K2 = 4.5 × 10–11 for carbonic acids.
Take : log 4.5 = 0.64

5) 0.8 M FeSO4 solution requires 160ml, 0.2M Al2(Cr2O7)3 in acidic medium, Calculate volume (in ml)
of FeSO4 consumed -

6) For the reaction

2A(g) + 3B(ℓ) C(g) + 4D(ℓ) ; ΔH = 300 cal/mol
calculate ΔU (in calorie) of reaction when 3 moles of A(g) react with 4 moles of B(ℓ) at 27°C
(R = 2cal/mol-K)

7) Number of ions/species which convert acidic solution of KMnO4 (Purple) to Mn+2?

CO2 , , Sn+2 , I– , F– , Fe+2 , C2H5OH , H3PO3 , H2O2 ,

8) How many of the following have positive ?

3+ 2+ 3+ 2+
(1) Fe (aq) → Fe (aq) (2) Co (aq) → Co (aq)
(3) Mn3+ (aq) → Mn2+ (aq) (4) Cr3+ (aq) → Cr2+ (aq)
(5) Cu2+ (aq) → Cu(s)

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let a point 'R' be between P(1, 0) and Q(e, 1) on the graph of y = ℓnx such that the tangent to the
graph at a point 'R' is parallel to the line through points P and Q then of the following option(s)
is(are) correct ?

(A) x co-ordinate of the point 'R' is e – 1

(B)
x co-ordinate of the point 'R' is

(C)
if the equation of tangent at R is y = f(x) then
(D) normal at P for y = ℓnx intersect y = ex at (0, 1)

2) If A = and B = . (where arg(z) represents

principle value of argument of z & C denotes set of all complex number), then choose correct
statement

(A) A ∩ B represent complex number lying inside or on the boundary of segment of circle.
Area of region belongs to A ∩ B is equal to
(B)

(C)
Area of region belongs to A ∩ B is equal to
(D) Area of region bounded by region B is π.

3) If and are unit vectors such that and , then

(A) are coplanar if λ = 1

(B) angle between and is 30° if λ = –1
(C) angle between and is 150° if λ = –1
(D) if λ = 1 angle between and is 60°

4) If point (4, 4) lies on parabola whose focus lies on x-axis and directrix is ℓx + my = 1 such that (ℓ,
m) lies on curve x2 + y2 – 32xy + 8x + 8y – 1 = 0 then :

(A) co-ordinates of focus may be (5, 0)

(B) co-ordinates of focus may be (3, 0)
If tangent at (4, 4) passes through origin, value of m may be
(C)

(D) If tangent at (4, 4) passes through origin, equation of axis may be x – 4y – 3 = 0

5) The sum of infinite terms of series

is

(A) cot–1(1)
(B) tan–1(2)

(C)
(D) cot–1(1) + cot–1(3)

6) If α, β, γ are roots of the equation x3 – 3x + 1 = 0, then

(A) (α + β) (β + γ) (γ + α) = –1
(B) α2(β + γ) + β2(γ + α) + γ2(α + β) = 3
(C) (α + 1) (β + 1) (γ + 1) = –3
(D) α4 + β4 + γ4 = 18

SECTION-I (ii)

1) Let , where a, b > 0 be a hyperbola in the xy-plane whose centre is C, one of the
foci is F1. Foot of perpendicular from F1 upon line L : bx – ay = 0 is P. Triangle CF1P is an isosceles
triangle whose area is 8 sq. units.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) The length of transverse axis of H is (1)

(Q) The eccentricity of H is (2) 1

(R) The slope of L is (3) 4

(S) The distance between directrices of H is (4)

(5) 8
(A) P → 4;Q → 5;R → 2;S → 1
(B) P → 5;Q → 4;R → 2;S → 1
(C) P → 5;Q → 4;R → 2;S → 3
(D) P → 5;Q → 3;R → 2;S → 1

2) Let two lines be and , then

List-I List-II

(P) If β = 4 and α ∈ R – {1} (1) Non coplanar lines

(Q) If β = 4 and α = 1 (2) Coplanar lines

(R) If β ∈ R –{4} and α = 1 (3) Lines lie in a unique plane

(S) If β ∈ R – {4} and α ∈ R – {1} (4) Infinite planes containing both the lines

(5) Lines do not intersect

(A) P → 2,4;Q → 2,3,5;R → 1,5;S → 3
(B) P → 2,3,5;Q → 2,4;R → 2,3;S → 1,5
(C) P → 1,5;Q → 2,3;R → 2,4;S → 3,4,5
(D) P → 1,4,5;Q → 1,3;R → 4,5;S → 2,4
3) Match the statement in List-I with given value in List-II

List-I List-II

(P) (1)
is equal to

(Q) (2)
is equal to

(R) (3)

, where [.] and {.} denotes greatest

integer and fractional part function, is equal to

(S) (4)
, where [.]
denotes greatest integer function equal to
(A) P → 2;Q → 4;R → 2;S → 3
(B) P → 2;Q → 3;R → 1;S → 4
(C) P → 2;Q → 4;R → 3;S → 2
(D) P → 3;Q → 2;R → 4;S → 4

4)

List-I List-II

(P) f(x) = (x + 1) |(x – 1)| is not differentiable at x equals to (1) 5

(Q) (2) 2
If , then value of n is

f(x) = min{|x|, 1 – |x|}, is not differentiable at 'p'

(R) (3) 1
points, then p is equal to

(S) If then value of is (4) 3

equal to

(5) Prime number

(A) P → 1,5;Q → 3;R → 2,5;S → 4,5
(B) P → 3;Q → 1,5;R → 4,5;S → 2,5
(C) P → 3;Q → 4,5;R → 1,5;S → 2,5
(D) P → 4,5;Q → 2,5;R → 3;S → 1,5

SECTION-II
1) The ellipse is such that it has least area but contains the circle (x – 1)2 + y2 = 1. If
eccentricity of ellipse is e, then the value of 3e2 is equal to

2) Shortest distance between z-axis and the line , is

3) Let , if the maximum value of is M then the

value of is

4) Length of common chord of two circles of radii 3 and 4 which intersect orthogonally is ℓ, then
is

5) If (where C is constant of integration), then the

value of (3a + b) is equal to

6) Let f(0) = f ′ (0) = 0 and f ″ (x) = tan2x, then the absolute value of f(π) is

7) If and , then the value of , is

8) Let two points A(–6, 0) and B(0, 8). If C is a point on line x – y = 0 so that AC + BC is least, then

value of is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,B A,C A,B,C A,B A,D A,B,C,D

SECTION-I (ii)

Q. 7 8 9 10
A. A B C B

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 0.57 60.00 16.00 0.35 6.00 6.00 0.20 30.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,C,D A,B A,B,C,D A,B B,D A,B,D

SECTION-I (ii)

Q. 25 26 27 28
A. B B C D

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 2.00 9.00 5.00 8.36 720.00 1200.00 7.00 4.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,C,D A,B,D A,C A,B,C,D B,D B,C,D

SECTION-I (ii)

Q. 43 44 45 46
A. B B C B
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 2.00 2.00 5.00 5.00 25.00 4.92 6.00 7.00
 SOLUTIONS

PART-1 : PHYSICS

1) where y =

we know that resistance of non uniform cross section area =

so let at distance x from A. null point enist.
R1 = R2

2)

ΔV = |E · d| =

If B is earthed VB = 0

3)

Fig A : WA = +ve Fig B : WB =+ve

Fig C : WC = +ve Fig D : WD = –ve
∴ In process Fig–(D), heat is released.

4)

Magnetic field at the center will depends upon current division in upper and lower branch
current will depends upon material. Now we would calculate total length in upper branch and
lower branch. If both lengths are same then net magnetic field will be zero.
In case of A and B
(A) Total wire in upper branch = 1P + 2Q
Total wire in lower branch = 2P + Q
So net magnetic field will not be zero

(B) Total wire in upper branch =

Total wire in lower branch

So Net magnetic field will not be zero

(C) Total wire in upper branch =

Total wire in lower branch =

So net magnetic field will be zero

(D) Total wire in upper branch =

Total wire in lower branch =

So net magnetic field will be zero.

5)

(A)

(B)

(D) ; t = 1 sec.
6) The position of momentary
rest in S.H.M. is extreme position where velocity of particle is zero.
As the block loses contact with the plank at this position i.e. normal force becomes zero, it has
to be the upper extreme where acceleration of the block will be g downwards.

∴ ω2A = g ⇒ ω2 = = 25 ⇒ ω = 5 rad/s

Therefore period T = = s
Acceleration in S.H.M. is given by a = ω2x
From the figure we can see that,At lower extreme, acceleration is g upwards
∴ N – mg = ma ⇒ N = m (a +g) = 2mg
At halfway up, acceleration is g/2 downwards

∴ mg – N = ma ⇒ N = m (g – ) = mg
At halfway down acceleration is g/2 upwards

∴ N – mg = ma ⇒ N = m (g + )= mg

7) (A) =
= πRk0(T1 – T2)

(B) =

= (T1 – T2)
=

(C) = =

0
(D) = –πR2k · = –πR2k

2
∴ = = –πR k

0
2
= = πR k (T1 – T2)

∴ =

8) (P) Uniform E only → path may be straight line (when in direction of motion or opposite),
parabola (where and are in different direction) Uniform E only → V always changes.
(Q) Uniform B → path may be straight line.
(R) If E & B are parallel → V must be change, known uniform helix or straight line.
(S) If E are ⊥ → Straight line or cuboid path.

10)

11) We have distance between

AF = ℓ1 + ℓ1 – ℓ2 = 2ℓ1 – ℓ2
Since it must be independent of temperature
∴ 2(ℓ1)(1 + α1ΔT) – ℓ2(1 + α2ΔT) must have co-efficient of ΔT as zero
∴ 2ℓ1α1 = ℓ2α2

12) 140 × 1(80 – T) = 10 × 80 × 2 + 20 × 1 (T – 0)

140 × 80 – 1600 = 160 T
T = 60°C

13)

PE (per unit volume) =

PE ∝ 1/A2

14)

For process AB
TA = 300 K, TB = 600 K
W = nRΔT = nR(TB – TA) = 300nR = 600 R

Q = nCpΔT = 2 × R (300) = 1500 R

For process BC

W = nRTℓn = nRTℓn
= 1200 Rℓn2
Q = W = 1200 Rℓn2
For process CA

Q = nCVΔT + W
= –900R – 1200R = –2100R

15) n1 = n2

16)

Sensitivity = = 6000 div/A = 6div/mA

17)
By Kirchoff
10 – 2i – R(i – i1) – 4 = 0

i= ...(i)
10 – 2i – 6 = 0
i = 2 ...(ii)
by equation (i) & (ii)
R = 1Ω

18)

Q1 : Q2 = 2.1 : 3.9
 Q = Ceq . E

Q = 120µ
120 = 4 E
E = 30 V

PART-2 : CHEMISTRY

19)

21) 10 = [14 + 6 + log ]

20 = 20 + log ⇒ M = 122

22) &

23)

NCERT Based.

26) (P) Propan-2-ol + 2-methyl propanol

A B
attraction are equal between A-A, A-B, B-B
so follow to Raoult's law
mixture form ideal solution
(Q) H2O + HNO3
A B
A–B > A–A and B–B
option P,S
show –ve deviation from raoult's law so maximum boiling azeotrope
fractional distillation column gives azeotrope from residual liquid.

(R)
Attraction of A–B < A–A and B–B
hence it show +ve deviation from raoults law option - R

(S)
 A–B > A – A & B–B
show –ve deviaton from raoult's law maximum boiling azeotrope fractional distillation
column gives raoult's azeotrope from residual liquid
PS option
Q. 115, 118, 120, 122, 124

27) (A)

(B)
(C) MnO2 + conc. KOH + O2 K2MnO4 + H2O
(D)

29)

30) Theory based.

31)

a, b, c d, e

32) = 8.36

33) 0.8 ×
V = 720 ml

34) 3 mole 4 mole

2A(g) + 3B(ℓ) → C(g) + 4D(ℓ)
ΔH = ΔU + ΔngRT
For 1 mole reaction ; Δng = (1 – 2) = –1
= 300 – (–1) × 2 × 300 = 900 cal / mole

900 × cal = 1200 cal

PART-3 : MATHEMATICS
37)
Let R point is (x1, y1) then

= Slope of PQ

or
Now for option (C)
Area under tangent > Area under curve
for option (D)
Equation of normal at 'P' (1, 0) is x + y = 1 which is passing at (0, 1)

38)
Answer is obvious from the graph.

39) ⇒
sinθ1.sinθ2.cosθ = λ

θ1, θ2, θ ∈ [0, π]

Given ⇒
C-1 : λ = 1
sinθ1sinθ2cosθ = 1

; ; θ=0

Angle between and on be 120° or 60° and are coplanar

C-2 : λ = –1
 sinθ1sinθ2cosθ = –1

; ; θ=π

40) SP = PM

But given that

∴ α = 5 or 3
Take focus (3, 0)
Equation of directrix ℓx + my = 1 satisfies (0, 3) i.e. mirror image of
focus through tangent y = x
0 + 3m = 1

slope of line joining (0, 3) and (4, 4) is which is parallel to axis.

∴ Equation of axis y – 0 = (x – 3)
⇒ x – 4y – 3 = 0

41)

∴
Also

⇒ = cot–1(1) + cot–1(3)

but

42) We have
α + β + γ = 0, αβγ = –1
& αβ + βγ + γα = –3
(A) (α + β)(β + γ)(γ + α) = –γαβ = 1
(B) α2(–α) + β2(–β) + γ2(–γ)
= –(α3 + β3 + γ3) = –3αβγ = 3
(C) x3 – 3x + 1 = (x – α)(x – β)(x – γ)
put x = –1
(D) x3 – 3x + 1 = 0 ; x = α, β, γ
⇒ x4 – 3x2 + x = 0
Putting x = α, β, γ and adding
α4 + β4 + γ4 = 3(α2 + β2 + γ2) – (α + β + γ)
= 3[(α + β + γ)2 – 2(αβ + βγ + γα)]
= 18

43)
Length of perpendicular from F1(ae, 0)
upon bx – ay = 0 is equal to

F1P =

44) If
⇒ β = 4, then lines are parallel.
If β = 4 and the point on L2(3, 5, 5) satisfy L1, then the lines area identical otherwise lines are
not identical.

∴ ⇒α=1
If β ≠ 4, then lines are not parallel.

D = (1 – α)(3β – 12) = 3(α – 1)(β – 4).

If D ≠ 0 lines are skew ⇒ α ≠ 1.
If D = 0 lines area intersecting ⇒ α = 1

45) (P) I =

2I = =

∴I=

(Q)
x = sinθ ⇒ dx = cosθ dθ

(R) =

(S) ⇒ ⇒ [cosx + [secx]] = 1

⇒ [sinx + [cosx + [secx]]] =1 ⇒ [tanx + [sinx + [cosx + [secx]]]] = 1

46) (P) f(x) = (x + 1)|x – 1| is

not differentiable at x = 1

(Q)

(R)
(S)

47) For least area, circle must touch the ellipse solving the two equations

(b2 – a2)x2 + 2a2x – a2b2 = 0

D=0
∴ a2 + b2(b2 – a2) = 0 ....(1)
Also b2 = a2(1 – e2) ....(2)
∴ a2 + b2(–a2e2) = 0

thus

Area =
f(e) = e4 – e6
f ′ (e) = 4e3 – 6e5 = 0
2e3(2 – 3e2) = 0

48) equation of any plane containing the general plane is

....(1)

Therefore plane, parallel to z-axis is y + 2 = 0 ....(2)

Now, shortest distance between any point on z-axis (0, 0, 0 ) (say) from plane (2) is 2

49) Let

(z – y)
(z – y)2
maximum value is 15

50)
ℓ = 2(4sinθ)

51)
x = t2
a = 6, b = 7

52) f ″ (x) = tan2x = sec2x – 1

f ′ (x) = tanx – x + c
f ′ (0) = 0 ⇒ c = 0
f ′ (x) = tanx – x

f(x) = logesecx
f(0) = 0 ⇒ c = 0

53) If ;

then the value

RHL = f(g(1+)) = f(>2)
= 22 + 2 = 6
LHL = f(g(1–)) = f(>2)
= 22 + 2 = 6

So =6

54)
Reflection of B about line x – y = 0 is B ′ (8, 0) For (AC + BC) to be least point 'C' is
intersection of AB′ and y = x i.e. (0, 0) hence least value of AC + BC is 14