Chapter 10 discusses the stack as a last-in, first-out (LIFO) storage structure used in embedded systems, emphasizing its dynamic memory allocation capabilities and addressing in microcontroller data memory. It also covers subroutines, which are reusable pieces of code that enhance program efficiency by allowing jumps to specific tasks and managing return addresses via the stack. The chapter includes practical examples for implementing and debugging stack operations and subroutines in assembly programming.