Solutions of Assignment Level-II Structure of Atom

Chapter 1 Level-II

Structure of Atom
SOLUTIONS
SECTION - A

Objective Type Questions (One option is correct)

1. Answer (2)

e
Angle of deflection is directly proportional to .
m

2. Answer (1)

K.E.
  0 
r

For Cs, ν0 is minimum.

3. Answer (4)

hn1 = hn0 + KE1

or, hn1 = hn0 + KE1

KE1 = h(n1 – n0) …(i)

and KE2 = h(n2 – n0) …(ii)

(i) ÷ (ii),
K.E1 K
< = F
K.E 2 1

K 1  0

1  2  0

K 2  1
\ 0  d n
K1

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24 Structure of Atom Solutions of Assignment Level-II

4. Answer (2)

In two and two path is possible.

4 → 3 4→2

3 → 2 2→1

2→1

5. Answer (1)

Atomic spectrum are line spectrum.

6. Answer (3)

According to de Broglie equation,

h

mv
7. Answer (1)

Splitting in 2p orbitals takes place.

8. Answer (4)

p, d & f orbital have zero probability at nucleus surface.

9. Answer (4)

For all orbitals 4πr2dr.ψ2 is zero at surface of nucleus.

10. Answer (2)

At 2a0, 2  0

11. Answer (3)

Due to its shape.

12. Answer (3)

For hydrogen, in 2nd shell, four fold degeneracy is present.

13. Answer (1)

Electrons

n = 3, l = 2, m = +2 2

14. Answer (2)

1s2 2s1 2p6 3d5 is not allowed because in 2s there should be 2 electrons i.e. 2s2

15. Answer (1)

n (n  2)  4.9
n(n + 2) = 24

n2 + 2n – 24 = 0

(n + 6) (n – 4) = 0
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Solutions of Assignment Level-II Structure of Atom 25

n=4

4 unpaired electrons

h h
l ( l  1)  6
2 2
l=2

⇒ last subshell is d subshell, highest value of n is 3.

A+3 contains 4 unpaired electron.

Possible subshells

1s 2s 2p 3s 3p 4s 3d

Unpaired in A+3 = 4

In removal of total, 3e–, 2e– will be removed from 4s and 1e– from 3d.

3d must contain 4 unpaired e– in A+3.

A+3 = 1s2 2s2 2p6 3s2 3p6 3d4

A = 1s2 2s2 2p6 3s2 3p6 3d5, 4s2

Z = 25

Element is Mn.

SECTION - B

Objective Type Questions (One or more than one option(s) is/are correct)

1. Answer (1, 2, 4)
Nature of anode rays (not cathode rays) depend on nature of gas taken in discharge tube.
Anode rays sputter when incident on metal.
For different gases, charge on particles produced is different, hence deflection will be different.
2. Answer (1, 2, 3)
Kinetic energy ∝ frequency.
Number of photoelectrons µ Intensity.
Photoelectric current µ Intensity.
If frequency of incident light is less than threshold, photoelectron cannot be emitted by increasing
intensity of light.

3. Answer (1, 2, 3)
2
n
rn = a0 #
z
72 12
r7  r1  a0 #  a0 # = a0 (49 – 1) = a0. 48
1 1

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26 Structure of Atom Solutions of Assignment Level-II

2 2
6 1
r6  r1  a0 #  a0 # = a0 .35
1 1
52 12
r5  r1  a0 #  a0 # = a0 .24
1 1
4. Answer (1, 2, 3)

KE will be positive and isotopes have different ionization energies.

5. Answer (1, 3)
6 (6 − 1) 30
Total emission lines = = = 15
2 2

6. Answer (1, 2, 3, 4)

For He+ (Z = 2)
1
Lines of Balmer series are observed in U.V. region d ? z2 n .

7. Answer (1, 3)

2pr3 = nl

n2
2a0 #  n
Z
32
2a0 #  3
1
l = 6pa0

l = 6px  a0 = x
h

mv
h h
v 
m 6xm
8. Answer (1, 2, 4)

2pr = nl

2 r 2 # 3.14 # 0.529
 =
n 1
⇒ l = 3.32 Å

For 2nd orbit,

n2
n = 2 , r = a0 #
Z

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Solutions of Assignment Level-II Structure of Atom 27

a0 = 0.529

n2
2 a 0 #
Z n2
  d a r = a0 # n
n Z

2a0 n
  = 3.32 n
Z

l = 3.32 × 2 = 6.64 Å

For n = 3,

l = 3.32 × 3 = 9.96 Å

For n = 6,

l = 3.32 × 6 = 19.92 Å

9. Answer (1)

10. Answer (1, 3)

Cr (24) = 4s1 3d5

Cr+3 = 3d3

Fe (26) = 4s2 . 3d6

Fe+3 = 3d5

Co(27) = 4s2 3d7

Co+2 = 3d7

Ni (28) = 4s2 3d8

Ni+2 = 3d8

Cr+3 and Co+2 have same number of unpaired electron, hence, same magnetic moment.

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28 Structure of Atom Solutions of Assignment Level-II

11. Answer (1, 2, 4)

Fact.

12. Answer (2, 3)

n – l –1 = no. of radial nodes;

l = no. of angular nodes.

n – 1 = Total no. of nodes

n – l – 1 = l ⇒ n – 1 = 2l

13. Answer (1, 2, 3)

Those orbitals do not exist for which n # l .

14. Answer (2, 4)

h h
l ( l  1) 2 3 '2 3
2 2
l(l + 1) = 12

l 2 + l – 12 = 0

(l + 4) (l – 3) = 0

l = 3 ⇒ f subshell

f subshell has 7 degenerate orbitals.

L  l (l  1) BM

3.46  l (l  1)

11.97 = l(l + 1)

l(l + 1) = 12

l2 + l – 12 = 0

(l + 4) (l – 3) = 0

l = 3 ⇒ f subshell has

f subshell has 7 degenerate orbital.

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Solutions of Assignment Level-II Structure of Atom 29

15. Answer (2, 3)

The given electronic configuration violates Hund’s rule and Aufbau principle. Therefore, it does not
represent ground state electronic configuration of any atom.

SECTION - C
Linked Comprehension Type Questions

Comprehension-I

1. Answer (1)
1 1 1
 Rd  n
 4 9

1 R#5

 36

36

5R

36

5 # 1.097 # 10 7

l = 6.563 × 10–7m

l = 6563 Å

2. Answer (2)

Balmer series belong to visible region.

3. Answer (4)
1 1 1
 RZ 2 d 2  2 n …(i)
1 1 2
1 1 1
 RZ 2 d 2  2 n …(ii)
2 5 6

Divide equation (i) by (ii),

1
1
2 4

1 1 1

25 36

11
1 25 # 36

2 3
4
1 11 4
 #
 2 25 # 36 3

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30 Structure of Atom Solutions of Assignment Level-II

1 0.0163

2 1

l1 : l2 = 0.0163 : 1

Comprehension-II
1. Answer (1)
s-orbital is non-directional.
2. Answer (2)
Sign represent sign of wave function.
3. Answer (3)
For p-orbital, at nucleus surface, Y2 is zero.

Comprehension-III
1. Answer (4)
On the basis of (n + l) rule.
2. Answer (1)
In hydrogen energy depend on n only.
3. Answer (1)
Spin of E.C. should be maximum.

SECTION - D
Matrix-Match Type Questions

1. Answer A(s), B(r), C(p), D(q)

Cosmic rays have lowest wavelength.

2. Answer A(p), B(r), C(q), D(s)

Radial nodes = (n – l – 1)

3. Answer A(r), B(s), C(q), D(p)

Use electronic configuration.

4. Answer A(s), B(r), C(q), D(p)

d5 has 5 unpaired electrons.

d9 has 1 unpaired electrons.

d10 has 0 unpaired electrons, so colorless.

d6 has 4 unpaired electrons.

1
⇒ 4 # c m  2 = Total spin.
2

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Solutions of Assignment Level-II Structure of Atom 31

SECTION - E
Assertion-Reason Type Questions

1. Answer (4)
h

mv
1
mv 2 = KE
2
mv2 = 2KE

m2v2 = 2mKE

mv = 2mKE

h

2mKE
1
?
KE
Hence, as KE decreases, l increases.
2. Answer (2)
Fact
3. Answer (2)
Both the statements are correct.
4. Answer (2)
If (n + l) is same, then higher will be value of n, higher will be energy.
5. Answer (1)
p subshell has 3 orbitals and each orbital can take 2 electrons, hence, total 6 electrons can be
accommodated.
A subshell has 2l + 1 orbitals and each subshell can have 2e–, hence total number of electrons
= 2(2l + 1)
= 4l + 2
For p subshell, l = 1
6. Answer (1)
Factual.
7. Answer (2)
Fact
8. Answer (4)
Cr → 4s1 3d5
Cr+3 → 3d3
Sc → 4s2 3d1
Both configuration are different from each other.
Orbitals of atom are filled in increasing order of energy – Aufbau rule

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32 Structure of Atom Solutions of Assignment Level-II

SECTION - F
Integer Answer Type Questions

1. Answer (3)

2. Answer (6)

1 1
= G
18
E  2.18 # 10 2

n 1 n 22
1 1
18.16 # 10
20
 2.18 # 10 18 <  2 F
9 n
On solving n = 6

3. Answer (3)

1
?
KE

2 KE1

1 KE 2

4. Answer (6)

The atom have E.C. 3d64s2.

5. Answer (5)

I = 4 for g-subshell

Thus, the subshell will first appear in (n = I + 1 = 5) 5th shell.

h h
Angular momentum ^mvr h  n 5
2 2
∴ x=5

6. Answer (0)

Radial nodes = n – l – 1

7. Answer (5)

Electron is in 5s orbital.

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Solutions of Assignment Level-II Structure of Atom 33

SECTION - G
Previous Years Questions

1. Answer (C)

Centripetal force = Coulombic force of attraction

mV 2 KZe
2

=
r r2
KZe 2
V2 =
mr

nh
V=
2mr
2 2
n h
V2 =
42 m 2 r 2
2
KZe 2 n2 h2 h2 n 2 a0 n
∴  ⇒ r  e o 
mr 42 m 2 r 2 42 mKe 2 Z Z

hZ
Vn =
2ma0 n
2 2 2
1 h Z h
K.E. = mv n2  ; K.E. (for x = 2 and Z = 1) =
2 82 ma 02 n 2 322 ma 02

2. Answer (A)

Radial probability function curve for 1s is

Here ‘P’ is 4r 2  r2 dr

3. Answer (A, C)
2
Z
En = –13.6 # eV
n2
22
∴ 3.4 eV = –13.6 # ⇒ n=4
n2
n = 4, l = 2, m = 0 belongs to 4d orbital
Number of angular nodes in an orbital = value of l
Number of radial node in 4d = 1
Since it is a unielectronic species, there will be no shielding and the nuclear charge felt will be 2e.

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34 Structure of Atom Solutions of Assignment Level-II

4. Answer (B)

S1 state is 2s

In 2s, one radial node is present.

5. Answer (C)

Energy in S1 state

–13.6 # 3 2 9
=
E = – 13.6eV
2 2
4
E( H ) = –13.6 eV [Ground state]
1
1

So, energy = 2.25 × energy of e– in ground state in 1H1

6. Answer (B)
S2 state is 3p orbital.
Orbital angular momentum of 3p is 1.
7. Answer A(q, r); B(p, q, r, s); C(p, q, r), D(p, q)
8. Answer (D)
1s orbital is nondirectional so ψ will not depend upon cosθ.
Hence, 'D' is incorrect.
9. Answer (D)
For H-like species only D is correct, because
in (A), 1s orbital has no radial node.
In (B) for 3d z , xy plane is not nodal plane.
2

In (C), 2pz orbital has no radial node.

10. Answer (D)
For H-atom,
3
Z 2 d Zr n
1s-orbital ?d n e a 0
a0
3
Also, E 4  E 2 
16
2
E6  E 2 
9
27
Hence, (E6  E 2) #  E4  E2
32
11. Answer (A)
1
Kinetic energy ∝
n2
1
Potential energy ∝
n2
∴ Correct match : (III), P ; (IV), P

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Solutions of Assignment Level-II Structure of Atom 35

12. Answer (D)

In Bohr’s model

Radius ∝ n2

Angular momentum ∝ n
1
Kinetic energy ∝ 2
n
1
Potential energy ∝ 2
n
∴ Correct match : (I), (T) ; (II), (S)

13. Answer (4)

Energy of incident photon should be higher than work function to slow photoelectric effect.
34
6.62×10 ×3×10 8
Energy of photon =  19
 4.14 eV
300×10 9 ×1.6×10
14. Answer (9)

Out of 18 electrons present in 3rd shells.

1
Will have s  
2
15. Answer (5)
3RTNe TNe
MNe MNe
He MNe VNe MNe MNe MNe TNe 205 # 1000
    
Ne MHe VHe 3RTHe THe MHe THe 4 # 200
MHe MHe
MHe MHe
He  5Ne
16. Answer (6)

|ml| = 1

means ml can be +1 and –1

1
So, for n = 4 six orbitals are possible and bear six electrons with s = –
2
17. Answer (3)

Ground state configuration:

In second excited state, electron will jump from 1s to 2p, so degeneracy of second excited state of
H– is 3.

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36 Structure of Atom Solutions of Assignment Level-II

18. Answer (–5280.00 to –5240.00)

Potential energy of H-atom is taken as zero when electron and nucleus are at infinite distance (given).

∴ P.E. of a H-atom with electron in its ground state = – 27.2 eV (from Bohr's Model)

At internuclear distance 'd0; electron-electron repulsion and nucleus-nucleus repulsion are absent.

∴ P.E. of two H-atom = – 2 × 27.2 eV = – 54.4 eV

−
54.4 # 1.6 # 10 19 # 6.023 # 10 23
= − kJ/mol
1000
= – 5242.42 kJ/mol

19. Answer (30)

h 6.6 # 10 –27 –1
Momentum of photon   gm cm s
 330 # 10 –7
Momentum of 1 mole of He-atoms = m∆v
h
∴ mv  N A #

6 # 10 23 # 6.6 # 10 –27
4 # v 
330 # 10 –7
2
6 # 6.6 # 10
v   30 cm s –1
33 # 4
∴ Change in velocity of He-atoms = 30 cm s–1

20. Answer (30)

2
n
r = 52.9 × pm
z
2
52.9 # n
\ 105.8 = \ n2 = 2
2
2
n
=
and 26.45 52.9 × \ n1 = 1
2
1 1
E  R H hC × z = G
2
Q 
2 2
n1 n2
hc 1 1
 R H hC × z 2 = 
 2 2G
n1 n 2
34 8
6.6 × 10 × 3 × 10 1 1
× 4×;  E
18
 2.2 × 10
 1 4
6.6 × 10 –34 × 3 × 108 3
 = 2.2 × 10 –18 × 4 × 4

∴ λ = 300 Å
∴  30 nm

  

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