15-06-2025

1103CJA101021250059 JA

PHYSICS

SECTION-I (i)

1) Two straight infinitely long and thin parallel wires are spaced 0.1 m apart and carry a current
of 10 ampere each. Find the magnetic field at a point which is at a distance of 0.1 m from both wires
in the two cases when the currents are in the (a) same and (b) opposite directions

(A) when currents are in same direction, B = T

(B) when current are in opposite direction B = 2 × 10–5 T
(C) when currents are in same direction, B = 2 × 10–5 T
(D) when currents are in opposite direction B =

2) A current is flowing in a circular coil of radius R and the magnetic field at the centre is B0. At

what distance on the axis of the coil from centre, the magnetic field will be

(A)
(B)
(C) 2 R
(D) 8 R

3) The resulting magnetic field at the point O due to the current carrying wire shown in the figure

(A) is the same as due to the segment WX alone

(B) is the same as due to the segment VW alone
(C) is the same as due to the segment VWX alone
(D) is the same as due to the segment VWXY alone

4) A uniform disc of mass m has a particle P of same mass rigidly fixed at its circumference as
shown. the disc is placed on rough surface such that there is no slipping. Initially.
(A) friction is zero for all values of θ
friction on disc is in direction of motion for 0 < θ <
(B)

friction on disc is in direction of motion for

(C)

(D) friction on disc is 2μmg

5) A disc is free to rotate about an axis passing through its centre and perpendicular to its plane.
The moment of inertia of the disc about its rotation axis is I. A light ribbon is tightly wrapped over it
in multiple layers. The end of the ribbon is pulled out at a constant speed u. Let the radius of
ribboned disc be R at any time and thickness of ribbon be d (<<R). Then the force (F) be required to

pull the ribbon as a function of radius R, is

(A)

(B)

(C)

(D)

6) Two similar coils of radius R and number of turn N are lying concentrically with their planes at
right angles to each other. The current flowing in them are I and 2I respectively. The resultant
magnetic induction at the centre will be–

(A)

(B)

(C)
(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2

An infinitely long wire lying along z-axis carries a current I, flowing towards positive z-direction.
There is no other current, consider a circle in x-y plane with centre at (2 meter, 0, 0) and radius 1
meter. Divide the circle in small segments and let denote the length of a small segment in

anticlockwise direction, as shown.

1) The maximum value of path integral of the total magnetic field along the perimeter of
the given circle between any two points on the circle is

(A)

(B)

(C)

(D) 0

2) Consider two points A(3,0,0) and B(2,1,0) on the given circle. The path integral of the
total magnetic field along the perimeter of the given circle from A to B is,

(A)

(B)

(C)

(D) 0

Common Content for Question No. 3 to 4

A uniform wire frame of linear mass density λ having three sides each of length 2a is kept on a
smooth horizontal surface. An impulse J is applied at one end as shown in the figure. P is the
midpoint of AB.

3) The angular velocity of system just after the impulse is

(A)

(B)

(C)

(D)

4)

The velocity of point P just after the impulse is

(A)

(B)

(C)

(D)

Common Content for Question No. 5 to 6

A uniform rod of mass m and length ℓ is pivoted at point O. The rod is initially in vertical position
and touching a block of mass M which is at rest on a horizontal surface. The rod is given a slight jerk
and it starts rotating about point O. This causes the block to move forward as shown. The rod loses

contact with the block at θ = 30°. All surfaces are smooth.

5) The velocity of block when the rod loses contact with the block is
(A)

(B)

(C)

(D)

6) The value of ratio M/m is

(A) 2 : 3
(B) 3 : 2
(C) 4 : 3
(D) 3 : 4

SECTION-I (iii)

1) The list-I is having the graph of either electrostatic field or its magnitude versus position on x-axis
and magnetic field or its magnitude versus position on the x-axis for the system indicated in list-II.

List-I List-II

(I) (P)
Two infinite wires kept parallel to z-axis
carrying current along +z-direction.

(II) (Q)
Two infinite wires are kept parallel to z-axis.
One carrying current in +z-direction, other
carrying current in –z-direction.

(III) (R)
Two point charges each of magnitude +Q
are kept at points (–a, 0) and (a, 0).

(IV) (S)
Two point charges, +Q and –Q are kept
at points (–a, 0) and (a, 0) respectively
 (T)
Two infinite non-conducting rods are
kept parallel to the y-axis, each carrying
uniform charge density +λ.

(A) I → P;II → S;III → P;IV → S

(B) I → Q;II → S;III → Q;IV → S
(C) I → Q;II → S;III → Q;IV → T
(D) I → T;II → P;III → Q;IV → S

2) A long straight conductor of radius R carries a current I as shown. The current density j varies as
a function of radius according to j = br where b is a constant. Match the quantities in List-I with

those in List-II.

List-I List-II

(I) Binside (P) Maximum

(II) Bsurface (Q)

(III) Boutside (R)

(IV) I (total current inside wire) (S)

(T)

(A) I → R;II → Q;III → T;IV → P

(B) I → R;II → S;III → P;IV → Q
(C) I → P;II → Q;III → R;IV → S
(D) I → Q;II → PT;III → S;IV → R

3) Rod of mass = 1 kg, length ℓ = 2m is moving with linear speed v0 = 12 m/s and angular speed ω
= 4 rad/sec about center of mass of rod on smooth horizontal surface (as shown in figure). Its one
end collides with another identical rod and stick to it and start acting as single rod of length 2ℓ. [π =

3.14]
 List-I List-II

(P) Angular speed of rod just after collision (in rad/s) (1) 1.0

(Q) Loss in kinetic energy during collision (in joule) (2) 8.0

(R) Impulse exerted by rod-1 on rod-2 (in N-S) (3) 6.0

Time taken (in sec) by combined rod to complete four

(S) (4) 5.0
rotations

(5) 5.3
(A) P → 3;Q → 5;R → 1;S → 4
(B) P → 1;Q → 3;R → 2;S → 2
(C) P → 4;Q → 5;R → 1;S → 4
(D) P → 4;Q → 3;R → 3;S → 4

4) A uniform rod of length L is suspended from its end by a smooth hinge. The rod is free to rotate

in a vertical plane. If the rod is given an angular velocity of at the lowest point.

List-I List-II

Force exerted by the hinge in

(P) (1) increases continuously till the rod stops
the horizontal direction

Force exerted by the hinge in

(Q) (2) decreases continuously till the rod stops
the vertical direction

(R) Magnitude of Angular velocity of the rod (3) increases and then decreases till the rod stops

Magnitude of Angular acceleration of the

(S) (4) increases and decreases in a periodic manner
rod

(5) decreases and increases in a periodic manner

(A) P → 3;Q → 4;R → 2;S → 5
(B) P → 1;Q → 4;R → 2;S → 5
(C) P → 3;Q → 4;R → 4;S → 5
(D) P → 1;Q → 4;R → 1;S → 3

5) Column I shows four current configurations. Match each entry of column I with those axes in
column II along which the magnetic field at origin has positive component.

Column-II
Column-I
[+ve component of magnetic field at origin]
 (P) (1) x

(Q) (2) y

(R) (3) z

(S) (4) None

(A) P → 1,3;Q → 4;R → 1,2,3;S → 1,3

(B) P → 1,2;Q → 4;R → 1,3;S → 1,4
(C) P → 1,3;Q → 1,2;R → 1,4,;S → 2,3
(D) P → 1;Q → 2,3;R → 1,4;S → 2,4

CHEMISTRY

SECTION-I (i)

1) Identify reactions correctly matched with their major product ?

(A)

(B)

(C)

(D) All of these

2) Choose the correct product of the following reactions:

(A)

(B)
(C)

(D)

3) The emf of the following cell is 0.7995 V.

Pt | H2 (1 atm) | HNO3 (1M) || AgNO3 (1M) | Ag
If we add enough KCl to the Ag half cell so that the final Cl– is 1M. Now the measured emf of the cell
is 0.222 V. The Ksp of AgCl would be :

(A) 1 × 10–9.8
(B) 1 × 10–19.6
(C) 2 × 10–10
(D) 2.64 × 10–14

4) Zn Amalgam is prepared by electrolysis of aqueous ZnCl2 using Hg cathode (9 gm). How much
current is to be passed through ZnCl2 solution for 1000 seconds to prepare a Zn Amalgam with 25%
Zn by wt. (Zn = 65.4)

(A) 5.6 amp

(B) 7.2 amp
(C) 8.85 amp
(D) 11.2 amp

5) The major product in the following reaction

(A)
(B)

(C)

(D)

6) The structure of a molecule of N(SiMe3)3 is :-

(A) Pyramidal with angle close to 110°

(B) T-shaped with angle 90°
(C) Bent T-shaped with angle close to 89°
(D) Trigonal planar with bond angle close to 120°

SECTION-I (ii)

Common Content for Question No. 1 to 2

Alkane may be prepared from alkyl halide by Wurts method where alkyl halide reacted with Na in
presence of ether.

Mechanism :
1)

(A)

(B)

(C)

(D) No reaction

2)

Which of the following compounds is most reactive for Wurtz reaction ?

(A)

(B)

(C)
(D)

Common Content for Question No. 3 to 4

B is the first element of IIIrd group. It forms a number of electron deficient halides and hydrides.
Among the hydrides diborane is an important compound.

3) In B2H6 number of 3c – 2e bonds is/are

(A) 1
(B) 2
(C) 3
(D) None

4) Total number of 3C–2e bonds in

(A) 6
(B) 3
(C) 4
(D) 8

Common Content for Question No. 5 to 6

Dipole moment of a molecule is a vector sum of all the individual bond moments. Mathematically it is
μ = q × d, where q is magnitude of particle charges and d is the distance between centre of opposite
charges. Its main application includes, determination of polarity of bond, symmetry of molecule and
in calculation of % ionic character.

5) In HI molecule if observed dipole moment in 1.2 Debye and also the interionic distance between
atoms (dHI) is 1Å. The percentage covalent character in HI bond will be
(Electron charge e = 4.8 × 10–10 esu)

(A) 25%
(B) 75%
(C) 50%
(D) 12.5%

6) Which one has highest dipole moment?

(A) NH3
(B) NF3
(C) BF3
(D) PCl5
 SECTION-I (iii)

1) Match the following :

Column -I Column -II

(P) (1) (CH3)2CHCH2CH(CH3)2

(Q) (2) CH3CH2CH2CH3

(R) (3) (CH3)3CCH2CH3

(S) (4) CH3CH2C(CH3)2CH2CH3

(5) (CH3)3C–C(CH3)3
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 2;Q → 4;R → 1;S → 3
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 1;Q → 4;R → 1;S → 3

2) An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List-I. The

variation in conductivity of these reactions is given in List-II. Match List-I with List-II and select the
correct answer using the code given below the lists :

List-I List-II

(C2H5)3N + CH3COOH Conductivity decreases and then

(P) (1)
X Y increases

KI(0.1M) + AgNO3(0.01M) Conductivity decreases and then does

(Q) (2)
X Y not change much

CH3COOH + KOH Conductivity increases and then does not

(R) (3)
X Y change much

NaOH + HI Conductivity does not change much and

(S) (4)
X Y then increases
(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 1;Q → 4;R → 3;S → 2

3) Use following data to correctly match List-I with List-II :

, .

, , Ksp (AgCl) = 10–10,

Ksp (AgBr) = 5 × 10–13, and = 0.06.

 List-I List-II

M(s) | M2+(aq, 10–2 M) || X–(aq, 0.1M) | X2 (g,

(P) (1) Nonspontaneous
1 bar)

Pt(s) | H2(g, 1 bar) |NaOH(aq, 1M) || HCl(aq,

(Q) (2) Ecell = 2.02 volt
0.1M) | H2(g, 1 bar) | Pt(s)

(R) Ag(s) | AgBr(s) |Br– (aq, M) || Cl– (aq, (3) Ecell = 0 volt
1M) | AgCl(s) | Ag(s)

Pb(s) | PbI2(s) | I–(aq, 0.1M) || Cu2+(aq,

(S) (4) Ecell = 0.78 volt
0.01M) | Cu(s)

(5) Ecell = 0.59 volt

(A) P → 2;Q → 3;R → 4;S → 5
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 2;Q → 4;R → 3;S → 5

4) Match the following :

Column-I Column-II

(P) (1) Red P + HI

(Q) (2) Na/ether

(R) (3)

(S) (4) Zn–Hg/HCl

(A) P → 2;Q → 1;R → 2,3;S → 1,3,4

(B) P → 3;Q → 2;R → 1,3,4;S → 2,3
(C) P → 2;Q → 3;R → 1,3,4;S → 2,3
(D) P → 2;Q → 2,3;R → 1,3,4;S → 3

5) In a conductometric titration, small volume of titrant of higher concentration is added stepwise to

a larger volume of titrate of much lower concentration, and the conductance is measured after each
addition.
The limiting ionic conductivity (Λ0) values (in mS m2 mol–1) for different ions in aqueous solutions are
given below :

Ions Ag+ K+ Na+ H+ Cl– OH– CH3COO–

Λ0 6.2 7.4 5.0 35.0 7.2 7.6 16.0 19.9 4.1

For different combinations of titrates and titrants given in List-I, the graphs of 'conductance' versus
'volume of titrant' are given in List-II.
Match each entry in List-I with the appropriate entry in List-II and choose the correct option.
List-I List-II

Titrate : KCl
(P) (1)
Titrant : AgNO3

Titrate : AgNO3
(Q) (2)
Titrant : KCl

Titrate : NaOH
(R) (3)
Titrant : HCl

Titrate : NaOH
(S) (4)
Titrant : CH3COOH
 (5)

(A) P → 4;Q → 3;R → 2;S → 5

(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 3;Q → 4;R → 2;S → 5
(D) P → 4;Q → 3;R → 2;S → 1

MATHEMATICS

SECTION-I (i)

1) If then 16(sin(2θ) + cos(4θ) + sin(6θ)) is equal to:

(A) 23
(B) –27
(C) –23
(D) 27

2)

List-I List-II
(A) Sum of interior angles of heptagon is kπ, then k is (I) 6
2
(B) Number of solutions of equation 2sin 2x – 3sin2x + 1 = 0 in x ∈ [0, 2π], is (II) 3
2
If number of integers in range of (12sinx + 5cosx + 2) is N, then remainder, when N
(C) (III) 4
is divided by 10, is

(D) (IV) 5
Value of is
(A) (A)-IV, (B)-I, (C)-I, (D)-III
(B) (A)-IV, (B)-IV, (C)-III, (D)-II
(C) (A)-III, (B)-II, (C)-I, (D)-IV
(D) (A)-II, (B)-I, (C)-IV, (D)-III

3)

The number of points in , for which x2 – xsinx – cosx = 0, is

(A) 6
(B) 4
(C) 2
(D) 0

4) The x co-ordinate of the point on the curve which is closest to the point (2, 1) is

(A)

(B)

(C)

(D) 1

5) Which of the following points lies on the tangent to the curve x4ey+ 2 = 3 at the point (1, 0)
? [JEE MAIN 2020]

(A) (2, 2)
(B) (–2, 6)
(C) (–2, 4)
(D) (2, 6)

6) Let . If I(0) = 0 the I is equal to

(A)

(B)

(C)

(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2

Consider a function ƒ(x) such that . Where ƒ(1) = 6 and C is

constant of integration.

1) is equal to

(A)
(B)
(C)
(D)

2)

Equation of tangent to the curve at the point where curve intersect the y-axis is :

(A) x – y = 1
(B) x + y = 1
(C) y – x = 1
(D) x + y = –1

Common Content for Question No. 3 to 4

Answer Q. by appropriately matching the information given in the three columns of the following
table.
Let ƒ(x) = x + logex – x logex, x ∈ (0, ∞).
* Column 1 contains information about zeros of ƒ(x), ƒ'(x) and ƒ"(x).
* Column 2 contains information about the limiting behavior of ƒ(x), ƒ'(x) and ƒ"(x) at infinity.
* Column 3 contains information about increasing/decreasing nature of ƒ(x) and ƒ'(x).

Column 1 Column 2 Column 3

(I) ƒ(x) = 0 for some x ∈ (1, e2) (i) limx→∞ƒ(x) = 0 (P) ƒ is increasing in (0,1)

(II) ƒ'(x) = 0 for some x ∈ (1,e) (ii) limx→∞ƒ(x) = –∞ (Q) ƒ is decreasing in (e,e2)

(III) ƒ'(x) = 0 for some x ∈ (0,1) (iii) limx→∞ƒ'(x) = –∞ (R) ƒ' is increasing in (0,1)

(IV) ƒ"(x) = 0 for some x ∈ (1,e) (iv) limx→∞ƒ"(x) = 0 (S) ƒ' is decreasing in (e,e2)

3) Which of the following options is the only INCORRECT combination ?

(A) (II) (iii) (P)

(B) (II) (iv) (Q)
(C) (I) (iii) (P)
(D) (III) (i) (R)

4) Which of the following options is the only CORRECT combination ?

(A) (III) (iii) (R)

(B) (I) (i) (P)
(C) (IV) (iv) (S)
(D) (II) (ii) (Q)

Common Content for Question No. 5 to 6

Consider a function f defined by , which satisfies

and f(x) = f(4π – x) for all , then
5) If α is the length of the largest interval on which f(x) is increasing, then α =

(A)

(B) π
(C) 2π
(D) 4π

6) If f(x) is symmetric about , then β =

(A)

(B) α

(C)

(D) 2α

SECTION-I (iii)

1) Let ~ {1} & f(1) = 1, then

Match Column-I with Column-II.

Column-I Column-II

(P) f(x) is increasing in (1) x ∈ (1,∞)

(Q) f(x) is decreasing in (2)

x ∈ (0, ) ∪ (5, ∞)

(R) f(x) has a local minima in (3) x ∈ (0,1)

(S) f(x) = x has only one solution in (4) x ∈ (0,2)

(5) x ∈ (0, 1) ∪ (4, 5)

(A) P → 3;Q → 1;R → 4;S → 4
(B) P → 4;Q → 2;R → 1;S → 3
(C) P → 5;Q → 1;R → 2;S → 5
(D) P → 1;Q → 2;R → 3;S → 4

2) Let
Match the expressions/statements in Column I with expressions/statements in Column II.

Column-I Column-II
(P) If , then f(x) satisfies (1) 0 < f(x) < 1
(Q) If 1 < x < 2, then f(x) satisfies (2) f(x) < 0
(R) If 3 < x < 5, then f(x) satisfies (3) f(x) > 0
(S) If x > 5, then f(x) satisfies (4) f(x) < 1
(A) P → 1,2;Q → 3;R → 1,2,3;S → 4
(B) P → 1,3,4;Q → 2,4;R → 2,4;S → 1,3,4
(C) P → 1,3;Q → 2,4;R → 2;S → 1,4
(D) P → 1,3,4;Q → 1,3;R → 2,4;S → 3

3) The values of k ∈ R for which

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) sum of roots of x2 + (2 – k – k2)x – k2 = 0 is zero (1) –4

(Q) The roots of x2 + (2k – 1)x + k2 + 2 = 0 are in ratio 1 : 2 (2) 1

(R) Sum of the square of the roots of x2 – (k – 2)x – k – 1 = 0 assume the least value (3)

(S) kx2 – (k + 1)x + 2k – 1 = 0 has equal roots (4) –2

(5) –3
(A) P → 2,4;Q → 1;R → 2;S → 2,3
(B) P → 2,3;Q → 2;R → 1;S → 2,4
(C) P → 2,4;Q → 2,3;R → 2;S → 1
(D) P → 2;Q → 2,4;R → 2,3;S → 1

4)

Column-I Column-II

(P) If ƒ(x) = such that ƒ , then the value of ƒ is (1)

equal to

(Q) The number points of discontinuity of is k (2)

(where [.] denotes greatest integer function), then is equal to

(R) (3)
If such that , then h(1) is equal to

If (where D is constant of
(S) (4)

integration), then the value of (A + B + C) is equal to

(5)

(A) P → 1;Q → 3;R → 2;S → 5

(B) P → 4;Q → 2;R → 5;S → 1
(C) P → 3;Q → 1;R → 2;S → 4
(D) P → 1;Q → 2;R → 5;S → 1

5)

Column-I Column-II

P If curves y2 = 4ax and y = e–x/2a orthogonal then ‘a’ can take value (1) 3

If θ is angle between the curves y= [|sin x| + |cos x|], ([⋅] denote GIF) and x2 + y2
Q (2) 1
= 5 then cosecs2θ is

If curves y2 = 4a (x + a) and y2 = 4n (x + b) intersects each other orthogonally

R (3) 5/4
then can be equal to____

If y = x2 + 3x +c and x = y2 +3y + c touches each other at (h, k) then |h + k + c |

S (4) 2
can be equal to....
(A) P → 1,2,3;Q → 1,3;R → 2;S → 4
(B) P → 3,4;Q → 1;R → 1,3;S → 1,2,3
(C) P → 1,3;Q → 1,3,4;R → 1,2,3;S → 1,3
(D) P → 3,4;Q → 1,3;R → 3,4;S → 1,2,3
 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. B B D B C D

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. C B A D A C

SECTION-I (iii)

Q. 13 14 15 16 17
A. B D C A A

CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21 22 23
A. D C A C A D

SECTION-I (ii)

Q. 24 25 26 27 28 29
A. A B B A B A

SECTION-I (iii)

Q. 30 31 32 33 34
A. A A D C C

MATHEMATICS

SECTION-I (i)

Q. 35 36 37 38 39 40
A. C A C A B C

SECTION-I (ii)

Q. 41 42 43 44 45 46
A. B A D D C B
 SECTION-I (iii)

Q. 47 48 49 50 51
A. A B A D C
 SOLUTIONS

PHYSICS

1)

= 2 × 10–6 × 10 ×

B=
= 2 × 10–5

2)

3) B due to UV wire and yz wire = 0.

Bnet = B due to vwxy wire.

4) As there is no slipping, torque about point of contact mgRsinθ in clockwise direction. So

acceleration of C.M. is towards right equal to αR. Hence friction is towards right.

If torque is zero, so no friction.

5) ω r = u = Constant
ln ω + ln r = lnv

→
 ...(1)
If we consider an interval 'dt' in which radius decreases by 'dR', then

→ ...(2)
From (1) & (2)

Torque on disc = Iα

6)

7) Consider two points P and Q lying on dotted circle and equidistant from origin O. We draw a

circular arc QP with centre at origin O. The path integral of magnetic field, that is ,

along the dotted circle between two points P and Q is also is equal to path integral

along the arc QP whose centre is at origin. Therefore the path

integral of magnetic field along the dotted circle between two points P and Q.

The value of θ will be maximum when chord OQ and chord OP will be tangent

to the dotted circle, that is, . Hence the required maximum value = .

8)
the total magnetic field along the perimeter of the given circle from A to B is

9)

10)

11)

Decrease in potential energy of rod = increase in rotational kinetic energy of rod +

translational kinetic energy of block

Solving this equation, we get

12) At angle shown in figure :
Decrease in potential energy of rod = increase in rotational kinetic energy of rod +
translational kinetic energy of block.
But

From here we get,

.....(i)

.....(ii)
For block
.....(iii)
Now putting values of at and an from Eqs. (i) and (ii) in Eqs. (iii) and then putting N = 0 and
in the equation we get,

13) New Ans. (None of these) by Parantak Sharma sir

(P) Use right hand screw rule

(Q) Use right hand screw rule

(R) In right of +Q E = +ve

In left of + Q E = –ve

(S) No neutral point here

(T)
No answer matched

14)
Use ampere law of B.

15)
From linear momentum conservation
mv0 = 2mv

From angular momentum conservation about a point on surface which coincide with COM of
combined rod system.

Loss in KE = KEi – KFf

Linear impulse on rod 2

= 1 N-sec
Time taken to complete four rotation

16)

1 – cos θ = 1
cos θ = 90°

ω=0
Fx = 0

17) Use right hand curl rule to predict the direction of magnetic fields.
(A) B is along +ve × and +ve z.
 (B) B is along –ve x.
(C) B is along +ve x, +ve y and +ve z.
(D) B is along +ve x and + ve z.

CHEMISTRY

18) Explanation - Question is asking about correctly matched with their major product.
Concept -

A. Electrophilic addition of Br2 on cis and trans but - 2 - ene

B. Addition of HBr on conjugated diene

Solution -
(1) Trans + Br2 → meso / mesolike.

(2)

(3)

Final Answer - Option (4) is correct

19)
20)

(Ag+) = 10–9.8
Ksp = (Ag+) (Cl–) = (10–9.8) × (1) = 10–9.8

21)

Let x gm of Zn deposit on 9 gm of Hg

% of Zn in Amalgam

Eq. of Zn

Current i

22)

23)
Trigonal planer structure due to back-bonding (N→Si) and bond angle close to 120°.

24)
25)

26)
In B2H6 two (3C–2e–) bond is present.

28) % ionic =
⇒ % covalent = 100 – 25 = 75%

29)

NH3

30)

P-2, Q-1, R-4, S-3

31) (C2H5)3 N + CH3COOH ⇒ Weak acid and weak base so conductivity increases and then does
not change much so option 3 hence and (a).

32) (P)

or Ecell = 1.9 – 0.03 log =

(R) Ecell = 0 –

(S)

or, Ecell = 0.47 – 0.03 log

 = 0.47 – 0.03 log = 0.47 + 0.03 × 4 = 0.59 V.

33)

P-2; Q-3; R-1,3,4; S-2,3

34)

Option (P) :
On adding AgNO3 solution to KCl solution precipitation of AgCl will occur due to which Cl–
already present will be replaced by NO3– ions. So conductance of solution will decrease till
equivalence point. After complete precipitation of AgCl, further added AgNO3 will increase the
number of ions in resulting solution so conductance will increase.
Option (Q) :
On adding KCl solution to AgNO3 solution precipitation of AgCl will occur due to which already
present Ag+ ions will be replaced by K+ ions in solution. So conductance of solution will
increase. After complete precipitation of AgCl further added KCl will increase the number of
ions in resulting solution so conductance will increase further.
Option (R):
On adding HCl solution to NaOH solution, OH– will be replaced by Cl– ions so conductance of
solution decreases. After complete neutralisation further added HCl will increase number of
ions in the solution. So conductance will increase futher.
Option (S):
On adding CH3COOH solution to NaOH solution OH– will be replaced by CH3COO– ions, so
conductance of solution decreases. After complete neutralisation further added CH3COOH will
remain undissociated because it is a weak acid and there is also common ion effect on acetate
ions. So number of ions in solution will remain almost constant therefore conductance of
solution will remain constant.

MATHEMATICS

35)

Now :
sin6θ = 3sin2θ – 4 sin32θ

= – 23

36) (A) Use (n – 2)π

(B) sin2x = 1 or sin2x =

∴
(C) Range = [0, 225]
∴ Number of integers = 226

(D)

37)

Also f(0) = –1
So, graph of f(x)

Hence, given equation has 2 roots.

38) Closest distance exist always along the normal

Let

so

39)

x4ey + 2 = 3
d.w.r. to x

x4 ey y' + ey 4x3 + =0
at P(1, 0)
+4+ =0
⇒ = –2
Tangent at P(1, 0) is
y – 0 = –2 (x – 1)
2x + y = 2
(–2, 6) lies on it

40)
Let xtan x + 1= t

As I(0) = 0 ⇒ C = 0
41)

let 6 + 4x–5 – x–7 = t2 then

⇒ (–20x–6 + 7x–8)dx = 2tdt

42)

let 6 + 4x–5 – x–7 = t2 then

⇒ (–20x–6 + 7x–8)dx = 2tdt

= 6x7 + 4x2 + x – 1 = g(x)

g'(x) = 42x6 + 8x + 1
g'(0) = 1
equation of tangent at (0, –1) is y + 1 = x

43) f ' (x) is decreases and f ' (1) = 1

⇒ f ' (x) = 0 has no root in (0,1)

44)
⇒ f(x) is decreasing in (e, e2)

45) Let g(x) = , is increasing function of x.

∴ range of g(x) is

∴ f(x) = ,
Now let , then

i.e., f(t) + =π

i.e f(t) + π – – =π

i.e f(t) =

∴ f(x) = for

Thus f(x) = for

Also f(x) = f(4π – x) for all x ∈ [2π, 4π]
⇒ f(x) is symmetric about x = 2π
∴ from graph of f(x)
∴ α = 2π – 0 = 2π
∴β=α

46) Let g(x) = , is increasing function of x.

∴ range of g(x) is

∴ f(x) = ,
Now let , then

i.e., f(t) + =π

i.e f(t) + π – – =π

i.e f(t) =

∴ f(x) = for

Thus f(x) = for

Also f(x) = f(4π – x) for all x ∈ [2π, 4π]
⇒ f(x) is symmetric about x = 2π
∴ from graph of f(x)
∴ α = 2π – 0 = 2π
∴β=α

47)
F(1) = F(0) = 1

48)

for and x > 5;

⇒
⇒

Now,

(A) If ;
Hence, also
(B) If ;
(C) If ;
(D) If ;
Hence, also, .

49) (I) 2 – k – k2 = 0 ⇒ k = 1, – 2
(II) α + 2α = –(2k – 1)
 α(2α) = k2+ 2

(III) α2 + β2 = (k – 2)2 + 2(k +1)

= k2 – 2k + 6 = (k – 1)2 + 5
so for k= 1 it assume leastvalue

(IV) (k + 1)2 – 4k(2k – 1) = 0

7k2 – 6k – 1 = 0 ⇒ (7k + 1) (k – 1) = 0

50) (A) ƒ(x) = ⇒ƒ

(B)

discontinuous at 6 points

Hence

(C) Put

(D)

differentiate both side and compare coeff. to get

51)

(A) =

Product of slopes =
(B) 1≤ |sin x| + |cos x| ≤

⇒y=1
P(2,1)
(C) Let y2= 4a (x + a) ...(1)
2
and y = 4b (x + b) ...(2)
intersect each other at (h, k) then h = –(b +a)

Now for curve (1) is and for curve (2) is

Which is always true

can take any value from interval

(D) Inverse curves touch each other at line y = x
⇒ y = x is tangent to both curves ⇒ equation x = x2 + 3x +c has both equal roots
⇒ c =1 and x = –1 = h and y = –1 = k ⇒ |h + k + c | =1