Solution
Solution
9610ZJA801821250001 JA
PART-1 : PHYSICS
SECTION-I (i)
1)
On the basis of dimensions, decide which of the following relations cannot give displacement of
particle undergoing simple harmonic motion. y represent displacement; [a] = [L]; [t] = [T]
(A)
(B)
(C)
2)
Where x is a distance from fixed point. Which of the following has dimension of energy.
(A)
(B) CB2
(C) ABC
(D) C
(A) 3m
(B) 5m
(C) 6m
(D) 2m
4)
5) A positive point charge q is located inside a neutral hollow spherical conducting shell. The shell
has inner radius a and outer radius b ; b – a is not negligible. The shell is centred on the origin.
Which of the following is correct graph of electric field vs radial distance x or electric potential vs
radial distance x. The point charge can be located anywhere inside shell on x-axis.
(A)
(B)
(C)
(D)
6) You are moving a negative charge q < 0 at a small constant speed away from a uniformly charged
non-conducting spherical shell on which resides a negative charge Q < 0. The electrostatic field of Q
is E. Let U be the total energy of the system, Wa the work done by the force Fa you exert on q and WE
the work done by the electrostatic force FE on q. Then, as q is being moved,
SECTION-I (ii)
shell just after firing is times of kinetic energy of shell before firing.
(A) 4R + R
(B) 8R +
(C) 8R + R
(D) 6R + R
2) Minimum distances of shell and canon from center of earth are r1 and r2 then value of :-
(A) 4
(B) 16
(C) 8
(D) 12
(A) 2R
(B) R
(C) 2/3 R
(D) None of these
4)
(A) v0R
(B) v0R/2
(C) 2v0R/3 R
(D) None of these
SECTION-II
1)
Two identical balls of mass m = 0.9 g each are charged by the same charges, joined by a thread and
suspended from the ceiling (figure). Find the charge (in μC) that each ball should have so that the
tension in both the threads are same? The distance between the centers of balls is R = 3m (take g =
10 m/s2).
2)
The variation of potential with distance R from a fixed point is as shown below. The electric field at R
= 5 m is ....... volt/m
3) A particle is projected radially outwards from the surface of a planet with an initial speed of 4.0
km/s. Maximum height attained by the particle is h = 900 km from the planet’s surface. Find the
radius R (in km) of the planet taking g = 10 m/s2 on the surface of the planet. Fill R/900.
4) Two particles of combined mass M, placed in space with certain separation, are released.
Interaction between the particles is only of gravitational in nature and there is no external force
present. Acceleration of one particle with respect to each other when separation between them is R,
5) Force F & density ρ are related as then write modulus of sum of the dimensions of
length in α & β.
6) In a new system of units, mass, acceleration & frequency are taken as fundamental units. If unit of
mass is 100 g, unit of acceleration is 2 m/s2 and unit of frequency is 4 sec–1, in this new system of
units, then the value of 10 J in this new system is K × 100. Fill K.
X. The value of is
8) Three forces of magnitudes 3 N, 3 N and 6 N act at corners of a cuboid along three sides as
PART-2 : CHEMISTRY
SECTION-I (i)
1) Which of the following options is/are not correct w.r.t oxidation number (O.N.) ?
(A) The oxidation state of both the Nitrogen atoms in NH4NO3 is +1.
(B) O.N. of Sulphur in FeS2 is –2.
(C) O.N. of F can never be positive.
(D) O.N. of alkaline earth metals can either be 0 or +2 and no other value.
2) When a equimolar mixture of Cu2S and CuS is titrated with Ba(MnO4)2 in acidic medium, the final
products contain Cu2+, SO2 and Mn2+. If the Mol. mass of Cu2S, CuS and Ba(MnO4)2 are M1, M2 and
M3 respectively then :
(A)
Eq. mass of Cu2S is
(B)
Eq. mass of CuS is
(C)
Eq. mass of Ba(MnO4)2 is
(D) Cu2S and CuS both have same equivalents in mixture.
4) Lithium metal reacts with nitrogen gas to produce a white solid Lithium nitride (Li3N) according
to the reaction:
(Atomic mass of Li = 7, N = 14)
6 Li (s) + N2 (g) 2Li3N(s)
If 8.4 g of Li is taken initially with excess of N2 (g) then :
5) A sample of oxygen contains O16 & O18 isotopes only with percentage abundance respectively as
90% & 10%.
Identify the correct option(s) :
(A) y – x = 80 ml
(B) y + x = 160 ml
If the titration is started with phenolphthalein indicator and methyl orange is added at the end
(C)
point, 2x ml. HCl would be required further to reach end point.
(D) y + x = 120 ml.
SECTION-I (ii)
(A) CH2O
(B) C2H4O2
(C) C2H5O
(D) C4H10O2
(A) MnO
(B) MnO2
(C) Mn2O3
(D) Mn3O4
(A) 1
(B) 2
(C) 1/4
(D) 1/2
4)
The equivalent weight of Br2 in the comproportionation reaction is [Atomic weight of Br = 80]
(A) 80
(B) 32
(C) 96
(D) 40
SECTION-II
1) A gaseous mixture contains 2 moles of He and 6 moles H2 . Calculate average molar mass of the
mixture.
2) The volume of 0.10 M AgNO3 should be added to 10.0 ml of 0.09 M K2CrO4 to precipitate all
the chromate as Ag2CrO4 is (in mL)
3) What mass (kg) of H2SO4 could be produced in the process given below, if 5.52kg of FeS2 is used.
FeS2(s) + O2(g) → Fe2O3(s) + SO2(g)
SO2(g) + O2 (g) → SO3(g)
SO3(g) + H2O(ℓ) → H2SO4 (aq)
4) Potassium dichromate in acidic medium reacts with H2S to oxidise it as per given unbalanced
equation. How much kg of K2Cr2O7 must be required if 1000 kg of sulphur is to be produced by
following reaction ? (Molar mass of K2Cr2O7 = 294 g/mol).
5) Mass percentage of oxygen in divalent metal carbonate is 36%. If the number of metal atoms in
266.66 mg of this metal carbonate sample is x × 1020 then find value of x [NA = 6.02 × 1023]
6) A mineral consists of an equimolar mixture of the carbonates of two bivalent metals. One metal is
present to the extent of 13.2% by weight. 2.58 g of the mineral on heating lost 1.232 g of CO2.
Calculate the % by weight of the other metal.
7) The following redox reaction occurs in basic medium : NO3– + Zn(s) → Zn2+ + NH4+ , when the
above reaction is balanced such that the stoichiometric coefficients are in smallest whole number
ratio, then the difference of stoichiometric coefficient of OH– and Zn(s) ion will be -
8) Calculate the mass of anhydrous oxalic acid, which can be oxidised to CO2 (g) by 100 ml of an
MnO4– solution, 10 ml of which is capable of oxidising 50 ml of 1N I– to I2
PART-3 : MATHEMATICS
SECTION-I (i)
1) The values of x in [–2π, 2π], for which the graph of the function y = – secx and
(A)
(B)
(C)
[–2π, 2π] –
(D)
2) be a function that satisfies f(x) + f(y) = f(x + y) – x2y2 and if f(3) = 5 where z is a set
of integers then f(x) is
(A) One-one
(B) Many-one
(C) Onto
(D) Into
3) Given ƒ(1) = 2 and , then which of the following option is/are correct ?
(A)
ƒ
(B)
(C) ƒ(1001) = 2
(D) ƒ(2015) = –3
5)
Let α and β be the roots of x2 – x – 1 = 0, with α > β. For all positive integers n, define
(B)
(C)
n n
(D) bn = α + β for all n 1
6) For a quadratic plynomial f(x)=4x2 − 8kx + k, the statements which hold good are ?
(C)
f(x) = 0 has two distinct solutions in (0,1) for
(D) Minimum value of f(x) is k(1 + 12k) ∀ k ∈ R
SECTION-I (ii)
(A) α = 7n + 4
(B) α = 10n + 4
(C) α = 7n + 3
(D) α = 10n + 3
⇒
As α is a root of ax3 + bx2 + cx + d = 0
we get
⇒ dy3 + cy2 + by + a = 0
This is desired equation.
On the basis of above information, answer the following questions
3) If α, β are the roots of the equation ax2 + bx + c = 0, then the roots of the equation
a(2x + 1)2 + b(2x + 1) (x – 1) + c(x – 1)2 = 0 are-
,
(A)
(B)
,
,
(C)
,
(D)
⇒
As α is a root of ax3 + bx2 + cx + d = 0
we get
⇒ dy3 + cy2 + by + a = 0
This is desired equation.
On the basis of above information, answer the following questions
4) If α, β are the roots of the equation px2 – qx + r = 0, then the equation whose roots are and
is
SECTION-II
2) Let f(x) = 30 – 2x – x3, then find the number of positive integral values of ‘x’ which satisfies
f(f(f(x))) > f(f(-x)).
4) Consider the graph of real valued function ƒ(x) defined ∀ x ∈ as shown above. The number of
6)
The number of solutions of the equation for x ∈ [–4, 4], is (where [.] denotes
greatest integer function)
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5 6
A. B,D A,B A,B C,D A,B,D B,D
SECTION-I (ii)
Q. 7 8 9 10
A. B C B B
SECTION-II
Q. 11 12 13 14 15 16 17 18
A. 3.00 2.50 8.00 1.00 5.00 4.00 1.00 7.34 to 7.35
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 19 20 21 22 23 24
A. A,B A,B A,B,D A,B,C,D A,B,C,D A,B,C
SECTION-I (ii)
Q. 25 26 27 28
A. B B D C
SECTION-II
Q. 29 30 31 32 33 34 35 36
A. 2.50 18.00 9.00 3062.50 12.04 21.70 6.00 22.50
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 37 38 39 40 41 42
A. A,C B,D A,B,C B A,B,D A,B,C
SECTION-I (ii)
Q. 43 44 45 46
A. C A C C
SECTION-II
Q. 47 48 49 50 51 52 53 54
A. 0.00 2.00 4.00 4.00 6.00 8.00 1.00 22.00
SOLUTIONS
PART-1 : PHYSICS
1)
Trignometric ratios are defined only for angles, and angles should be dimensionless.
2)
3)
4)
6)
if charge is being moved slowly,
ωa + ωE = ΔKE = 0 [charge is moved slowly]
i.e. wa = – wE
also wE = – ΔU
thus wa = + ΔU
As force Fa and displacement are 180°
wa < 0
thus ΔU < 0
Therefore U decreases
7)
0
v2 = v =
and
For both shell and canon (V3 – Speed of apogee or perigee)
⇒ r2 – 16Rr + 32R2
r= or
both maximum and minimum distances of shell and canon are same so r1 = r2
8)
0
v2 = v =
and
For both shell and canon (V3 – Speed of apogee or perigee)
⇒ r2 – 16Rr + 32R2
r= or
both maximum and minimum distances of shell and canon are same so r1 = r2
9)
....(ii)
Solving both we get
r ⇒ 2R
∴ Height from surface is R.
10)
Area velocity =
11)
Fe = mg
⇒ q = 3 × 10–6 C
= 3 μC
12)
Intensity at 5m is same as at any point between B and C because the slope of BC is same
throughout (i.e., electric field between B and C is uniform). Therefore electric field at R = 5m
is equal to the slope of line BC hence by ;
At R = 1 m,
and at R = 3m potential is constant so E = 0.
13)
R = 72 × 105 m ⇒ 7200 km
14)
a1 = / M1
a2 = / M2
acceleation of M1 w.r.t. M2
arel. = a1 + a2
= =
15)
⇒ α = M2L–2T–2
β = ML–3
∴ (–2 – 3) = 5
16) [Energy] = ML2T–2 =
n1v1 = n2v2
n2 = 10
= 10 × 10 × × 16
n2 = 400
17)
18)
PART-2 : CHEMISTRY
n–factor = 8 6 10
Initial excess
moles = 1.2
23)
Atomic no. same for both so, Avg. protons per atom is 8.
Avg. no. of neutrons = Avg. atomic mass – Z = 8.2
x = 40 ml
With MeOH only :
1 × nAgA = 1 × nAg
= MAH = 59 + 1 = 60
ratio
nC = 1 EF ⇒ CH2O
nH = = 0.8 2
nO = = 0.4 1 n= =2
MF = C2H4O2
Mn 63.3 1.15 1
O 36.7 2.29 2
28)
Anode (Br– )5
nF =
Equivalent weight = =
= 32 × 3 = 96
29)
30)
∴ W= = 9 Kg
32)
Every 294 g K2Cr2O7 gives 96 g of S, So 3062.5 kg of K2Cr2O7 is required to produce 1000 kg of
sulphur.
36 =
⇒ M = 73.33
Molar mass of metal carbonate = 73.33 + 60 = 133.33
x = 12.04
= ×1.232 = 1.68 gm
so total wt. of carbonates = 1.68 gm
wt. of metal (A + B) = 2.58 – 1.68
= 0.90 gm
wt. of B = 0.90 – 0.34
36)
PART-3 : MATHEMATICS
37)
No solution
For the graphs coincide, sin(x) has to be a one one function in that given
domain.
Hence the required domain is
Or
38) Put y = 1
f(x) – f(x + 1) = –x2 – f(1)
now put x = 1 to n
x = 1; f(1) – f(2) = –12 – f(1)
x = 2; f(2) – f(3) = –22 – f(1)
x = 3; f(3) – f(4) = –32 – f(1)
x = n; f(n) – f(n + 1) = –n2 – f(1)
Add above n equations
f(1) – f(n + 1) = –[12 + 22 + 32 + 42 + ........+ n2] – nf(1)
Now put n = 2
f(1) – f(3) = –5 – 4f(1) ⇒ f (1) = 0
39)
∵
∴ .....(i)
or ƒ(n + 4) = ƒ(n) ∀ n ∈ N
hence ƒ(n) is a periodic sequence with period 4
using (A) put n = 1, 2, 3
we get
Now ƒ(2012) = ƒ(4) = –3
ƒ(2013) = ƒ(1) = 2
ƒ(2015) = ƒ(3) =
ƒ(1001) = ƒ(1) = 2
,
If (b, a) ∈ S then
41)
α, β are roots of x2 – x –1
ar+2 – ar
= ar+1
⇒ ar+2 – ar+1 = ar
Now
Further, bn = an–1 + an+1
= αn + βn
D. Min. value
43) a R b ⇒ 3a – 3b + ∈ QC
a R a ⇒ 3a – 3a + = ∈ QC
R is reflexive
a R b ⇒ 3a – 3b + ∈ QC
b R a ⇒ 3b – 3a + QC
when 3a – 3b = then
3b – 3a = –
a R b ⇒ 3a – 3b + ∈ QC
b R c ⇒ 3b – 3c + ∈ QC
a R c ⇒ 3a – 3c + QC
R is not transitive
45)
ax2 + bx + c = 0
=0
=y
2x + 1 = xy – y
(2 – y)x = –1–y
x=
Option c is correct
46)
px2 – qx + r = 0
y=
= α2
α=
pα2 + r = qα
py – r + r =
p2y2 =
p2y2 – q2y + =0
p3y2 – pq2y + q2r = 0
Option C is correct
47)
Period of f(x) = 2π
Range
49)
51)
and
and
and
and
⇒
⇒ or
⇒ x= 3, 4, 5, –5, –4, –3
Total 6 values
52)