Structure of the Atom - Class 11 Chemistry Notes
1. Introduction
Atoms are the basic building blocks of matter. Early models of atoms couldnt explain many
observations like spectra. Scientists developed better models.
2. Subatomic Particles
Electron: Charge = -1.61019 C, Mass = 9.11031 kg
Proton: Charge = +1.61019 C, Mass = 1.6721027 kg
Neutron: Charge = 0, Mass = 1.6751027 kg
3. Atomic Models
Thomsons Model: Atom is a positive sphere with electrons.
Rutherfords Model: Atom has a dense, positively charged nucleus; electrons revolve around it.
Bohrs Model: Electrons revolve in fixed orbits; energy emitted/absorbed during transitions.
4. Atomic Number (Z), Mass Number (A), Isotopes
Z = No. of protons; A = No. of protons + neutrons
Isotopes: Same Z, different A (e.g. 1H, 2H, 3H)
5. Isobars and Isotones
Isobars: Same A, different Z (e.g. 40Ca and 40Ar)
Isotones: Same neutrons, different Z and A
6. Electron Distribution (Bohr-Bury Rules)
Max electrons in shell = 2n2; Outer shell max = 8 electrons
7. Emission Spectrum of Hydrogen
When electrons fall to lower orbits, energy is released.
Lyman (n=1, UV), Balmer (n=2, Visible), Paschen, Brackett, Pfund (Infrared)
8. Quantum Numbers
n (Principal), l (Azimuthal), m (Magnetic), s (Spin)
9. Heisenbergs Uncertainty Principle
x p h / (4)
10. de Broglies Equation
= h / mv (Wave-particle duality of electrons)
11. Electron Configuration Rules
Aufbau Principle: Fill lower energy orbitals first
Pauli Principle: No two electrons have same 4 quantum numbers
Hunds Rule: Fill orbitals singly before pairing
12. Examples of Configurations
H = 1s1, He = 1s2, O = 1s2 2s2 2p4
Summary:
- Atomic Number = No. of protons/electrons
- Mass Number = Protons + Neutrons
- Isotopes = Same Z, diff A
- Isobars = Same A, diff Z
- Quantum Numbers = Describe electrons position and energy